Materials Literature
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Abstract In the subambient thermal volatilization analysis (TVA) technique, degradation products initially at −196°C are allowed to warm up to ambient temperature in a controlled manner under vacuum conditions, and volatilization from the sample tube to a trap at −196°C is monitored by means of a Pirani gauge. The tec…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA nucleophilic acetaldehyde equivalent. Preparation and synthetic applications of cis-2-ethoxyvinyllithiumRobert H. Wollenberg, Kim F. Albizati, and Rohan PeriesCite this: J. Am. Chem. Soc. 1977, 99, 22, 7365–7367Publication Date (Print):October 1, 1977Publication History Pu…
Escherichia coli cells prepared for transformation by treatment with cold 0.1 M CaCl2 remained viable and competent after storage at -82 degrees C in 15% glycerol; thawed-cell samples yielded up to 10(6) transformants per microgram of plasmid deoxyribonucleic acid.
Switching and oscillation were found in SnO2-VOx-PdO ceramics. This switching does not appear above 60°C. However, under 40°C, it comprises two switching actions and depends upon the ambient temperature. The oscillation is irregular and the amplitude is as great as 30−40 V at room temperature.
The dielectric behavior of triglycine sulphate has been investigated near the phase-transition temperature for varying thicknesses of the crystal. Measurements have been carried out at a frequency of 1 kHz. The results indicate that the dielectric constant of triglycine sulphate does not go to infinity at the transiti…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis and studies of trimethylamine adducts with tin(II) halidesC. C. Hsu and R. A. GeanangelCite this: Inorg. Chem. 1977, 16, 10, 2529–2534Publication Date (Print):October 1, 1977Publication History Published online1 May 2002Published inissue 1 October 1977https://pubs.…
An octahedral multi-anvil apparatus has been developed for the study of X-ray diffraction under high pressure. High pressures up to 150 kbar can be generated in the centre of split cones when they move together as external load is applied upon the outer surfaces. The X-ray beam is focused to the specimen through a hor…
A polymethyl methacrylate insulator rod in vacuum is stressed by high-voltage pulses having 3-ns rise times, with the result that 40-mm-long incomplete discharges occur at the end of the rod. Time-resolved measurements of electron emission from different areas on the insulator surface indicate that a discharge propaga…
The photoelectron spectra of PbCl 2 , PbBr 2 and SnCl 2 , which have the lead chloride-type crystal structure, have been measured with X-rays and extreme ultraviolet rays in order to investigate the electronic structures of their valence bands. The photoelectron spectra of TlCl and Pbl 2 have also been measured for co…
The dielectric properties of polydimethylsiloxane fluids have been investigated under dc and ac fields as a function of field, frequency, temperature, and water content. The results of the ac studies have shown that the dielectric constant and dielectric loss of the fluid exhibit several transitions as a function of t…
A scaling theory is proposed for solids under hydrostatic pressures which do not undergo structural phase transitions or symmetry distortions or for which distortions may be neglected. The theory is tested with two adjustable parameters by computing the linear frequency shifts (dν/dP) for the optical transitions 4A2(F…
A development of a conic fitting procedure is described which enables the X-ray source point in Kossel diffraction to be determined solely by analysis of shadows cast on the recording film and so dispenses, in subsequent analysis of the pattern, with the need to have prior knowledge of the crystal structure of the spe…
NRC publication: Yes
There is an ever increasing interest in studying electrical conduction and polarization phenomena in polymers. This is partly due to the increasing application of plastics in the electric and electronic industry, partly to the close connection between electric, magnetic and mechanical relaxation phenomena. It is becom…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTUnusual electron-transfer processes involving electron-rich and electron-deficient metallocenesJohn D. L. Holloway, William L. Bowden, and William E. Geiger Jr.Cite this: J. Am. Chem. Soc. 1977, 99, 21, 7089–7090Publication Date (Print):October 1, 1977Publication History Pub…
Abstract The electronic band structure of systems with screw symmetry is developed using the smallest screw displacement as elementary operation. For atomic and molecular helical systems the resulting Hartree‐Fock SCF‐LCAO formulae are presented. Results for ferroelectric HC1 and HP are reported, obtained with the MUN…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNitrosylmetalloporphyrins. 4. Molecular stereochemistry of two crystalline forms of nitrosyl-.alpha.,.beta.,.gamma.,.delta.-tetraphenylporphinato(4-methylpiperidine)iron(II). A structural correlation with .nu.(NO)W. Robert Scheidt, A. Chris Brinegar, E. B. Ferro, and John F.…
Machine learning (ML) is transforming all areas of science. The complex and time-consuming calculations in molecular simulations are particularly suitable for an ML revolution and have already been profoundly affected by the application of existing ML ...Read More
The results of the published work on the high pressure-high temperature properties of the AB-type compounds have been compiled and evaluated. All pressure studies above the range of 1 kilobar have been included with an emphasis on the accurate characterization of the solid-solid phase boundaries and the experimental m…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure of a very small piece of silver metal. The octahedral silver (Ag6) molecule. Two crystal structures of partially decomposed vacuum-dehydrated fully silver(1+) ion-exchanged zeolite AYang Kim and Karl SeffCite this: J. Am. Chem. Soc. 1977, 99, 21, 7055–7057Publicati…