Materials Literature
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Adsorbed natural gas has various advantages and is relatively more economical than liquefaction and compression. In our present investigation, we have prepared the carbon monolith from a phenol resin mixed with a renewable resource (such as cotton fiber) after carbonization. The compositions were optimized to determin…
Abstract The two novel thioantimonates(III) (C 6 N 3 H 17 2+ )Sb 6 S 10 ( I ) and (C 7 N 2 H 13 + ) 3 Sb 9 S 15 ( II ) were synthesized under solvothermal conditions reacting Sb and S with the amines 1‐(2‐aminoethyl)‐piperazine (C 6 N 3 H 15 ) and 1, 5‐diazabicyclo[4.3.0.]non‐5‐en (DBN, C 7 N 2 H 12 ), respectively. T…
The growth kinetics of crystals of bis(imidazolium 2,6-dicarboxypyridine) M (II) dihydrate, where M = Cu, Ni, Co, Zn, and Mn, were studied in situ using atomic force microscopy. The aspect ratios of specific crystal facets were found to vary systematically with changes in the total concentration of the three component…
A detailed investigation of the reorganization processes occurring in the crystalline phase of poly(butylene terephthalate) (PBT) during fusion was performed by temperature-modulated differential scanning calorimetry (TMDSC). Quasi-isothermal TMDSC analyses were conducted for extended times at different temperatures i…
The structure of amorphous ice under pressure has been studied by molecular dynamics at 160 K. The starting low-density phase undergoes significant changes as the density increases, and at rho=1.51 g/cm(3) our calculated g(OO)(r) is in excellent agreement with in situ neutron diffraction data obtained at 1.8 GPa and 1…
This presentation is an overview of clean/strip processing for low Cu/low-k technology. The paper starts with a brief analysis of dry etch processes that determine the issues in subsequent processes; in the case of porous low-k dielectrics, etch conditions must be carefully optimized to find an optimal balance between…
An amorphous 50/50 atactic polypropylene (aPP)/isotactic polypropylene (iPP) mixture at 125 degrees C was simulated using a second nearest neighbor diamond lattice and a three states rotational isometric state model. The result suggests that at the liquidlike density that corresponds to the atmospheric pressure, aPP p…
ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTA Reexamination of and Me of Syndiotactic Polypropylenes with Metallocene CatalystsChenyang Liu, Jian Yu, Jiasong He, Wei Liu, Chunyan Sun, and Zhenhua JingView Author Information Key Laboratory of Engineering Plastics, Joint Laboratory of Polymer Science and Materials, Institu…
The one-dimensional paracrystal model is generalized by folding the lattice sites with objects whose scattering lengths or sizes and separation display a spatial correlation from cell to cell. A general theory to calculate the diffuse scattering and the scattering-length autocorrelation function is developed. The inve…
The miscibility and thermal degradation of blends of poly(bisphenol A carbonate) (PBC) with poly(vinyl chloride) (PVC) have been studied in inert atmosphere by a differential thermal/thermogravimetry analyzer. The blend showed a single glass transition temperature consistent with the Fox equation prediction suggesting…
Abstract Summary: Carbon nanotubes (CNTs) have been grown on MCM‐41 supported Fe nanoparticles and the as‐prepared (no further purification) CNT‐silica hybrid was directly incorporated into nylon‐6 (PA6) by simple melt‐compounding. The urchin‐shaped CNT‐silica hybrid filler was observed to be homogeneously dispersed t…
Abstract The reaction of bismuth and bismuth trichloride with sulfur or selenium, respectively, in a AlCl 3 /NaCl melt at 130 °C leads to (Bi 4 S 4 )[AlCl 4 ] 4 1 and (Bi 4 Se 4 )[AlCl 4 ] 4 2 in the form of red and amber colored crystals. Both crystallize isotypically in the tetragonal space group $I{\bar 4}$ with th…
Terminally protected acyclic tripeptides Boc-Tyr(1)-Val(2)-Tyr(3)-OMe 1 and Boc-Tyr(1)-Ile(2)-Tyr(3)-OMe 2 self-assemble into nanotubes in crystals through various noncovalent interactions with an average internal diameter of 5 A (0.5 nm), and the tubular ensemble is developed through the hydrogen-bonded side chains o…
This study investigated the mucoadhesive property of a hydrophobically modified copolymer N-isopropylacryamide and glycidylacrylamide NIPAM-N-Gly-(C18)2 (NIPAM-Gly). Prior studies demonstrated that the interfacial properties of this copolymer are pH dependent and that the chains form strong hydrogen bonds at pH < 7 vi…
Crystal structural parameters (21 positional parameters and nine isotropic Debye-Waller factors) of the intermediate phase of hexagonal barium titanate (h-BaTiO3) have been refined by a structure analysis method using convergent-beam electron diffraction (CBED); this method was developed by Tsuda & Tanaka [Acta Cryst.…
Nonoxidative activation of methane was carried out over Ag/ZSM-5 catalysts, prepared by the wetness impregnation method, and the catalysts were characterized by various techniques. Theoretical calculation was further employed to clarify the reaction mechanism of methane coupling over the catalysts. Ag + ions were foun…
We present a simple and computationally efficient classical atomistic model of silica in which the silicon and oxygen are simulated as hard spheres with four and two association sites, respectively. We have performed isobaric-isothermal Monte Carlo simulations to study the mechanical and phase behavior of this model.…
Very strong electronic communication, manifested in a K(C) value of ca. 10(9), has been found in a system of three compounds separated by one electron oxidation where each compound contains two metal-metal bonded Mo(2)(n+) units linked by a dimethyloxamidate anion, CH(3)N(O)C-C(O)NCH(3)(2)(-). The Mo-Mo distances incr…
The localized, sustained delivery of growth factors for wound healing therapy is actively being explored by gene transfer to the wound site. Biocompatible matrices such as bovine collagen have demonstrated usefulness in sustaining gene therapy vectors that express growth factors in local sites for tissue repair. Here,…
Abstract The new meta ‐oxoborates γ‐ RE (BO 2 ) 3 ( RE = La ‐ Nd) (≡ RE B 3 O 6 ) were obtained as colourless (La, Ce), light green (Pr) and pale violet (Nd) crystalline powders by the reaction of CeO 2 , Pr 6 O 11 , or RE 2 O 3 ( RE = La, Nd) and B 2 O 3 in a Walker‐type multianvil apparatus under high‐pressure/high‐…