Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBlend miscibility of bisphenol A polycarbonate and poly(ethylene terephthalate) as studied by solid-state high-resolution carbon-13 NMR spectroscopyP. Mark Henrichs, John Tribone, Dennis J. Massa, and James M. HewittCite this: Macromolecules 1988, 21, 5, 1282–1291Publication…
Abstract The growth and dissolution of oxide layers on silicon has been studied under illumination and in the dark by analyzing current transients at different voltages in solutions of NH 4 F of various concentrations at pH values between 1 and 4.5. When the oxidation rate of the silicon at high enough anodic bias and…
A review is given of glow discharge techniques which are useful for conditioning vacuum vessels for high-vacuum applications. Substantial development of glow discharge techniques has been done for the purpose of in situ conditioning of the large ultrahigh vacuum systems for particle accelerators and magnetic fusion de…
The resistance of coarse‐grained alumina to stable crack growth, initiated from “naturally’occurring surface flaws, was studied in strength tests with a bend‐bar technique. The surface cracks experienced R‐curve behavior over the first few hundred micrometers; i.e., the applied crack driving force had to be increased…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxidation of carbon monoxide on palladium: role of the alumina supportF. Rumpf, H. Poppa, and M. BoudartCite this: Langmuir 1988, 4, 3, 722–728Publication Date (Print):May 1, 1988Publication History Published online1 May 2002Published inissue 1 May 1988https://pubs.acs.org/d…
Polymer films containing dispersions of liquid crystal microdroplets have considerable potential for use in displays and other light control devices. These polymer-dispersed liquid crystal (PDLC) films operate by electric field control of light scattering, rather than by polarization control as in the case of twisted…
Betaine phosphite, an addition compound of the amino acid betaine and phosphorous acid, can be grown in single crystal form from aqueous solutions. Structural, optical, dielectric, and caloric data of this new material are reported. At least two phase transitions are observed in (CH3)3NCH2COO˙H3PO3. The lower one, aro…
Qualitative X-ray microanalysis of biological specimens requires an approach that is somewhat different from that used in the materials sciences. The first step is deconvolution and background subtraction on the obtained spectrum. The further treatment depends on the type of specimen: thin, thick, or semithick. For th…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIn-plane structure of underpotentially deposited copper on gold(111) determined by surface EXAFSO. R. Melroy, M. G. Samant, G. L. Borges, J. G. Gordon II, L. Blum, J. H. White, M. J. Albarelli, M. McMillan, and H. D. AbrunaCite this: Langmuir 1988, 4, 3, 728–732Publication D…
Annealing of polymers below the glass transition temperature results in a decrease in enthalpy that is recovered during heating. The enthalpy recovery is visible as an endothermic peak in a differential scanning calorimetry (DSC) scan. The position of this peak depends on the thermal treatment given and on the structu…
The analytical function of crack extension to a fractional power is used to represent the fracture resistance of a vitreous‐bonded 96% alumina ceramic. A varying flaw size, controlled by Vickers indentation loading between 3 and 300 N, was placed on the prospective tensile surfaces of four‐point bend specimens, previo…
The use of an arterial prosthesis with a tapered lumen has several important advantages; for example, improved stability of flow, increased wall shear and better matching of its size with that of the host vessel. Tapering may, however, lead to increased energy losses, particularly if the angle of taper is large and th…
Based on the concept of bond polarizabilities the optical properties of a crystal are traced back to the orientation of its bonds and to the individual bond parameters \bar \betaand Δβ. A test with various sulfate compounds shows that the average bond parameters \bar \beta describe the average refractive indices with…
The crystal and magnetic structure of Ga substituted MnAl alloys has been investigated by neutron diffraction. Gallium atoms are found to occupy both the (0,0,0) and ( (1)/(2) , (1)/(2) , (1)/(2) ) crystallographic sites [differently from Al which occupy ( (1)/(2) , (1)/(2) , (1)/(2) ) sites] and have a preference for…
We have used photoemission spectroscopy with synchrotron radiation in the energy range hν=40–140 eV to study the interface formation of Ag overlayers on cubic SiC(100). Our data are consistent with a three-dimensional island growth mode of Ag at room temperature. The substrate attenuation curve supports a model of red…
Nuclear reaction data for the doubly differential cross sections of inelastic electron scattering and of electronucleon and electropion production are parametrized by analytic models of the major reaction mechanisms. Predictive FORTRAN codes for the yields of reaction products have been developed for all nuclei intera…
Rubber compounding: principles, materials, and techniques , Rubber compounding: principles, materials, and techniques , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی
The effect of the nickel content on the pitting resistance of AISI(1) 304 stainless steel (SS) and Alloys 800 and 600 in chloride-thiosulfate solutions was investigated using two techniques, scratching and slow-stepped potentiostatic polarization. Adverse effects of nickel were seen at both low and high thiosulfate co…
The interdiffusion of Cu and Si was studied using ion scattering spectrometry (ISS) and x-ray photoelectron spectroscopy (XPS). The samples were prepared in very high vacuum (VHV) by evaporating Cu onto Ar+-cleaned and -annealed Si(111) surfaces. The surfaces were transferred directly from VHV to UHV and analyzed by I…
Stresses in oxide scale–metal systems can lead to decohesion of the scales when critical values are exceeded, which manifests itself in stable growth of interfacial cracks and separation along the scale/metal interface or in sudden spalling of the scale or of parts of it as a result of unstable cracking processes. The…