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Phenalenyl-Based Highly Conductive Molecular Systems with Hydrogen-Bonded Networks: Synthesis, Physical Properties, and Crystal Structures of 1,3- and 1,6-Diazaphenalenes, and Their Protonated Salts and Charge-Transfer Complexes with TCNQ

T. Murata、Yasushi Morita、Kozo Fukui 等 7 位作者2006-06-01Bulletin of the Chemical Society of Japan

Abstract Protonated salts and charge-transfer complexes of the 1,3- and 1,6-diazaphenalene (DAP) systems 5–7 have been investigated for new conducting molecule-based materials. Cyclic voltammetry measurements revealed that DAP derivatives are stronger electron donors than hydroquinone, and some of them possess compara…

Magnetism in coordination complexesConducting polymers and applicationsOrganic and Molecular Conductors Research

(S)‐Isoleucine and (R)‐2‐octanol as chiral precursors of new chiral liquid crystalline thiadiazoles: synthesis, mesomorphic and ferroelectric properties

M. Parra、Jorge Vergara、Paulina I. Hidalgo 等 5 位作者2006-06-01Liquid Crystals

New chiral Schiff bases with a 1,3,4‐thiadiazole unit in the rigid core were synthesized (SB1–SB4). These compounds contain a chiral chain derived from (S)‐isoleucine and (R)‐2‐octanol. Their liquid crystalline properties were studied by polarizing optical microscopy, differential scanning calorimetry and X‐ray diffra…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Boron Nitride Particle Filled Paraffin Wax as a Phase-Change Thermal Interface Material

Zongrong Liu、D.D.L. Chung2006-06-01Journal of Electronic Packaging

Wax (predominantly tricosane paraffin wax, with a melting temperature of 48°C) filled with hexagonal boron nitride (BN) particles (5-11μm) was found to be an effective phase-change thermal interface material. The thermal contact conductance, as measured with the interface material between copper surfaces, decreased wi…

Phase Change Materials ResearchHeat Transfer and OptimizationThermal properties of materials

Construction of Three-dimensional Framework with 1,8-Anthrylene and Butadiynylene Building Units: Synthesis and Properties of Cyclic Tetramers

Michio Goichi、Shinji Toyota2006-06-01Chemistry Letters

Abstract As a new type of π-conjugated macrocycles, 1,8-anthrylene–butadiynylene cyclic tetramers were synthesized by metal-catalyzed oxidative coupling reactions. The fluorescence spectrum of the nonsubstituted derivative indicated partial formation of an excimer in the excited state. The macrocyclic structure underg…

Supramolecular Chemistry and ComplexesLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds

Properties of Polypropylene/Carbon Nanotube Composites Compatibilized by Maleic Anhydride Grafted SEBS

Xing Ping Zhou、Haiyan Peng、Fandi Zeng 等 5 位作者2006-06-01Key engineering materials

Isotactic polypropylene (PP)/carbon nanotube (CNT) composites compatibilized by maleic anhydride grafted styrene-ethylene/butylenes-styrene copolymer (MA-SEBS) were prepared by melt compunding and compression moulding. The melt compouding torque, thermal properties, dynamical mechanical behavior, mechanical and anti-s…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Development of a 45 kVA Single-Phase Model HTS Transformer

Yang Wang、Joon Han、Xin Zhao 等 11 位作者2006-06-01IEEE Transactions on Applied Superconductivity

This paper presents design and test of a single-phase HTS transformer with capacity of 45 kVA operated in liquid nitrogen of 77 K for primary/secondary voltages of 2400/160 V. The windings were wound by stainless steel-enforced multifilamentary Bi2223/Ag tapes. The structures of primary and secondary windings are sole…

Physics of Superconductivity and MagnetismElectric Motor Design and AnalysisMagnetic Properties and Applications

