Materials Literature
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Gadolinium-based carbon nanostructures are poised to make a significant impact as advanced contrast agents (CAs) for magnetic resonance imaging (MRI) in medicine. This paper reviews and forecasts gadonanotubes as synthons for the design of high-performance MRI CA probes with efficacies up to 100 times greater than cur…
In the last two years we have witnessed the exciting experimental discovery of soft matter with nontrivial quasiperiodic long-range order – a new form of matter termed a soft quasicrystal. Two groups have independently discovered such order in soft matter: Zeng et al. in a system of dendrimer liquid crystals; and Taka…
We propose a new approach to fabricating carbon nanotube (CNT) vias, which uses preformed catalyst nanoparticles to grow CNTs. A newly-designed impactor provided size-classified catalyst particles, and a new deposition system injected them into via holes down to 40 nm in diameter. The resultant CNT-via resistance was…
The HAD superfamily is a large superfamily of proteins which share a conserved core domain that provides those active site residues responsible for the chemistry common to all family members. The superfamily is further divided into the four subfamilies I, IIA, IIB, and III, based on the topology and insertion site of…
A planar pi-conjugated heteroaromatic molecule 1 has been synthesized and fully characterized; it combines two characteristics, a charge-transfer transition originating from its inherent donor-acceptor nature in its neutral state and an intervalence charge-transfer transition in its 1(2+) mixed-valence state.
We utilize a series of structurally homologous, multi-porphyrin-based, fluorophores (PBFs) in order to explore the capacity of polymer vesicles (polymersomes) to stably incorporate large hydrophobic molecules, non-covalently within their thick lamellar membranes. Through aqueous hydration of dry, uniform thin-films of…
Fluorescent magnetite nanocomposites based on magnetic nanoparticles, a polyhedral octaaminopropylsilsesquioxane and a porphyrin derivative have been prepared. The intracellular uptake of the nanocomposites by macrophage and bone osteoblast cells, and their potential as MRI contrast agents, has been demonstrated.
Superhydrophobic surfaces, characterized by water contact angles greater than 150 degrees, can be produced by means of intermediate organogels, which were formed by perfluoroalkyl chain-containing organogelators with volatile organic solvents.
A coupled Cellular Automaton (CA)–Finite Element (FE) model is presented for the prediction of solidification grain structures coupled with the calculation of solid and liquid flow induced macrosegregation. The model is applied to simulate the solidification of a Pb–48wt%Sn alloy in a rectangular cavity cooled down fr…
Surface-initiated radical polymerization was carried out in order to modify the surface of inorganic solid and metal oxide nanoparticles. Novel (inorganic nanoparticles/polymer) nanocomposites were prepared through a direct polymer grafting reaction from the surfaces of magnetite (Fe3O4) (d ¼ 10 and 25 nm) and titaniu…
Poly(methyl methacrylate) zine oxide (ZnO) (PMMA/ZnO) nanocomposites were successfully prepared by the solution radical copolymerization of the monomer, methyl methacrylate (MMA), and the oleic acid–modified ZnO nanoparticles (OA‐ZnO) with 2,2′‐azobis(isobutylonitrile) (AIBN) as initiator in toluene. The products were…
Extended and oriented nanostructures are desirable for many applications, but direct fabrication of complex nanostructures with well-aligned morphology, orientation, and surface architectures remains a significant challenge. Here, we study a simple electrochemical anodizing process to fabricate arrays of titanium (Ti)…
One of the principal successes of de novo protein design has been the creation of small, robust protein-cofactor complexes which can serve as simplified models, or maquettes, of more complicated multicofactor protein complexes commonly found in nature. Different maquettes, generated by us and others, recreate a variet…
We report the design and synthesis of Ir-complex functionalized CdSe/ZnS quantum dots (QDs), in which the QD plays a key role in imaging, while the Ir-complex acts as a sensitizer to produce singlet oxygen; this conceptual design presents a novel scheme in both bio-imaging and photodynamic therapy.
Multigram quantities of Cu nanowires ca. 25 nm in diameter and µm in length have been produced by AC electrodeposition into porous aluminium oxide (PAO) templates. Multiple, large-area Al electrodes (5 × 11 cm or 10 × 25 cm) are anodized in parallel at 25.0 V in 0.3 M H2SO4(aq) using custom built baths. The pores are…
{Fe[Gd(2)bpy(DTTA)(2)(H(2)O)(4)](3)}(4-) is a self-assembled, metallostar-structured potential MRI contrast agent, with six efficiently relaxing Gd(3+) centres confined into a small molecular space. Its proton relaxivity is particularly remarkable at very high magnetic fields (r(1) = 15.8 mM(-1) s(-1) at 200 MHz, 37 d…
Discotic liquid crystals based on triindole, a novel redox active central core, have been synthesized and their mesomorphic behaviour investigated.
We report on real molecular complexes and propose strategies that explore the possibility of implementation of specific quantum computation architectures with molecular spin systems. We focus on Cr3+ carboxylate derivatives and use the Loss-DiVincenzo scheme as reference.
The steady-state oxygen permeation through polycrystalline , synthesized by a citric acid-based technique and sintered at , has been measured as a function of oxygen gradient, temperature , and membrane thickness . In agreement with earlier reports, the membranes show high permeation rates, comparable to those found f…
With light scattering titrations, we show that complex coacervate core micelles (C3Ms) form from a diblock copolymer with a polyelectrolyte block and either an oppositely charged polyelectrolyte, a diblock copolymer with an oppositely charged polyelectrolyte or a mixture of the two. The effect of added salt and pH on…