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Natural Products as a Source of Environmentally Friendly Corrosion Inhibitors: The Case of Gum Exudate from Acacia seyal var. seyal

Joseph Buchweishaija、GS Mhinzi2007-01-01Portugaliae electrochimica acta

The inhibitive effect of the gum exudate from Acacia seyal var. seyal on the corrosion of mild steel in drinking water was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. The results obtained show that gum exudates could serve as effective inhibitors for the…

Corrosion Behavior and InhibitionNanocomposite Films for Food PackagingPolymer composites and self-healing

Enhanced Fowler-Nordheim tunneling effect in nanocrystallite Si based LED with interfacial Si nano-pyramids

Gong‐Ru Lin、Chun‐Jung Lin、Chi-Kuan Lin2007-01-01Optics Express

The premier observation on the enhanced light emission from such a metal-SiO(x)-Si light emitting diode (MOSLED) with Si nano-pyramids at SiO(x)/Si interface is demonstrated at low biases. The Si nano-pyramids exhibits capability in providing the roughness of the SiO(x)/Si interface, and improving the Fowler-Nordheim…

Semiconductor materials and devicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

The effect of surface active solutes on bubbles in an acoustic field

Muthupandian Ashokkumar、Franz Grieser2007-01-01Physical Chemistry Chemical Physics

The interaction between gas bubbles and ultrasound in water leads to acoustic cavitation under specific experimental conditions. Acoustic cavitation has been used in a number of areas, these include therapeutic applications, contrast imaging, synthesis of nanomaterials, production of nanoemulsions, treatment of food m…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaHydrogen's biological and therapeutic effects

A pulsed electron gun for ultrafast electron diffraction at surfaces

A. Janzen、B. Krenzer、O. Heinz 等 9 位作者2007-01-01Review of Scientific Instruments

The construction of a pulsed electron gun for ultrafast reflection high-energy electron diffraction experiments at surfaces is reported. Special emphasis is placed on the characterization of the electron source: a photocathode, consisting of a 10 nm thin Au film deposited onto a sapphire substrate. Electron pulses are…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

Stepwise interfacial self-assembly of nanoparticles via specific DNA pairing

Bo Wang、Miao Wang、Hao‐Li Zhang 等 10 位作者2007-01-01Physical Chemistry Chemical Physics

In the present work, we succeeded in alternatively depositing inorganic nanoparticles and functionalized DNA bases onto the water/oil interface from the water and oil bulk phases. The ligands used were functional thymines and adenines. Their thiol and phosphate groups were used to cap inorganic nanoparticles and their…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesPolymer Surface Interaction Studies

Synthesis of carboxylic group functionalized mesoporous silicas (CFMSs) with various structures

Lu Han、Yasuhiro Sakamoto、Osamu Terasaki 等 5 位作者2007-01-01Journal of Materials Chemistry

Carboxylic group functionalized mesoporous silicas (CFMSs) were successfully synthesized by using cationic surfactants as templates and carboxyethylsilanetriol sodium salt (CES) as a co-structure directing agent (CSDA). Well ordered two-dimensional (2D) p6mm, cubic Fmm, intergrowth of Fmm and P63/mmc, and cubic Fdm wi…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Effects of the Solvent Concentration (Solid Loading) on the Processing and Properties of the Composite Electrode

E. Ligneel、Bernard Lestriez、A. Hudhomme 等 4 位作者2007-01-01Journal of The Electrochemical Society

For various composite electrodes with the same composition 80( % , % CB, % PMMA)-20(EC-PC), and made by the solvent casting technique, the cycled capacity varies between 100 and depending on the initial volatile solvent concentration. For a concentration below the optimal one, the electrode dispersion exhibits a yield…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsElectrowetting and Microfluidic Technologies

Eco-friendly Inhibitors from Naturally Occurring Exudate Gums for Aluminium Corrosion Inhibition in Acidic Medium

Savıour A. Umoren、I.B. Obot、Eno E. Ebenso 等 4 位作者2007-01-01Portugaliae electrochimica acta

Exudates gums from Pachylobus edulis (PE) and Raphia hookeri (RH) were evaluated as corrosion inhibitors for aluminium in HCl using weight loss and thermometric measurements at 30 -60 o C. The exudates were found to retard corrosion rate of aluminium. The inhibition efficiency (%1) increased with increase in concentra…

Corrosion Behavior and InhibitionMaterial Properties and Applications

Photoinduced energy and electron transfer in 1,8-naphthalimide–corrole dyads

Mariusz Tasior、Daniel T. Gryko、Marek Cembor 等 6 位作者2007-01-01New Journal of Chemistry

A series of corrole-1,8-naphthalimide dyads has been synthesized. The dyads were assembled in a convergent fashion from two fragments via a corrole forming reaction. Central to the success of the synthetic strategy was the preparation of suitably functionalized derivatives of naphthalene-1,8-carboxymide. Six different…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesSurface Chemistry and Catalysis

Carbon nanotubes and their toxicity

Amit Jain、Neelesh Kumar Mehra、Neeraj Lodhi 等 7 位作者2007-01-01Nanotoxicology

The vital need of studying the toxicological profile of carbon nanotubes (CNTs) has emerged from the rapidly enhancing utility of CNTs in the field of nanobiology and drug delivery. This review highlights the vivid aspect of CNTs’ toxicity comprising of in-vitro to in-vivo toxicological profile vis-à-vis the various p…