The degradation of oil painted copper surfaces

Lydia-Chara Pavlopoulou、David H. Watkinson2006-06-01Studies in Conservation

Degradation of oil painted copper surfaces involves chemical, physical and mechanical processes that are influenced by the prevailing environment. The oil paint/copper interface formed between the lower layers of paint and its copper support determines the stability of the system. Components within the painted copper…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsCultural Heritage Materials Analysis

Electrical conduction of carbon nanotube atomic force microscopy tips: Applications in nanofabrication

Alexander J. Austin、Cattien V. Nguyen、Quoc Ngo2006-06-01Journal of Applied Physics

This paper reports the electrical transport properties of the interface of a multiwalled carbon nanotube (MWNT) in physical end contact with a hydrogen-passivated Si surface and a Pt surface. The electrical measurement was performed in an atomic force microscope (AFM) with a MWNT attached to a scanning probe in contac…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Disclination Velocity in Bistable Chiral Splay Nematic Liquid Crystal Device

Chul Gyu Jhun、Chao Ping Chen、Sung Lyoung Lee 等 6 位作者2006-06-01Japanese Journal of Applied Physics

We investigate how miscellaneous parameters influence the velocity of the disclination line in a bistable chiral splay nematic liquid crystal (BCSN LC) device, using a model derived from the relationship of the free energy loss rate with dissipation energy. The disclination velocity is consistently coupled with the fr…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationAdvanced Optical Imaging Technologies

Aliphatic Polyesters for Advanced Technologies – Structural Characterization of Biopolyesters with the Aid of Mass Spectrometry

Grażyna Adamus2006-06-01Macromolecular Symposia

Abstract Application of the ESI‐ mass spectrometry technique for the structural studies of biopoliesters is reported. The structural studies were performed on two selected commercially available biopolyesters i.e. poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyvalerate) (PHBV) and poly(3‐hydroxybutyrate‐ co ‐3‐hydroxyhexanoate)…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionCarbon dioxide utilization in catalysis

Application of Photoresponsive Polymers Carrying Crown Ether and Spirobenzopyran Side Chains to Photochemical Valve

Keiichi Kimura、Hidefumi Sakamoto、Takateru Nakamura2006-06-01Journal of Nanoscience and Nanotechnology

A vinyl copolymer carrying crown ether and spirobenzopyran side chains, which undergoes significant photoinduced rheology changes, i.e., contraction and extension of its polymer chain, was applied to a material for photocontrol system of solvent permeation rate, so-called, photochemical valve. Macroporous polyethylene…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Orientational order parameter of the nematic liquid crystalline phase ofF-actin

Jorge Viamontes、Suresh Narayanan、Alec Sandy 等 4 位作者2006-06-01Physical Review E

We measured the orientational order parameter of $F$-actin traversing the isotropic-nematic phase transition using a combination of techniques, including fluorescence imaging, local birefringence measurements, and small-angle x-ray scattering. The order parameter approaches a saturated value of 0.75 for actin concentr…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesAdvanced Fluorescence Microscopy Techniques

Copolyesters of ϵ‐Caprolactone, Isosorbide and Suberic Acid by Ring‐Opening Copolymerization

Saber Chatti、Hans R. Kricheldorf2006-06-01Journal of Macromolecular Science Part A

Biodegradable copolyesters were prepared by copolymerization of ϵ‐caprolactone (ϵCL) with a cyclic polyester consisting of isosorbide and suberic acid (CPIS). Four initiators were compared: Sn(II)2‐ethylhexanoate (SnOct2) in combination with benzyl alcohol, 2,2‐dimethyl‐2‐stanna‐1,3‐dioxepane (DSDOP) lanthanium and yt…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsCarbon dioxide utilization in catalysis

Study On The Electrical Equivalent Circuit Models of Polluted Outdoor Insulators

Waluyo Waluyo、Parouli M. Pakpahan、Suwarno Suwarno2006-06-01OpenAlex

During operation, an outdoor high voltage insulator may come under various stresses. One of them is environmental pollution, where pollutants stick to the insulator surface. The polluted condition may produce leakage currents or even electrical discharges. Their waveforms are normally non-pure sinusoidal. To understan…

