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Notes. A planar, binucleating, pyrazole derivative ligand. Crystal structure of bis[µ-3,5-bis(2′-pyridyl)pyrazolato-N 1 N′:N 2 N″]-bis[dimethanolnickel( II )] dichloride dihydrate

Jaume Casabó、Josefina Pons、K. S. Siddiqi 等 6 位作者1989-01-01Journal of the Chemical Society Dalton Transactions

The co-ordinating properties of the ligand 3,5-bis(2-pyridyl)pyrazole (Hbpypz) are reported and complexes of general formulae [M(bpypz)]NO3·xH2O (M = CoII, NiII, CuII, ZnII, or CdII), [M(bpypz)] Cl·xH2O (M = MnII, CoII, NiII, or ZnII), and [M(bpypz)]Br·xH2O (M = CoII NiII or ZnII) are described. The crystal and molecu…

Metal complexes synthesis and propertiesMagnetism in coordination complexesSynthesis and Characterization of Heterocyclic Compounds

Improving adhesion of wood fiber with polystyrene by the chemical treatment of fiber with a coupling agent and the influence on the mechanical properties of composites

D. Maldas、B. V. Kokta1989-01-01Journal of Adhesion Science and Technology

—The mechanical properties of polystyrene filled with chemithermomechanical pulp and wood residues of softwood and hardwood species, which were precoated with phthalic anhydride and various polymers, e.g. polystyrene and PVC, have been investigated. The extent of improvement in the mechanical properties of the composi…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesInnovations in Concrete and Construction Materials

Computer Calculation of Water-Clay Interactions Using Atomic Pair Potentials

Neal T. Skipper1989-01-01Clay Minerals

A B S T RA C T : Existing data on interatomic potentials have been used to study the interactions between an uncharged clay sheet and a water molecule. Calculations show that most of the clay surface is relatively hydrophobic, with binding energies for a water molecule in the range 1-0-4.5 kcal mo1-1 . There is, howev…

Geological and Geochemical AnalysisSoil and Unsaturated FlowClay minerals and soil interactions

Calcium and Sulfate Retention by Two Oxisols of the Brazilian Cerrado

E. Marcano‐Martinez、Murray B. McBride1989-01-01Soil Science Society of America Journal

Abstract The ability of two representative oxisols from the Cerrado region of Brazil to adsorb Ca 2+ and SO 2‐ 4 , when in their natural acidic state, was determined by using dissolved CaCl 2 , K 2 SO 4 and CaSO 4 salts as adsorbates. Calcium adsorption from CaCl 2 and CaSO 4 was nearly linearly dependent on the equil…

Soil and Unsaturated FlowClay minerals and soil interactionsMine drainage and remediation techniques

One-Dimensional Transient Fluid Model for Fuel/Coolant Interaction Analysis

C. Chu、Michael L. Corradini1989-01-01Nuclear Science and Engineering

A fuel/coolant interaction (FCI) is a phenomenon that may occur during a light water reactor severe accident when molten fuel comes into contact with residual water in-vessel or in the reactor containment. A new one-dimensional multifluid transient model, which currently has the capability of examining nonexplosive FC…

Nuclear Materials and PropertiesCombustion and Detonation ProcessesNuclear Engineering Thermal-Hydraulics

Calcification in echinoderms

Philippe Dúbois、C.P. Chen、Michel Jangoux 等 4 位作者1989-01-01Dépôt institutionnel de l'Université libre de Bruxelles (Université Libre de Bruxelles)

info:eu-repo/semantics/published

Marine Bivalve and Aquaculture StudiesCalcium Carbonate Crystallization and InhibitionEchinoderm biology and ecology

Effect of chemical treatment of fibers on the mechanical properties of polyethylene-wood fiber composites

Rishi Raj、B. V. Kokta、Claude Daneault1989-01-01Journal of Adhesion Science and Technology

—Linear low-density polyethylene (LLDPE) was reinforced with chemithermomechanical (CTMP) aspen fiber, wood flour, and cellulose flour. Wood fibers were treated with isocyanate or a vinylsilane coupling agent to improve the adhesion between the fiber and polymer. Composites were made at different weight percentages of…

Natural Fiber Reinforced Composites

Fracture Mechanics: Perspectives and Directions (Twentieth Symposium)

RP Wei、RP Gangloff1989-01-01OpenAlex

Description Provides overviews of the major developments in fracture mechanics and associated applications over the past 20 years, and highlights directions for future developments and applications. 6 major sections include: • Analytical Fracture Mechanics • Nonlinear and Time Dependent Fracture Mechanics • Microstruc…

High-Velocity Impact and Material Behavior

Environmental Aspects of Stabilization and Solidification of Hazardous and Radioactive Wastes

Paul J. Côté、M Gilliam1989-01-01OpenAlex

Description STP 1033 provides a unique perspective on stabilization and solidification research as performed by the hazardous and radioactive waste communities. These papers are grouped into 4 sections: Processes; Regulatory Aspects and Testing Methods; Laboratory Evaluation; and Large Scale Evaluation or Demonstratio…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Infrared study of the thermal decomposition of heteropolyacids of the series H3+xPMo12–xVxO40

A. Bielański、A. Małecka、Ludmila Kybelkova1989-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

F.t.i.r. spectroscopy has been used for the study of dehydration of heteropolyacids (HPA) of the series H3+xPMo12–xVxO40 carried out in vacuo at 298–673 K and also for the study of ammonia sorption on the same samples. Pumping at room temperature results in the departure of water of crystallization; the protons, which…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsPigment Synthesis and Properties

