Materials Literature
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The coverage of vicinal, stepped surfaces with molecules is simulated with the help of a two-dimensional Ising model including local distortions and an Ehrlich-Schwoebel barrier term at the steps. An effective two-spin model is capable to describe the main properties of this distorted Ising model. It is employed to an…
A series of conjugated poly( p -phenylene carbazole) copolymers, poly( N -hexyl-3,6-carbazole- alt -2,5-bisdodecyloxyphenylene) [ P1 ], poly( N -ethylhexyl-3,6-carbazole- alt- 2,5-bisdodecyloxyphenylene) [ P2 ], and poly( N -dodecyl-3,6-carbazole- alt -2,5-bisdodecyloxyphenylene) [ P3 ] were prepared by using palladiu…
Gold nanostructured films of various thicknesses (15, 30, and 60 nm) are deposited over regular arrays of polystyrene nanospheres in an attempt to evaluate their potential as SERS-active substrates. Atomic force microscopy is used to topographically characterize the substrates as well as to ensure the thickness of the…
Diagnosing microbiologically influenced corrosion (MIC) after it has occurred requires a combination of microbiological, metallurgical, and chemical analyses. MIC investigations have typically attempted to 1) identify causative microorganisms in the bulk medium or associated with the corrosion products, 2) identify a…
Over the past few decades significant advances have been made in the development of nanopharmaceuticals (including phospholipid and polymer-based therapeutics) against cancer. There is still, however, room for improvement. Today, many researchers are focusing on the development of innovative approaches to selectively…
A comprehensive survey of high speed weld bead defects is presented with strong emphasis on the formation of humping and undercutting in autogenous and non-autogenous fusion welding processes. Blowhole and overlap weld defects are also discussed. Although experimental results from previous studies are informative, the…
In this paper, we develop accurate and scalable models for the magnetic inductance in bundles of single-walled carbon nanotubes, which have been proposed as a means to alleviate the increasingly critical resistance problems associated with traditional copper interconnect in very large scale integration (VLSI) applicat…
Multiferroic laminated composites of PbZr0.52Ti0.48O3(PZT)∕CoFe2O4(CFO)∕PbZr0.52Ti0.48O3 were prepared by conventional ceramic processing. The interdiffusion of the elements between different layers occurred, altering material properties. The dielectric behavior of such a sandwiched ceramic was dominated by the relati…
The Sr/Ca ratio of biogenic carbonate is widely used as a proxy for paleotemperature. This application is supported by empirical calibrations of Sr/Ca as a function of temperature, but it is also known that Sr uptake in calcite gauged by K d Sr = is affected by other variables, including bulk precipitation rate (K d S…
Highly aligned arrays of multiwalled carbon nanotube (MWCNT) on layered Si substrates have been synthesized by chemical vapor deposition (CVD). The effect of the substrate design and the process parameters on the growth mechanism were studied. Adding water vapor to the reaction gas mixture of hydrogen and ethylene enh…
We develop an athermal version of the shear-transformation-zone (STZ) theory of amorphous plasticity in materials where thermal activation of irreversible molecular rearrangements is negligible or nonexistent. In many respects, this theory has broader applicability and yet is simpler than its thermal predecessors. For…
Lithium aluminum silicate glass system (LAS) implanted with chromium ions is prepared. The reflectance and transmittance measurements are used to determine the dispersion of absorption coefficient. The optical data are explained in terms of the different oxidation states adopted by the chromium ions into the glass net…
This article focuses on a range of elements critical to this process; form the fundamental chemistry, through computational and measurement techniques to the solutions that are in use today. Degassing contributes greatly to the quality of power cables by improving the certainty in electrical testing and improving the…
The solid-solid interaction and thermal decomposition behavior of 2wt% Ag2O in ZnO powder have been investigated by using thermogravimetry analysis and differential thermal analysis. Ag2O, which remained stable in ZnO up to 200°C, was observed to be thermally decomposed to Ag+ ions in the temperature range of 200–250°…
A novel supramolecular electron donor-acceptor hybrid (1) has been designed through axial coordination of a perylenebisimide moiety [BPyPDI], bearing two 4-pyridyl substituents at the imido positions, to the ruthenium(II) metal centers of two phthalocyanines [Ru(CO)Pc]. This modular protocol enables access to electron…
A conventional optical superlens for imaging beyond the diffraction limit produces images only in the near-field zone of the superlens. In contrast, an optical far-field superlens (FSL) device has a remarkable transmission property that leads to a one-to-one relationship between the far-field and the near-field angula…
To compare the intrinsic thermoelectric (TE) properties of heavily Nb-doped TiO2 to those of heavily Nb-doped SrTiO3 [S. Ohta et al., Appl. Phys. Lett. 87, 092108 (2005)], the electrical conductivity (σ), carrier concentration (ne), Hall mobility (μHall), and Seebeck coefficient (S) of heavily Nb-doped TiO2 (anatase)…
We present a method for organizing metallic nanoparticles in solution that is based on the hydrophobic effect and does not require either hydrogen bonding or molecular recognition. When amphiphilic V-shaped molecules are attached to a gold cluster, an aggregation process ensues in aqueous solution and leads to the for…
Thrombosis is a major cause of poor patency in synthetic vascular grafts for small diameter vessel (< 6 mm) bypass. Arteries have a host of structural mechanisms by which they prevent triggering of platelet activation and the clotting cascade. Many of these are present in vascular endothelial cells. These mechanisms a…
Dendrimers have generated tremendous interest in the field of drug delivery. Despite indications of their utility as drug carriers, the inherent cytotoxicity associated with polycationic dendrimers acts as a limiting factor to their clinical applications. Many functionalization strategies have been adopted to mask per…