High voltage insulation and dielectric phenomena

Arrays of lipid bilayers and liposomes on patterned polyelectrolyte templates

Neeraj Kohli、Sachin Vaidya、Robert Y. Ofoli 等 5 位作者2006-06-01Journal of Colloid and Interface Science

This paper presents novel methods to produce arrays of lipid bilayers and liposomes on patterned polyelectrolyte multilayers. We created the arrays by exposing patterns of poly(dimethyldiallylammonium chloride) (PDAC), polyethylene glycol (m-dPEG) acid, and poly(allylamine hydrochloride) (PAH) on polyelectrolyte multi…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Synthesis of γ‐Ga 2 O 3 –Al 2 O 3 Solid Solutions by the Glycothermal Method

Masaru Takahashi、Noriyuki Inoue、Tatsuya Takeguchi 等 6 位作者2006-06-01Journal of the American Ceramic Society

The reaction of mixtures of aluminum isopropoxide and gallium acetylacetonate in 1,4‐butanediol or 1,5‐pentanediol at high temperatures (glycothermal reaction) directly gave the γ‐Ga 2 O 3 –Al 2 O 3 solid solutions, which had high catalytic activities for selective reduction of NO using methane as the reducing agent.…

Advanced Photocatalysis TechniquesMicrowave Dielectric Ceramics SynthesisGa2O3 and related materials

Temporal response and first order volume changes during grating formation in photopolymers

John V. Kelly、Michael R. Gleeson、Ciara E. Close 等 7 位作者2006-06-01Journal of Applied Physics

We examine the evolution of the refractive index modulation when recording gratings in an acrylamide based photopolymer. A nonlocal diffusion model is used to predict theoretically the grating evolution. The model has been developed to account for both nonlocal spatial and temporal effects in the medium, which can be…

Photonic and Optical DevicesPhotorefractive and Nonlinear OpticsOptical Coatings and Gratings

Devulcanization of styrenebutadiene (SBR) waste tire by controlled oxidation

Rachel R.V.A. Rios、Manuela Gontijo、Vany Ferraz 等 5 位作者2006-06-01Journal of the Brazilian Chemical Society

This work describes the devulcanization of vulcanized SBR (Styrene Butadiene Rubber) based on controlled oxidation with nitric acid. IR, ¹H and 13C-NMR, CHN elemental analyses, TG, GPC and TPD-MS (Temperature Programmed Decomposition-Mass Spectrometry) experiments suggest that nitric acid promotes two processes: (i) d…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsbiodegradable polymer synthesis and properties

Stability Aspects of the High Strength High Conductivity Microcomposite Cu-Nb Wires Properties

V.I. Pantsyrny、A.K. Shikov、A. Vorobieva 等 7 位作者2006-06-01IEEE Transactions on Applied Superconductivity

Extremely high strength in microcomposite Cu-Nb wires is associated with ultra-fine-scale microstructure. The extended interfaces between ribbon-like niobium filaments and copper matrix contain the areas of semi-coherent interfaces that are apparently the main reason of significant level of residual stresses observed…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsElectromagnetic Effects on Materials

On the mechanisms governing the texture and microstructure evolution during static recrystallization and grain growth of low alloyed zirconium sheets (Zr702)

N. Dewobroto、Nathalie Bozzolo、Pierre Barbéris 等 4 位作者2006-06-01International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde)

Abstract Low alloyed zirconium sheets (Zr702) have been cold-rolled up to 80% thickness reduction and submitted to various isothermal treatments. The aim was to identify the mechanisms which produce microstructure and texture changes during recrystallization and grain growth. XRD and texture analysis, FEG–SEM with EBS…

Microstructure and mechanical propertiesMagnesium Alloys: Properties and ApplicationsNuclear Materials and Properties