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Properties of polypropylene/aluminum trihydroxide composites containing nanosized organoclay

Noora Ristolainen、Ulla Hippi、Jukka Seppälä 等 5 位作者2005-10-10Polymer Engineering and Science

Abstract Montmorillonite is a promising substitute for aluminum trihydroxide in flame‐retardant polypropylene/aluminum trihydroxide (PP/ATH) composites. Study was made of the partial substitution of organoclay for ATH in PP/ATH composites. The total concentration of filler was kept at 30 wt%. The composites were compa…

biodegradable polymer synthesis and propertiesFlame retardant materials and propertiesPolymer Nanocomposites and Properties

Electron-beam-induced current and cathodoluminescence studies of thermally activated increase for carrier diffusion length and lifetime in n-type ZnO

O. Lopatiuk、Leonid Chernyak、A. Osinsky 等 5 位作者2005-10-10Applied Physics Letters

Temperature dependence of the minority carrier diffusion length and lifetime in bulk n-type ZnO was studied using electron-beam-induced current and cathodoluminescence techniques. The diffusion length was observed to increase exponentially over the temperature range from 25 °C to 125 °C, yielding activation energy of…

Ga2O3 and related materialsChalcogenide Semiconductor Thin FilmsZnO doping and properties

Alkali-metal-doping dynamics and anomalous lattice contraction of individual debundled carbon nanotubes

Gugang Chen、Clascídia Aparecida Furtado、U. J. Kim 等 4 位作者2005-10-10Physical Review B

The dynamics of K doping of thin films of semiconducting debundled single-walled carbon nanotubes (SWNTs) on a $\mathrm{Si}∕{\mathrm{SiO}}_{2}$ substrate is followed using in situ Raman scattering. Similar to the behavior we observed in the Cs doping of bundled SWNTs, four distinct intervals during doping can be disti…

Graphene research and applicationsCarbon Nanotubes in CompositesMechanical and Optical Resonators

Resistivity minima and Kondo effect in ferromagnetic GaMnAs films

Hongtao He、Cheng Yang、W. K. Ge 等 6 位作者2005-10-10Applied Physics Letters

The temperature dependence of the resistivity of ferromagnetic GaMnAs, as-grown or low-temperature-annealed samples is measured from 2to290K. A resistivity minimum is observed with a corresponding temperature TM around 10K for each sample. Below TM, the resistivity exhibits logarithmic temperature dependence, as αln(T…

Semiconductor materials and devicesQuantum and electron transport phenomenaZnO doping and properties

Quantifying the working stroke of tetrathiafulvalene-based electrochemically-driven linear motor-molecules

Sune Nygaard、Bo W. Laursen、Amar H. Flood 等 6 位作者2005-10-10Chemical Communications

A highly constrained [2]rotaxane, constructed in such a way that the tetracationic cyclobis(paraquat-p-phenylene) ring is restricted to reside on a monopyrrolotetrathiafulvalene unit, has been synthesised and characterised. This design allows the deslipping free energy barrier for the tetracationic ring in all three r…

Electron Spin Resonance StudiesMagnetism in coordination complexesOrganic and Molecular Conductors Research

Enhanced continua and discrete lattices for modelling granular assemblies

A.S.J. Suiker、René de Borst2005-10-10Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences

This article discusses the derivation of continuum models that can be used for modelling the inhomogeneous mechanical behaviour of granular assemblies. These so-called kinematically enhanced models are of the strain-gradient type and of the strain-gradient micro-polar type, and are derived by means of homogenizing the…

Composite Material MechanicsRock Mechanics and ModelingNonlocal and gradient elasticity in micro/nano structures

Migration-assisted energy transfer at conjugated polymer/metal interfaces

D. E. Markov、Paul W. M. Blom2005-10-10Physical Review B

The dynamics of exciton quenching in a conjugated polymer due to the presence of metal films is analyzed using time-resolved photoluminescence. The quenching is governed by direct radiationless energy transfer to the metal and is further enhanced by diffusion of excitons into the depletion area of the exciton populati…

Conducting polymers and applicationsOrganic Light-Emitting Diodes ResearchOrganic Electronics and Photovoltaics

Preparation and optical scattering characterization of gold nanorods and their application to a dot-immunogold assay

А. В. Алексеева、В. А. Богатырев、Л. А. Дыкман 等 7 位作者2005-10-10Applied Optics

We describe optical monitoring of the synthesis of gold nanorods (NRs) based on seed-mediated growth in the presence of the soft surfactant template cetyltrimethyilammonium bromide. To separate NRs from spheres and surfactants we fractionated samples in the density gradient of glycerol. The optical properties of NRs w…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsNanoparticle-Based Drug Delivery

Ferromagnetism in Mn-Doped GaN Nanowires

Qian Wang、Qiang Sun、Puru Jena2005-10-10Physical Review Letters

Using density functional theory we show that the magnetic coupling of Mn atoms in the nanowires, unlike that in the thin film, is ferromagnetic. This ferromagnetic coupling, brought about due to the confinement of electrons in the radial direction and the curvature of the Mn-doped GaN nanowires' surface, is mediated b…