Carbon Nanotubes in CompositesNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Dielectric properties of short sisal/coir hybrid fibre reinforced natural rubber composites

A. P. Haseena、G. Unnikrishnan、G. Kalaprasad2007-01-01Composite Interfaces

The dielectric properties, such as dielectric constant, volume resistivity and dielectric loss factor, of sisal/coir hybrid fibre reinforced natural rubber composites have been studied as a function of fibre loading, fibre ratio, frequency, chemical modification of fibres and the presence of a bonding agent. The diele…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesDielectric materials and actuators

Initial Stages of the HCl-Induced High-Temperature Corrosion of Alloy 310

Nicklas Folkeson、L.-G. Johansson、Jan‐Erik Svensson2007-01-01Journal of The Electrochemical Society

Polished 310 stainless steel coupons were exposed isothermally in a horizontal tube furnace at 500 ° C for 1 – 168 h . The exposure gas consisted of N 2 with 5% O 2 and 500 ppm HCl(g). The corroded samples were analyzed by X-ray diffraction, focused ion beam microanalysis, scanning electron microscopy with energy-disp…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMolten salt chemistry and electrochemical processes

Orientated assembly of single-walled carbon nanotubes and applications

Limin Huang、Zhang Jia、Stephen O’Brien2007-01-01Journal of Materials Chemistry

Single-walled carbon nanotubes (SWNTs) have unique structural, mechanical, thermal and electrical properties, which make them attractive and important building blocks for nanotechnology. Orientated assembly of SWNTs presents a crucial prerequisite for both fundamental research at the individual SWNT level and nanotube…

Carbon Nanotubes in CompositesGraphene research and applicationsNanowire Synthesis and Applications

Comparison Between E-beam and Ultraviolet Curing to Perform Porous a-SiOC:H

V. Jousseaume、A. Zenasni、L. Favennec 等 7 位作者2007-01-01Journal of The Electrochemical Society

Porous ultralow- k films are required by the microelectronics industry as interlayer dielectrics for technologies and below. These porous insulating films can be deposited by plasma-enhanced chemical vapor deposition using a porogen approach. It consists of the codeposition of a matrix precursor and a sacrificial orga…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Thermal conduction from microcantilever heaters in partial vacuum

Jungchul Lee、Tanya L. Wright、Mark R. Abel 等 7 位作者2007-01-01Journal of Applied Physics

This paper reports the thermal and electrical characteristics of a heated microcantilever in air and helium over a wide range of pressures. The cantilever heater size modulates thermal conductance between the cantilever and its gaseous surroundings; and the Knudsen number, Kn characterizes this thermal conductance. Wh…

Heat Transfer and OptimizationThermal properties of materialsThermal Radiation and Cooling Technologies

A series of nickel phosphonate–carboxylate cages

B. Breeze、Muralidharan Shanmugam、Floriana Tuna 等 4 位作者2007-01-01Chemical Communications

Three new polymetallic nickel(II) phosphonate complexes are reported; in one cage the twelve nickel centres are arranged at the vertices of a truncated tetrahedron in a similar manner to a Keggin ion.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Rechargeable Organic Radical Battery with Electrospun, Fibrous Membrane-Based Polymer Electrolyte

Jae‐Kwang Kim、Gouri Cheruvally、Jaewon Choi 等 6 位作者2007-01-01Journal of The Electrochemical Society

An organic radical battery (ORB) operating at room temperature with lithium metal anode and radical polymer poly(2,2,6,6-tetramethylpiperidinyloxy-4-ylmethacrylate) (PTMA) cathode with a microporous polymer electrolyte based on electrospun poly(vinylidene fluoride- co -hexafluoropropylene) membrane has been demonstrat…

Advanced Battery Materials and TechnologiesConducting polymers and applicationsAdvanced battery technologies research

Direct fabrication of single-walled carbon nanotube macro-films on flexible substrates

Hongwei Zhu、Bingqing Wei2007-01-01Chemical Communications

We employed a floating chemical vapor deposition technique and applied a liquid (solution)-free precursor system for the fabrication of single-walled carbon nanotube macro-films on various flexible substrates from metallic foils to polymer films.

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

Decay of natural stones caused by fire damage

J. Sippel、Siegfried Siegesmund、T. Weiss 等 5 位作者2007-01-01Geological Society London Special Publications

Abstract Almost every representative ancient building suffered from a fire during its history. Therefore, several limestones, sandstones, a gypsum, granites, tuffs, an orthogneiss and two marbles have been tested to analyse the effect of fire. Thermal expansion measurements up to 1000 °C reveal that every rock shows a…

Building materials and conservationClay minerals and soil interactionsGrouting, Rheology, and Soil Mechanics

Luminescence Properties of (Sr[sub 1−u]Ba[sub u])Si[sub 2]O[sub 2]N[sub 2]:Eu[sup 2+], Yellow or Orange Phosphors for White LEDs, Synthesized with (Sr[sub 1−u]Ba[sub u])[sub 2]SiO[sub 4]:Eu[sup 2+] as a Precursor

Bong-Goo Yun、Yoshinobu Miyamoto、Hajime Yamamoto2007-01-01Journal of The Electrochemical Society

Luminescence properties and formation process of , phosphors suitable for white light-emmitting (LEDs), were investigated. These phosphors were synthesized by a method using as a precursor instead of simple oxides. Compared with a conventional solid-state reaction method, this method provides increased luminescence ef…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsGlass properties and applications