Materials Literature
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Intergranular embrittlement due to grain boundary segregation of phosphorus is recognized as one of the potential degradation factors in irradiated reactor low alloy steels at high neutron fluence. In this study, low alloy steels thermally aged at 400-500°C were investigated to evaluate the correlation between phospho…
Langmuir films of members of two homologous series, the 4‐n‐alkyl‐4′‐cyanobiphenyls (nCB) for n = 2–14 and trans‐4‐n‐alkyl(4′‐cyanophenyl)cyclohexanes (PCHn) for n = 2–12, have been studied by recording surface pressure/area isotherms and by Brewster angle microscopy. It has been found that the compounds with very sho…
The dissolution of deposited, protective iron carbonate films in oil and gas transportation pipelines may drastically enhance corrosive processes on steel surfaces, and thus, seriously affect the longevity of the equipment in use. An investigation had been carried out to get a better understanding of the kinetics and…
Acidification of tetrakis(4-hydroxyphenyl)porphyrin (THPP) and tetrakis(3,5-dihydroxyphenyl)porphyrin (OHPP) in dichloromethane solutions has been investigated as a function of the nature of the counteranion. These porphyrins exhibit different patterns of behavior, and extended aggregates are formed displaying broad e…
The self-assembly of supramolcular clusters of Gd(III) hydroxypyridinone complexes, templated by an Fe(III) terephthalamide center, is presented. The peripheral Gd(III) ions are each coordinated by two water molecules which exchange rapidly with the bulk solvent. These properties, along with the high rigidity of the s…
A poly-β-hydroxybutyrate (PHB) accumulating, Gram positive Bacillus thuringiensis R1 was isolated from the soil samples. The growth of the organism and PHB accumulation in the presence of different carbon sources was studied. While maximum dry cell mass accumulation (3.90 to 4.11g/L) resulted in the presence of glycer…
We investigate the temperature dependence of conduction in size-controlled silicon nanocrystals. The nanocrystals are ∼8nm in diameter, covered by ∼1.5nm thick SiO2 shells. In 300nm thick films for temperatures T from 30to200K, the conductivity σ follows a ln(σ) vs 1∕T1∕2 dependence. This may be associated with either…
A novel approach is presented to improve the dispersion of oxidized single-walled carbon nanotubes (SWNTs) in a copolymer matrix by tuning hydrogen-bonding interactions to enhance dispersion. Nanocomposites of single-walled carbon nanotubes and copolymers of styrene and vinyl phenol (PSVPh) with varying vinyl phenol c…
Cubic pyrochlore (Bi1.5Zn0.5)(Zn0.5−x∕3TixNb1.5−2x∕3)O7 ceramics with 0⩽x⩽1.5 were synthesized and investigated between 100Hz and 100THz by means of broadband dielectric spectroscopy, time-domain terahertz transmission spectroscopy, Fourier transform infrared reflectivity spectroscopy and Raman scattering. Bi1.5ZnNb1.…
We have calculated the electric field enhancement factor for a metallic cylinder with a hemispherical end-cap in a plane capacitor geometry paying particular attention to the dependence of the field enhancement factor on the anode distance. In addition, we have investigated the angular dependence of the local field at…
Abstract The specific impact of low molecular weight organic gels on polymer crystallisation is examined. Conventional nucleating agents (NA) influence the polyolefins crystallisation and improve their mechanical properties, via an epitaxial mechanism. In the particular case where the pair NA/polymer form a gel at int…
Abstract Band structure models are proposed to help understand carrier‐induced ferromagnetism in diluted magnetic semiconductors. We describe both hole‐ and electron‐mediated ferromagnetism. For hole‐mediated ferromagnetism, we show that there are two distinct mechanisms related to the stabilization of ferromagnetism.…
Abstract This article describes some of the exciting results obtained during the study of the gelation behavior of bile acid derivatives in the authors laboratory. The serendipitous discovery of charge‐transfer interaction promoted gelation of organic solvents by (steroid)pyrene derivatives/TNF is presented. In this c…
ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionORIGINAL ARTICLEThis notice is a correctionBioinspired Surfaces with Special WettabilityTaolei Sun, Lin Feng, Xuefeng Gao, and Lei JiangCite this: Acc. Chem. Res. 2006, 39, 7, 487Publication Date (Web):July 18, 2006Publication History Published online18 July 2006Publ…
Microcracking behaviour in the gas tungsten arc multipass weld metal of alloy 690 was investigated. The majority of microcracks occurred within about 300 μm from the fusion line of the subsequent weld bead and propagated along the solidification boundaries in the multipass weld metal. The morphology of the crack surfa…
Rubbers are high molecular weight polymeric materials, which possess very low interchain attraction, low glass transition temperature and predominantly amorphous nature with low green strength. Fillers like carbon black and silica are frequently added to rubbers in order to improve the mechanical properties of the com…
ZnO nanorod arrays fabricated on ZnO buffer layers on Si wafers were grown using a low-temperature solution method and were characterized by various techniques. Buffer layers were prepared using metal organic chemical vapor deposition and a sputter-oxidation method. Aligned ZnO nanorods were deposited at 90°C on the s…
An experimental study on smectite dissolution was carried out using in-situ TMAFM and CMAFM (tapping mode and contact mode atomic force microscopy, respectively) analyses at 25 °C under alkaline conditions. Smectite particles dissolved via the retreat of the edge surfaces without scratching by the AFM tip, except in a…
The role of self-trapping and defect trapping of hydrogen and helium implanted into tungsten has been investigated using density functional theory (DFT) calculations, molecular dynamics simulations, and kinetic Monte Carlo simulations (KMCSs). The potential energy curves of hydrogen or helium pairs were obtained by mo…
The structural behavior of a cancrinite, Na 5.96 Ca 1.52 [Al 6 Si 6 O 24 ](CO 3 ) 1.57 ·1.75H 2 O, was determined by using in situ synchrotron X-ray powder diffraction data [λ = 0.91806(5) Å] at room pressure and from 25 to 982 °C. The sample was heated at a rate of about 9.5 °C/min, and X-ray traces were collected at…