ZnO doping and propertiesMagnetic properties of thin filmsGaN-based semiconductor devices and materials

Aqueous routes to lanthanide-doped oxide nanophosphors

Valérie Buissette、Domitille Giaume、Thierry Gacoin 等 4 位作者2005-10-10Journal of Materials Chemistry

Besides well-known quantum dots, lanthanide-doped oxide nanocrystals form a new promising class of nanophosphors. Lanthanide vanadate and phosphate nanoparticles are prepared as well-dispersed and highly concentrated colloids by a very simple aqueous route, using competition between precipitation and complexation reac…

Nanocluster Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesLuminescence Properties of Advanced Materials

A discrete nonlinear mass transfer equation with applications in solid-state sintering of ceramic materials

D. T. Hristopulos、L. Leonidakis、A. Tsetsekou2005-10-10arXiv

The evolution of grain structures in materials is a complex and multiscale process that determines the material's final properties. Understanding the dynamics of grain growth is a key factor for controlling this process. We propose a phenomenological approach, based on a nonlinear, discrete mass transfer equation for…

Materials Science

Ca_25Co_22O_56(OH)_28: a layered misfit compound

T. Klimczuk、H. W. Zandbergen、N. M. van der Pers 等 7 位作者2005-10-10arXiv

The high pressure synthesis, structure and magnetic properties of Ca_25Co_22O_56(OH)_28 are reported. The compound has a misfit structure, consisting of double, square calcium oxide hydroxide rock-salt-like layers between hexagonal CoO_2 layers. The misfit compound crystallizes in the monoclinic space group C2/m, and…

Materials Science

Polarization-Dependent Resonant Anomalous Surface X-ray Scattering of CO/Pt(111)

Andreas Menzel、Yuriy V. Tolmachev、Kee-Chul Chang 等 7 位作者2005-10-10arXiv

Polarization dependence of resonant anomalous surface x-ray scattering (RASXS) was studied for interfaces buried in electrolytes or in high-pressure gas. We demonstrate that RASXS exhibits strong polarization dependence when the surface is only slightly modified by adsorption of light elements such as carbon monoxide…

Materials Science

Role of the spin-orbit splitting and the dynamical fluctuations in the Si(557)-Au surface

Daniel Sanchez-Portal、Sampsa Riikonen、Richard M. Martin2005-10-10arXiv

Our it ab initio calculations show that spin-orbit coupling is crucial to understand the electronic structure of the Si(557)-Au surface. The spin-orbit splitting produces the two one-dimensional bands observed in photoemission, which were previously attributed to spin-charge separation in a Luttinger liquid. This spin…

Materials Science

Structural models for the Si(553)-Au atomic chain reconstruction

Sampsa Riikonen、Daniel Sanchez-Portal2005-10-10arXiv

Recent photoemission experiments on the Si(553)-Au reconstruction show a one-dimensional band with a peculiar ~1/4 filling. This band could provide an opportunity for observing large spin-charge separation if electron-electron interactions could be increased. To this end, it is necessary to understand in detail the or…

Materials Science

Resonance Anomalous Surface X-ray Scattering

Andreas Menzel、Kee-Chul Chang、Vladimir Komanicky 等 7 位作者2005-10-10arXiv

Resonance anomalous surface x-ray scattering (RASXS) technique was applied to electrochemical interface studies. It was used to determine the chemical states of electrochemically formed anodic oxide monolayers on platinum surface. It is shown that RASXS exhibits strong polarization dependence when the surface is signi…

Materials Science

Comparison of the properties of GaN grown on complex Si-based structures

Shengqiang Zhou、A. Vantomme、B. S. Zhang 等 5 位作者2005-10-10arXiv

With the aim of investigating the possible integration of opto-electronic devices, epitaxial GaN layers have been grown on Si(111) SOI and on Si/CoSi2/Si(111) using metalorganic chemical vapor deposition. The samples are found to possess a highly oriented wurtzite structure, a uniform thickness and abrupt interfaces.…

Materials Science

Magnetism of ordered Sm/Co(0001) surface structures

J. E. Prieto、O. Krupin、S. Gorovikov 等 6 位作者2005-10-10arXiv

The epitaxial system Sm/Co(0001) was studied for Sm coverages up to 1 monolayer (ML) on top of ultrathin Co/W(110) epitaxial films. Two ordered phases were found for 1/3 and 1 ML Sm, respectively. The valence state of Sm was determined by means of photoemission and magnetic properties were measured by magneto-optical…

Materials Science

Boundary conditions for interfaces of electromagnetic (photonic) crystals and generalized Ewald-Oseen extinction principle

Pavel A. Belov、Constantin R. Simovski2005-10-10arXiv

The problem of plane-wave diffraction on semi-infinite orthorhombic electromagnetic (photonic) crystals of general kind is considered. Boundary conditions are obtained in the form of infinite system of equations relating amplitudes of incident wave, eigenmodes excited in the crystal and scattered spatial harmonics. Ge…

Materials Science