Materials Literature
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A trisilanol derivative of polyhedral oligomeric silsesquioxane (POSS), trisilanolisobutyl-POSS, has recently been reported to form stable monolayers at the air/water interface. This paper explores the mono- and multilayer properties of another POSS derivative, trisilanolcyclohexyl-POSS, with pi-A isotherm and Brewste…
In the title compound, [Cd(C12H8F2N3)2(C5H5N)2], the Cd atom lies on a crystallographic twofold axis in space group Iba2. The coordination geometry about the Cd(II) ion corresponds to a rhombically distorted octahedron, with two deprotonated 1,3-bis(2-fluorophenyl)triazenide ions, viz. FC6H4NNNC6H4F-, acting as bident…
Reactions between the Os(VI)-nitrido salts (e.g., trans-[Os(VI)(tpy)(Cl)(2)(N)]PF(6) (tpy = 2,2':6',2"-terpyridine), cis-[Os(VI)(tpy)(Cl)(2)(N)]PF(6), and fac-[Os(VI)(tpm)(Cl)(2)(N)]PF(6) (tpm = tris(pyrazol-1-yl)methane)) and the hydroxylamines (e.g., H(2)NOH and MeHNOH) and the methoxylamines (e.g., H(2)NOMe and MeH…
Alumina-supported vanadium particles were prepared under ultrahigh vacuum (UHV) conditions and characterized with respect to their structural and CO adsorption properties. As supporting oxide, we used a thin, well-ordered alumina film grown on NiAl(110). This allows the application of scanning tunneling microscopy (ST…
Lu 1.98 Ln 0.02 O 3 (Ln = Nd, Eu, and Er) powders obtained by propellant synthesis were characterized using XRD, SAXS, TEM, and SEM. Samples have a very porous, open morphology with fractal scaling properties. The building blocks of the fractal aggregates are 60−90 nm lanthanide-doped cubic Lu 2 O 3 crystalline partic…
Nanoscale, high surface area cerium oxide (ceria) powders and stable, high-concentration (>1 M) ceria sols were prepared by a new method based on homogeneous precipitation in an acidic environment using cerium(IV) nitrate as the precursor. The results are compared with ceria powders and sols prepared by a hydrothermal…
Protein folding is a central problem in the biological sciences. To generate residue-specific information on the equilibrium folding of cytochrome c, we have semisynthesized the protein with specifically deuterated residues. The C-D bonds may be easily visualized in an otherwise transparent region of the IR spectra, e…
A room-temperature EPR (electron paramagnetic resonance) study on the charring (under He flow) and char transformation (by air) of pectin, cellulose, and tobacco is reported. The EPR intensities of pectin and tobacco chars (with charring temperatures from 250 °C to 600 °C) first increase rapidly and then decrease slow…
Nanorods of MoO 3 are accessible in gram quantities from MoO 3 ·2H 2 O via a flexible one-step solvothermal reaction. Several hours of treatment in water at 180 °C are sufficient to convert the starting material quantitatively into rods with diameters around 100 nm and microscale lengths. The formation of MoO 3 rods p…
We present measurements of the optical spectra on single crystals of spinel-type compound \cis. This material undergoes a sharp metal-insulator transition at 230 K. Upon entering the insulating state, the optical conductivity shows an abrupt spectral weight transfer and an optical excitation gap opens. In the metallic…
We study transport properties of a two-dimensional electron system with Rashba spin-orbit coupling in a perpendicular magnetic field. The spin orbit coupling competes with Zeeman splitting to introduce additional degeneracies between different Landau levels at certain magnetic fields. This degeneracy, if occuring at t…
Polymorph selectivity has been achieved during crystallization of anthranilic acid (AA) and 5-methyl-2-[(2-nitrophyenyl)amino]-3-thiophenecarbonitrile (ROY), both considered benchmarks of polymorphic behavior, within nanoporous glass beads and polymer monoliths. Whereas polymorph III of AA crystallizes from the melt o…
Ag-TiO(2) films exhibiting multicolor photochromism were prepared by photoelectrochemical reduction of Ag(+) to Ag nanoparticles in nanoporous TiO(2) films under UV light. Color of the Ag-TiO(2) film, initially brownish-gray, changes under a colored visible light to the color of the light and reverts to brownish-gray…
We have introduced a method to identify functional shifts in protein families. Our method is based on the calculation of an active-site conservation ratio, which we call the "ASC ratio." For a structurally based alignment of a protein family, this ratio is the average sequence similarity of the active-site region comp…
Liming is an effective method of correcting soil acidity, but the cost and other factors, such as sub-soil acidity, topography, and nutrient availability may limit its benefits. An alternative option is to grow acid tolerant plants. Pot experiments are an effective way of identifying plants with the genetic potential…
Abstract Hydrogel coatings of monoacrylated poly(ethylene glycol) (PEG) methyl ethers of different molecular weights were attached to silicon rubber surfaces and crosslinked with hexanediol diacrylate or ethoxylated trimethylolpropane diacrylate by UV polymerization. The wetting, evaluated with the water contact angle…
We study equilibrium and nonequilibrium properties of a simple "generic embedded-atom model" (GEAM) for metals. The model allows to derive simple analytical expressions for several zero-temperature constitutive properties--in overall agreement with real metals. The model metal is then subjected to shear deformation an…
A very mild method for the preparation of various 2‐diazo‐1,3‐carbonyl compounds in the presence of environmentally attractive solid acids such as clays in a heterogeneous manner in moderate to good yield is reported.
We investigated the phenomenon of photoinduced nematic-isotropic (N-I) transition for different concentrations of a long-chain alkane, viz., octadecane (OD), and a host liquid crystalline material having a small quantity (4.5 mol %) of a photoactive azo compound. As expected, the N-I transition temperature diminishes…
We discuss how the curvature of a substrate influences wetting by a nematic liquid crystal concentrating on the surface of a spherical particle. Our investigation is based on Landau-de Gennes free energy formulated in terms of second-rank nematic order parameter Q(ij). We review the method to treat wetting transitions…