Materials Literature
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Looking beyond the traditional applications of polyurethanes (PUR), Polyurethanes as Specialty Chemicals presents a different approach to polyurethane chemistry by examining a range of new products and new research for both environmental and medical applications. This book is also the first in its field to provide use…
We determined the vanadium oxidation state and local coordination environment in disordered samples of magnetic $\mathrm{V}{[\mathrm{TCNE}]}_{x}(x\ensuremath{\approx}2)$ prepared by chemical vapor deposition (CVD). Systematic studies of the x-ray absorption near-edge structure (XANES) in this material and reference co…
Highly ordered Mg/Al-based layered double hydroxide (LDH) nanocrystals on Si substrates were successfully obtained by ultrasonic treatment in organic solvents. LDHs intercalated with aliphatic α,ω-dicarboxylate were prepared through anion exchange by solvothermal treatment at around 100 °C. Binary solvent mixtures of…
Atom transfer radical polymerization (ATRP) was used to prepare a new series of ABA triblock copolymers that are photoactive thermoplastic elastomers. The samples synthesized have the same rubbery midblock of poly( n -butyl acrylate) (PnBA) but differ in the degree of polymerization of the end blocks of a methacrylate…
The correlation between optical, structural, and light-emitting properties of annealed Si-rich silica samples containing different amounts of Si nanocrystals is studied. The intensity of the 1.6eV emission band weakens when the Raman signal coming from the Si nanocrystals gets stronger. On the contrary, the absorption…
Improved endothelialization without platelet adhesion is essential to enhance the long-term patency of synthetic vascular grafts and other blood-contacting devices. We have developed a dually modified polyurethaneurea by incorporating endothelial cell adhesive YIGSR peptide sequences as chain extenders and nonthrombog…
Abstract Chitosan coatings prominently improved both the gloss and oxygen barrier properties of paper. The gloss value in the machine direction was increased as a function of added chitosan. An oxygen‐permeability value of 1.1 cm 3 /m 2 d was obtained when 6.9 g/m 2 chitosan was applied to 80 g/m 2 copy paper. In addi…
The combination of combinatorial techniques for the synthesis as well as for the screening of novel star-shaped block copolymers consisting of a poly(ethylene glycol) core and a poly(caprolactone) shell leads to a fast evaluation of interesting properties of these materials. The polymers could be synthesized in a full…
We use transient photoluminescence to spectrally resolve the emission from 1, 2, and 3 electron-hole pairs states in $\mathrm{CdSe}$ colloidal quantum dots with radii ranging between 2.3 and $5.2\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$. The power dependence of the triexciton, biexciton and single exciton emission inten…
Room-temperature ferromagnetism is observed in chemically synthesized powder samples of Sn1−xCoxO2 with x=0.005 and 0.01. Magnetic hysteresis loops are observed at 300K with coercivity Hc∼630Oe, saturation magnetization Ms∼0.133μB∕Co ion, and about 31% remanence. Analyses of the magnetization data of paramagnetic samp…
Lanthanide phosphate nanocrystals exhibiting the rhabdophane-type structure and mean particle sizes below 10 nm are synthesized by hydrolysis of an aqueous mixture of sodium tripolyphosphate (Na 5 P 3 O 10 ) and lanthanide salts. 31 P NMR studies show that polyphosphate groups act both as a source of orthophosphate an…
In this paper we report the surface-initiated polymerization of poly( N -isopropylacrylamide) (pNIPAAM), a stimulus-responsive polymer, from monolayers of ω-mercaptoundecyl bromoisobutyrate on gold-coated surfaces. pNIPAAM was polymerized in aqueous solution at a low methanol concentration at room temperature to maint…
Electron emission measurements were conducted on individual carbon nanotubes. The nanotubes had a closed end and their surfaces were thoroughly cleaned. It is shown conclusively that individual carbon nanotube electron emitters indeed exhibit Fowler–Nordheim behavior and have a work function of 5.1±0.1eV for the nanot…
Cholesteric liquid crystal elastomers have interesting and potentially very useful photonic properties. In an ideal monodomain configuration of these materials, one finds a Bragg-reflection of light in a narrow wavelength range and a particular circular polarization. This is due to the periodic structure of the materi…
In recent years, thin-film organic field-effect transistors (OFETs) have begun to be considered as a possible alternative to the hydrogenated amorphous silicon thin-film transistors (a-Si:H TFT's) used in active matrix flat panel displays and other large-area electronics applications. Low-temperature processability, l…
The effect of grain size on structural, magnetic and transport properties in electron-doped manganites La0.9Te0.1MnO3 has been investigated. All samples show a rhombohedral structure with the space group at room temperature. It shows that the Mn-O-Mn bond angle decreases and the Mn-O bond length increases with the inc…
The possible redox (oxidation reduction) chemical methods for precisely determining the oxygen content in the perovskite manganites including hole-doped La1-xCaxMnOy and electron-doped La1-xTexMnOy compounds are described. For manganites annealed at different temperatures, the oxygen content of the samples was determi…
We report on the first direct observation of a transition from a Tomonaga-Luttinger liquid to a Fermi-liquid behavior in potassium-intercalated mats of single-wall carbon nanotubes. Using high resolution photoemission spectroscopy, an analysis of the spectral shape near the Fermi level reveals a Tomonaga-Luttinger liq…
Tetragonal ZrO 2 exhibits good ionic conductivity, high strength, and fracture toughness. But while annealing at relatively low temperatures (63−400 °C), tetragonal ZrO 2 spontaneously transforms to a monoclinic one, and its electrical and mechanical properties degrade severely. The phenomenological observations of th…
We study the defect-induced nonlinear transmission of a periodic structure created by alternating slabs of two materials with positive and negative refractive index. We demonstrate bistable switching and tunable nonlinear transmission in an unconventional band gap that corresponds to the vanishing average refractive i…