Materials Literature
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Very precise electrical conductivity data on a series of six glasses (molar composition 25[xNa 2 O+(l−x)K 2 O]‐5Al 2 O 3 −70SiO 2 with 0.95 ≤x≤l) have been obtained over a large temperature range (∼310°C). Analysis of these data suggests that the preexponential term in the Arrhenius conductivity equation is temperatur…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheoretical study of o-quinone complexes of ironDouglas J. Gordon and Richard F. FenskeCite this: Inorg. Chem. 1982, 21, 8, 2916–2923Publication Date (Print):August 1, 1982Publication History Published online1 May 2002Published inissue 1 August 1982https://pubs.acs.org/doi/1…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectrochemical characterization of a novel rhodium(II) dimer, Rh2(ONHCCF3)4Karl M. Kadish, D. Lancon, A. M. Dennis, and J. L. BearCite this: Inorg. Chem. 1982, 21, 8, 2987–2992Publication Date (Print):August 1, 1982Publication History Published online1 May 2002Published ini…
Abstract An evaluation of the physical properties of iron, cobalt, nickel, and copper high oxidation states in oxides shows the influence of chemical bonding and structural factors on the electronic configuration. Such correlations are illustrated by the synthesis of the first six‐coordinated iron(V) oxide: La 2 LiFeO…
In fine-grained polycrystalline solids both lattice and grain-boundary diffusion contribute to the effective volume diffusivity. In tracer diffusion experiments the concentration–penetration profiles can be suitably analysed to distinguish between these two components. This paper presents new data on 59Fe diffusion in…
Abstract Clayey sediments of marine origin having sensitivities (ratio of undisturbed to remolded shear strength) as high as 1000 at a reduced salt concentration are found around Ariake Bay, Kyushu, Japan. The clay fraction of the sediments contains smectite as a principal mineral (33–42%) in contrast to the illitic c…
Based on a tunneling pair recombination concept, rigorous expressions of thermostimulated luminescence (TSL), phosphorescence (PP), and photostimulated luminescence (PSL) are derived. A novel method of examining the ratio of PSL and PP at fixed temperatures and fixed times is shown to be useful for the determination o…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew trinuclear, oxo-centered, basic carboxylate compounds of transition metals. 2. Synthesis and x-ray structure of V3(O)3(THF)(C6H5CO2)6, a compound with a deviant structureF. Albert Cotton, Gregg E. Lewis, and Graham N. MottCite this: Inorg. Chem. 1982, 21, 8, 3127–3130Pub…
The thermoluminescence properties of three different preparations of lithium borate have been studied with specific reference to their use in medical dosimetry. The properties of lithium borate powder doped with copper make it more attractive for low dose measurements than the more conventional phosphor doped with man…
Abstract An analysis of the available data on the thermostability and imino acid content of various collagens has shown that the change of the denaturation temperature ( t m ) of the collagen triple helix, as well as the temperature of hydrothermic shrinkage ( t s ) of collagen fibrils, depends on the number of hydrox…
The anomalous skin effect is treated classically using a convective derivative to describe non-local effects. This approach yields a simple and accurate means by which to evaluate the optical properties of a metal over the entire frequency range in which the anomalous skin effect is significant. Furthermore, it can ca…
Critical load characteristics for the indentation‐induced median crack in ternary lead‐zinc‐borate and commercial silicate glasses were investigated. The critical load is directly proportional to the fracture toughness/Vickers microhardness term, supporting the Lawn‐Evans model; however, the magnitude of the load is c…
Abstract A series of polyether polyol (polyoxypropylene capped with polyoxyethylene), 4‐4′ diphenylmethane diisocyanate, and 1,4 butane diol urethanes were prepared by reaction injection molding with different levels of catalyst (dibutyl tin dilaurate). The degree of phase separation, morphology, and molecular weight…
The angular reflectance of a graded-index layer, of arbitrary refractive-index profile, on the surface of a uniform substrate is calculated exactly by direct numerical integration of the wave equation for both states of polarization of the incident light. A study of the results for a number of selected profiles shows…
Methods of computer molecular dynamics have been applied to model a 𝒥 = 5 symmetric-tilt coincidence grain boundary. A pairwise Lennard-Jones 6–12 potential was used to simulate the atomic interactions in a bicrystal containing up to 396 atoms. At simulated temperatures of approximately half the potential well depth t…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheoretical study of o-quinone complexes of chromium and vanadiumDouglas J. Gordon and Richard F. FenskeCite this: Inorg. Chem. 1982, 21, 8, 2907–2915Publication Date (Print):August 1, 1982Publication History Published online1 May 2002Published inissue 1 August 1982https://p…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIsolation of an iron-nitrene complex from the dioxygen- and iron porphyrin-dependent oxidation of a hydrazineD. Mansuy, P. Battioni, and J. P. MahyCite this: J. Am. Chem. Soc. 1982, 104, 16, 4487–4489Publication Date (Print):August 1, 1982Publication History Published online…
Binary iron‐base alloys containing chromium additions of 3, 9, 12, and 18% were passivated in borate buffer ( p H 8.4). The passive films formed on these alloys were investigated by Auger, ESCA, and SIMS techniques. For the Fe‐3Cr alloy passivated in the potential range 0.65–1.45V vs. RHE, the Auger spectra showed neg…
Cells of a pseudomonad associated with pipeline corrosion grown on a complex medium were orange in color and vigorously reduced ferric iron. The intensity of orange color of cells grown on a synthetic medium and their ability to reduce ferric iron was directly related to the iron content of the medium. Absorption spec…
Abstract A procedure has been developed for characterizing cellulose ethers on the basis of the distribution of substituent groups along the polymer backbone. This method has been applied to carboxy‐methylcellulose. The technique uses cellulase, a cellulose‐degrading enzyme. Degradation as a function of time is follow…