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Green Self‐Assembling Porphyrins and Chlorins as Mimics of the Natural Bacteriochlorophylls c, d, and e

Teodor Silviu Balaban、Myriam Linke‐Schaetzel、Anil Dnyanoba Bhise 等 5 位作者2004-08-30European Journal of Organic Chemistry

Abstract Novel porphyrins and chlorins that self‐assemble in nonpolar solvents in a manner similar to that of the bacteriochlorophylls c , d , and e have been synthesized by a common protective group approach. The supramolecular assemblies have broad and red‐shifted absorption spectra in comparison to those of the mon…

Porphyrin and Phthalocyanine ChemistryPhotosynthetic Processes and MechanismsPorphyrin Metabolism and Disorders

Technique for patterning macroporous silicon and the fabrication of bars of 2D photonic crystals with vertical walls

E. V. Astrova、T. N. Borovinskaya、V. A. Tolmachev 等 4 位作者2004-08-30Semiconductors

A new technological process for fabricating structures with vertical walls in a thick layer of macroporous silicon on a substrate is reported. The problem of photolithography has been solved by patterning on the back side of the wafer. As a result, the silicon substrate itself serves as a mask through which certain pa…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsPhotonic Crystals and Applications

Certain features of Ga diffusion in ZnS powders

Yu. Yu. Bacherikov、I. P. Vorona、S. V. Optasyuk 等 5 位作者2004-08-30Semiconductors

Spectra of photoluminescence and electron spin resonance were investigated for ZnS powders annealed in the presence of metallic Ga with limited access of atmospheric air. Analysis of these spectra showed that there was no Ga impurity in the annealed ZnS powders. It was established that subsequent free access of air to…

Quantum Dots Synthesis And Properties

A study of magnetic clusters in Co‐doped ZnO using neutron scattering

Hyunjun Lee、Gihun Ryu、Sung‐Kyu Kim 等 7 位作者2004-08-30physica status solidi (b)

Abstract We report on a study of magnetic cluster in Co‐doped ZnO using neutron diffraction. The samples are fabricated by the sol–gel process and the structural properties are characterized by X‐ray diffraction and neutron diffraction. The diffraction data obtained by neutron are compared with the results of X‐ray di…

Advanced Condensed Matter PhysicsMagnetic and transport properties of perovskites and related materialsZnO doping and properties

ELECTROCHEMICAL COPOLYMERIZATION OF N-METHYL PYRROLE WITH CARBAZOLE

A. Sezai̇ Saraç、Murat Ateş、Elif Altürk Parlak2004-08-30International Journal of Polymeric Materials

Electrocopolymerization of N-methylpyrrole (NMePy) and Carbazole (Cz) was conducted in acetonitrile. Oxidative chemical random copolymerization of NMePy and Cz was also realized by Cerium (IV) ammonium nitrate (CAN) for comparison. The properties of the resulting copolymers were investigated by spectroscopic methods (…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Shake-up valence excitations inCuOby resonant inelastic x-ray scattering

G. Döring、Christian Sternemann、A. Kaprolat 等 6 位作者2004-08-30Physical Review B

Shake-up satellites are found in the resonant inelastic x-ray scattering spectra of $\mathrm{CuO}$ single crystals, excited by means of monochromatized synchrotron radiation with energies near the $\mathrm{Cu}$ $K$-edge. Within the limits of third-order perturbation treatment, the satellites are attributed to charge t…

Magnetic properties of thin filmsZnO doping and propertiesCopper-based nanomaterials and applications

A crystal structure of ultra-dispersed form of polytetrafluoroethylene based on X-ray powder diffraction data

V. M. Bouznik、С. Д. Кирик、Leonid A. Solovyov 等 4 位作者2004-08-30Powder Diffraction

An X-Ray powder diffraction study of ultra-dispersed polytetrafluoroethylene was carried out. As well as a regular polytetrafluoroethylene the ultra-dispersed form contents a high proportion of the crystalline phase. The X-ray diffraction pattern could be described with two-dimensional hexagonal unit cell [a=5.685(1)…

X-ray Diffraction in CrystallographyInorganic Fluorides and Related CompoundsCrystallography and molecular interactions

Structure and microstructure of gypsum and its relevance to Rietveld quantitative phase analyses

Ángeles G. De la Torre、María-Gema López-Olmo、C. Álvarez-Rúa 等 5 位作者2004-08-30Powder Diffraction

Single crystals of gypsum were studied in a diffractometer equipped with a CCD two-dimensional detector. The microstructure of the crystal gave wide poorly shaped spots showing sometimes curved streaks around the spots, which made the integration process very difficult, yielding a low quality structure. The crystal st…

High-pressure geophysics and materialsX-ray Diffraction in CrystallographyCrystal Structures and Properties

Lattice thermal conductivity of superlattice structures

David Broido、T. L. Reinecke2004-08-30Physical Review B

We give a quantitative inelastic phonon Boltzmann equation theory of thermal transport in quantum well superlattices due to anharmonic three phonon processes. The thermal conductivity is calculated as a function of the mass ratio of the constituent atoms and of the superlattice period. We show that there is a competit…

Thermal properties of materialsThermal Radiation and Cooling TechnologiesAdvanced Thermoelectric Materials and Devices

Practical Engineering Failure Analysis

H. M. Tawancy、Anwar Ul‐Hamid、Nureddin M. Abbas2004-08-30OpenAlex

Filling a gap in the literature, Practical Engineering Failure Analysis vividly demonstrates the correct methodology to conduct successful failure analyses, as well as offering the background necessary for these investigations. This authoritative reference covers procedures to reduce the occurrence of component failur…

Mechanical and Thermal Properties AnalysisMetal Alloys Wear and PropertiesMaterial Properties and Applications

Performance limits of uncooled VO x microbolometer focal plane arrays

Margaret Kohin、Neal Butler2004-08-30Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Uncooled microbolometer technology has shown dramatic improvements in recent years as tens of thousands of imaging systems have been delivered. This paper outlines the performance limits that must be overcome to continue to achieve performance improvements.

