Materials Literature
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This article reviews the various theoretical approaches that have been developed for determination of the surface tension of solids, and the applications to food industrial products. The surface tension of a solid is a characteristic of surface properties and interfacial interactions such as adsorption, wetting or adh…
The preparation and characterization of nitric oxide (NO)-releasing dendrimer conjugates are reported. Generation 3 and 5 polypropylenimine dendrimers (DAB-Am-16 and DAB-Am-64) were modified at the exterior to impart different amine functionalities. The ability to store NO on a dendritic scaffold using N-diazeniumdiol…
A series of low-melting phthalonitrile oligomers were prepared in which variable-length multiple aromatic ether linkages interconnect the terminal phthalonitrile units. These materials were designed to address the need for a processable resin system with good high-temperature properties. The melt-processable oligomers…
Although diamond has the highest known room temperature thermal conductivity, k∼2200W∕mK, highly sp3 amorphous carbon films have k<15W∕mK. We carry out an integrated experimental and simulation study of thermal transport in ultrananocrystalline diamond (UNCD) films. The experiments show that UNCD films with a g…
A new type of materials, the backbone-thermoresponsive hyperbranched polyether, was successfully synthesized by proton-transfer polymerization of 1,4-butanediol diglycidyl ether and various triols, and the lower critical solution temperature (LCST) values can be readily adjusted from 19.0 to 40.3 degrees C by changing…
Abstract The crystallization kinetics and degree of crystallinity of polycaprolactone (PCL) were studied using the technique of differential scanning calorimetry (DSC). The crystallization exotherms measured using DSC were analyzed using a modified Avrami equation. The modification limited the analysis of the data to…
The addition of chromium and molybdenum to nickel creates alloys with exceptional corrosion resistance in a diverse range of environments. This study examines the complementary roles of chromium and molybdenum in nickel alloy passivation. Four nickel alloys with varying amounts of chromium and molybdenum were studied…
In this paper, it is demonstrated that varactor-loaded split-ring resonators (VLSRRs) coupled to microstrip lines can lead to metamaterial transmission lines with tuning capability. Both negative permeability (mu<0) and double (or left-handed) negative media have been designed and fabricated with tuning ranges as wide…
Molecular dynamics simulations of high density hard sphere fluids clearly show a breakdown of the Stokes-Einstein equation (SE). This result has been conjectured to be due to the presence of mobile particles, i.e., ones which have the propensity to "hop" distances that are integer multiples of the interparticle distan…
Barium titanate nanowires synthesized with a surfactant-free hydrothermal method have been characterized by various techniques such as transmission electron microscopy (TEM), scanning electron microscopy (SEM), synchrotron X-ray diffraction, X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. The TEM and S…
Porous single crystals of Cr 2 O 3 and Co 3 O 4 templated by mesoporous silicas, SBA-15 and KIT-6, have been fabricated. Specimens at different stages of crystal growth were characterized by using XRD and high-resolution transmission electron microscopy. The final products of oxide porous single crystals were also cha…
The use of magnetic micro- and nano-particles as carriers for in vivo targeting of therapeutic compounds was first proposed over 25 years ago. Since then, a variety of animal studies have demonstrated the efficacy of the technique, however, only a handful of Phase I/II clinical trials have taken place. While the theor…
A coupled-Bloch-mode model for explaining various optical properties of strongly modulated subwavelength lamellar gratings is proposed. The model evidences the key role played by propagative Bloch modes, which bounce inside the grating and couple at the grating interfaces. Many optical properties of these gratings, su…
Recently, there has been an increased interest in the problem of wave transmission through sub-wavelength apertures, following successful experimental demonstration by several groups for enhancing optical power transmission through nano-scale holes in metallic screens due to properly designed periodic corrugation. Oli…
We present a density-functional theory study addressing the on-surface adsorption of oxygen at the Pd(11N) (N =3,5,7) vicinal surfaces, which exhibit (111) steps and (100) terraces of increasing width. We find the binding to be predominantly governed by the local coordination at the adsorption site. This leads to very…
Currents across thin insulators are commonly taken as single electrons moving across classically forbidden regions; this independent particle picture is well-known to describe most tunneling phenomena. Examining quantum transport from a different perspective, i.e., by explicit treatment of electron-electron interactio…
In-situ synchrotron X-ray diffraction (XRD) was used to monitor the thermal decomposition (thermolysis) of Cd thiolates precursors embedded in a polymer matrix and the nucleation of CdS nanoparticles. A thiolate precursor/polymer solid foil was heated to 300 degrees C in the X-ray diffraction setup of beamline W1.1 at…
There is a huge and confusing literature about inorganic crystal structure prediction. The word "prediction" is used sometimes as meaning "structure determination" since the process described needs the knowledge of the chemical composition and of the cell parameters. Some clarifications are presented here together wit…
We present a new model of homogeneous aggregation that contains the essential physical ideas of the classical predecessors, the Becker-Doring and Lifshitz-Slyovoz models. These classical models, which give different predictions, are asymptotic limits of the new model at small (BD) and large (LS) cluster sizes. Since t…
Intrinsic optical transition energies for isolated and individual single wall carbon nanotubes grown over trenches are measured using tunable resonant Raman scattering. Previously measured E22_S optical transitions from nanotubes in surfactants are blue shifted 70-90 meV with respect to our measurements of nanotubes i…