Nickel Complexes Containing Sterically Demanding Thiolate Ligands: [Ni8S(SC4H9)9]⊖, a Mixed‐Valence Nickel Sulfide Thiolate Cluster, and [Ni4(SC3H7)8], a Homoleptic Nickel Thiolate

Thomas Krüger、Bernt Krebs、Gerald Henkel1989-01-01Angewandte Chemie International Edition in English

A sulfide ion at the center of an Ni6 prism capped by two additional Ni atoms, and the presence of nine μ2-StBu bridges are the characteristic features of the structure of 1. The mean oxidation state for nickel in diamagnetic 1 is + 1.25. The anion 1 is the first pure nickel–sulfur complex with nickel in an unusual ox…

Metal complexes synthesis and propertiesNanocluster Synthesis and ApplicationsInorganic Chemistry and Materials

Mechanism of Grain Orientation During Hot‐Pressing of Bismuth Titanate

Toshio Kimura、Takeshi Yoshimoto、Nobuyoshi Iida 等 5 位作者1989-01-01Journal of the American Ceramic Society

Grain‐oriented Bi 4 Ti 3 O 12 ceramics have been prepared by hot‐pressing. Platelike grains align during hot‐pressing; the long‐axis direction perpendicular to the crystal c axis is oriented perpendicular to the pressing direction. The effects of hotpressing conditions such as temperature, pressure, time, and type of…

Advanced ceramic materials synthesisAdvanced materials and compositesPowder Metallurgy Techniques and Materials

Reactions of heteropolyanions in non-polar solvents. Part 3. Activation of dioxygen by manganese(II) centres in polytungstates. Oxidation of hindered phenols

Dimitris E. Katsoulis、Michael T. Pope1989-01-01Journal of the Chemical Society Dalton Transactions

The heteropolyanions [XW11O39{MnII(OH2)}]n–[X = P(1), Si (2), Ge (3), or B (4)] and α2-[P2W17O61{MnII(OH2)}]8–(5) have been transferred into non-polar solvents (benzene, toluene) with the aid of tetraheptylammonium bromide or other phase-transfer agents. Following dehydration of their non-polar solutions, anions (2) a…

Polyoxometalates: Synthesis and ApplicationsOxidative Organic Chemistry ReactionsVanadium and Halogenation Chemistry

Characterization of the mixed perovskite BaSn1–xSbxO3 by electrolyte electroreflectance, diffuse reflectance, and X-ray photoelectron spectroscopy

Gerardo Larramona、Claudio Gutiérrez、M.I. da Silva Pereira 等 5 位作者1989-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The band gap of the mixed perovskite BaSn1–xSbxO3 has been reported to be 134 kJ mol–1(J-M. Hermann, M. R. Nunes and F. M. A. da Costa, J. Chem. Soc., Faraday Trans. I, 1982, 78, 1983), corresponding to 1.4 eV, which is the optimum value for solar-energy conversion. In order to confirm this value, pressed discs of the…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Microstructure and Corrosion Studies for Optimized PWR and BWR Zircaloy Cladding

F. Garzarolli、E Steinberg、H.G. Weidinger1989-01-01OpenAlex

The increased discharge burnups envisaged today require an optimization of the Zircaloy cladding properties with regard to corrosion with different strategies for optimizing the corrosion for boiling water reactor (BWR) and pressure water reactor (PWR) applications. A broad laboratory study showed that the influence o…

Fusion materials and technologiesNuclear Materials and PropertiesNuclear and radioactivity studies

Spatial and temporal trends of diatom flux in British Columbian fjords

Constance Sancetta1989-01-01Journal of Plankton Research

The monthly flux of diatom taxa at four sites in two fjords of British Columbia, Canada, was determined over a 3-year period by particle interceptor traps. Saanich Inlet is a small basin with little horizontal density gradient while Jervis Inlet experiences seasonal runoff and strong vertical stratification. The basic…

Marine and coastal ecosystemsDiatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Al-doped Nd-Fe-B permanent magnets: wetting and microstructural investigations

K.G. Knoch、Gerhard Schneider、J. Fidler 等 5 位作者1989-01-01IEEE Transactions on Magnetics

The coercivity of Nd-Fe-B sintered magnets has been improved by Al additions. To study the microstructural effect of Al addition, two types of investigation were formed: (1) the change in the wetting behavior of the liquid phase, at the sintering temperature, was studied by measurements of the wetting angle; and (2) t…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Hot-working behavior of cast Pr-Fe-B magnets

Tatsuya Shimoda、K. Akioka、Osamu Kobayashi 等 7 位作者1989-01-01IEEE Transactions on Magnetics

The hot working is done at a low strain rate (hot pressing) and a high strain rate (hot rolling). Magnetic alignment induced by the hot working is found to be closely related to the microstructure of the cast ingots and the direction of principal stress. The appropriate structure is a columnar structure. The c-axis of…

Magnetic Properties and ApplicationsMagnetic Properties of AlloysSuperconducting Materials and Applications

Synthesis of Amorphous Boron Nitride by Pressure Pyrolysis of Borazine

Shin‐ichi Hirano、Toshinobu Yogo、Asada Satoshi 等 4 位作者1989-01-01Journal of the American Ceramic Society

Amorphous BN that contains hydrogen could be synthesized by pressure pyrolysis of borazine below 700°C at 100 MPa. The fraction of B and N bonded to H in the pyrolysis product could be controlled by changing the pressure pyrolysis condition. The pyrolysis product at 700°C and 100 MPa showed formation of B‐N‐B bonds of…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research