Infrared Target Detection MethodologiesTransition Metal Oxide NanomaterialsThermal Radiation and Cooling Technologies

First-principles calculation of defect-formation energies in theY2(Ti,Sn,Zr)2O7pyrochlore

W. R. Panero、Lars Stixrude、Rodney C. Ewing2004-08-30Physical Review B

Isometric pyrochlore, ${\mathrm{A}}_{2}{\mathrm{B}}_{2}{\mathrm{O}}_{7}$, with compositions in the ${\mathrm{Y}}_{2}{(\mathrm{Ti},\mathrm{Sn},\mathrm{Zr})}_{2}{\mathrm{O}}_{7}$ ternary system, are of particular interest because there are dramatic changes in properties, such as ionic conductivity, and response to radia…

Electronic and Structural Properties of OxidesNuclear materials and radiation effectsAdvanced Condensed Matter Physics

O 2 activation by binuclear Cu sites: Noncoupled versus exchange coupled reaction mechanisms

Peng Chen、Edward I. Solomon2004-08-30Proceedings of the National Academy of Sciences

Binuclear Cu proteins play vital roles in O(2) binding and activation in biology and can be classified into coupled and noncoupled binuclear sites based on the magnetic interaction between the two Cu centers. Coupled binuclear Cu proteins include hemocyanin, tyrosinase, and catechol oxidase. These proteins have two Cu…

Porphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry ReactionsElectrochemical Analysis and Applications

Nonlinear conductance in molecular devices: molecular length dependence

Z. Crljen、A. Grigoriev、G. Wendin 等 4 位作者2004-08-30arXiv

We theoretically study the electronic transport in the monolayer of dithiolated phenylene vinylene oligomeres coupled to the (111) surfaces of gold electrodes. We use non-equilibrium Green functions (NEGF) and density functional theory(DFT) implemented in the TranSIESTA package to obtain a full ab initio self-consiste…

Materials Science

Numerical simulations of two dimensional magnetic domain patterns

E. A. Jagla2004-08-30arXiv

I show that a model for the interaction of magnetic domains that includes a short range ferromagnetic and a long range dipolar anti-ferromagnetic interaction reproduces very well many characteristic features of two-dimensional magnetic domain patterns. In particular bubble and stripe phases are obtained, along with po…

cond-mat.stat-mechMaterials Science

Epitaxial growth and properties of cobalt-dopedZnOonα−Al2O3single-crystal substrates

Ai-Xiang Tuan、J. Daniel Bryan、A. B. Pakhomov 等 12 位作者2004-08-30Physical Review B

$\mathrm{Co}$-doped $\mathrm{ZnO}({\mathrm{Co}}_{x}{\mathrm{Zn}}_{1\ensuremath{-}x}\mathrm{O})$ is of potential interest for spintronics due to the prediction of room-temperature ferromagnetism. We have grown epitaxial ${\mathrm{Co}}_{x}{\mathrm{Zn}}_{1\ensuremath{-}x}\mathrm{O}$ films on ${\mathrm{Al}}_{2}{\mathrm{O}…

Advanced Condensed Matter PhysicsZnO doping and propertiesElectronic and Structural Properties of Oxides

Theoretical study of dislocation nucleation from simple surface defects in semiconductors

Julien Godet、Laurent Pizzagalli、S. Brochard 等 4 位作者2004-08-30Physical Review B

Large-scale atomistic calculations, using empirical potentials for modeling semiconductors, have been performed on a stressed system with linear surface defects like steps. Although the elastic limits of systems with surface defects remain close to the theoretical strength, the results show that these defects weaken t…

Microstructure and mechanical propertiesThermal properties of materialsSurface and Thin Film Phenomena

The XPS peak structure of condensed aromatic anhydrides and imides

M. Jung、U. Baston、T. Porwol 等 5 位作者2004-08-30arXiv

Photoelectron spectra of aromatic anhydrides and imides like PTCDA (perylene-tetracarboxylic dianhydride), PTCDI (perylene-tetracarboxylic diimide), and NDCA (naphthalene-dicarboxylic anhydride) on smooth single crystal surfaces show complex double peak structures in both the O1s and the anhydride C1s range. The peak…

Materials Science

A Review of Liquid Phase Epitaxial Grown Gallium Arsenide

D. Alexiev、D. A. Prokopovich、S. Thomson 等 6 位作者2004-08-30arXiv

Liquid phase epitaxy of gallium arsenide (LPE GaAs) has been investigated intensively from the late 1960's to the present and has now a special place in the manufacture of wide band, compound semiconductor radiation detectors. Although this particular process appears to have gained prominence in the last three decades…

Materials Science

The chemistry of La on the Si(001) surface

Christopher R. Ashman、Clemens J. Foerst、Karlheinz Schwarz 等 4 位作者2004-08-30arXiv

This paper reports state-of-the-art electronic structure calculations of La adsorption on the Si(001) surface. We predict La chains in the low coverage limit, which condense in a stable phase at a coverage of 1/5 monolayer. At 1/3 monolayer we predict a chemically rather inert, stable phase. La changes its oxidation s…

Materials Science