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Immobilized Hyperbranched Glycoacrylate Films as Bioactive Supports

Sharmila Muthukrishnan、Mirko Nitschke、Stefan Gramm 等 7 位作者2006-07-31Macromolecular Bioscience

[Image: see text] We report on the low-pressure plasma immobilization, characterization and application of thin films of hyperbranched glycoacrylates, poly(3-O-acryloyl-alpha,beta-D-glucopyranoside) (AGlc), on PTFE-like fluorocarbon surfaces. This method is an efficient and versatile way to immobilize sugar-carrying b…

RNA Interference and Gene DeliveryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Novel Hybrid Polymer Brushes with Alternating Dendritic Wedges and Linear Side Chains

Yanhong Zhang、Xiaokai Li、Guohua Deng 等 4 位作者2006-07-31Macromolecular Chemistry and Physics

Abstract Summary: Novel hybrid polymer brushes with alternating dendritic wedge and linear chain as side chains were reported in this paper. Firstly, dendronized polymer initiators of generation one to three, G n MIBr ( n = 1, 2, 3), were synthesized through the alternating copolymerization of styryl dendrons and male…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Use of PP Grafted with Itaconic Acid as a New Compatibilizer for PP/Clay Nanocomposites

Edwin Moncada、Raúl Quijada、Ingo Lieberwirth 等 4 位作者2006-07-31Macromolecular Chemistry and Physics

Abstract Summary: Functionalized PP samples with different percentages of grafted IA, i.e., 0.7, 1 or 1.8 wt.‐%, with similar molecular weights were used as compatibilizers in PP/clay nanocomposites. PP nanocomposites containing 1 wt.‐% of organically modified clays, i.e., montmorillonite, natural hectorite and synthe…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

Flame‐retardant finishing of cotton fleece fabric: part I. The use of a hydroxy‐functional organophosphorus oligomer and dimethyloldihydroxylethyleneurea

Charles Q. Yang、Xiaoqun Qiu2006-07-31Fire and Materials

Abstract Cotton fleece has become a popular fashion in recent years. However, most of the 100% cotton fleece fabric is not able to meet the federal flammability standard (‘ 16 CFR Part 1610: Standard for the Flammability of Clothing Textiles ’) without chemical treatment. In this research, we investigated the use of t…

Fire dynamics and safety researchFlame retardant materials and properties

The New Silver Thiostannate (1,4‐dabH2)Ag2SnS4: Solvothermal Synthesis, Crystal Structure and Spectroscopic Properties

Nicole Pienack、Wolfgang Bensch2006-07-31Zeitschrift für anorganische und allgemeine Chemie

Abstract The new compound (1,4‐dabH 2 )Ag 2 SnS 4 (1,4‐dab = 1,4‐diaminobutane) was prepared under solvothermal conditions and crystallizes in the tetragonal space group P4 2 /n with lattice parameters a = 14.7847(8) Å, c = 11.9087(6) Å, V = 2603.1(2) Å 3 , Z = 8. In the structure SnS 4 tetrahedra and AgS 3 triangles…

Crystal Structures and PropertiesNanocluster Synthesis and ApplicationsOrganometallic Compounds Synthesis and Characterization

Undissociated screw dislocation in Si: Glide or shuffle set?

Cai‐Zhuang Wang、Ju Li、Kai‐Ming Ho 等 4 位作者2006-07-31Applied Physics Letters

In diamond and zinc blende crystals, the competition between glide and shuffle-set slips has been intensively studied. In particular, the undissociated screw dislocation in Si seen at low temperature about five years ago was generally believed to be shuffle set. In this letter, the authors have performed tight-binding…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsAdvanced Surface Polishing Techniques

Magnetic properties of ZnMnO films grown at low temperature by atomic layer deposition

Anna Wójcik、K. Kopalko、M. Godlewski 等 7 位作者2006-07-31Applied Physics Letters

The authors demonstrate that by lowering deposition temperature of ZnMnO films (T<500°C) they can avoid Mn clustering and creation of inclusions of Mn oxides, which are frequently formed in ZnMnO layers grown by high temperature methods. Low temperature growth is achieved using atomic layer deposition and organ…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsMagnetic and transport properties of perovskites and related materials

Application of principal component analysis to discriminate the Raman spectra of functionalized multiwalled carbon nanotubes

R.Y. Sato-Berrú、Elena V. Basiuk、José M. Sániger2006-07-31Journal of Raman Spectroscopy

Abstract Raman spectra of starting (pristine) and functionalized multiwalled carbon nanotubes (MWNTs) were analyzed by principal component analysis (PCA) because the original Raman spectra showed very little differences between them. The nanotubes were functionalized with amines: dodecylamine (MWNT1), nonylamine (MWNT…

Carbon Nanotubes in CompositesConducting polymers and applicationsMechanical and Optical Resonators

Possible liquid-liquid transition of gallium confined in opal

Cheng Tien、E. V. Charnaya、Wenya Wang 等 5 位作者2006-07-31Physical Review B

We have performed nuclear magnetic resonance (NMR) measurements on gallium confined in opal. In a cooling process, between 260 and $220\phantom{\rule{0.3em}{0ex}}\mathrm{K}$, the NMR spectra of gallium in opal exhibit two separate peaks at $\ensuremath{\sim}122.579\phantom{\rule{0.2em}{0ex}}48$ (low frequency, LF) and…

Material Dynamics and PropertiesTheoretical and Computational PhysicsSpectroscopy and Quantum Chemical Studies

Surfactant adsorption at superhydrophobic surfaces

Michele Ferrari、Francesca Ravera、Silvia Rao 等 4 位作者2006-07-31Applied Physics Letters

Here the wetting of ionic and nonionic surfactant solutions on a superhydrophobic interface, obtained by using a mixed inorganic-organic coating providing a fractal-like structure, has been investigated to define the role of adsorption at these interfaces. The presence of the amphiphilic molecules is effective in lowe…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferAdhesion, Friction, and Surface Interactions

Atomic layer deposition of W on nanoporous carbon aerogels

Jeffrey W. Elam、Joseph A. Libera、Michael J. Pellin 等 6 位作者2006-07-31Applied Physics Letters

In this study, the authors demonstrate the ability to apply precise, conformal W coatings onto all surfaces of nanoporous carbon aerogels using atomic layer deposition (ALD). The resulting material has a filamentous structure in which the W completely encapsulates the carbon aerogel strands. The material mass increase…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesAerogels and thermal insulation

Spin polarization of quaternary Co2Cr1−xFexAl Heusler alloys

S. V. Karthik、A. Rajanikanth、Y. K. Takahashi 等 5 位作者2006-07-31Applied Physics Letters

Point contact Andreev reflection measurements of Co2Cr1−xFexAl Heusler alloys showed that the spin polarization P decreases with x from P=0.62 for x=0.0toP=0.54 for x=0.4 and then increases slightly to P=0.56 for x=1.0. The deviation in P of the samples with x=0.0 and 0.4 from the theoretical predictions (P>0.9…

2D Materials and ApplicationsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Polycrystalline silicon-germanium heating layer for phase-change memory applications

Seung-Yun Lee、Kyu-Jeong Choi、Sang-Ouk Ryu 等 9 位作者2006-07-31Applied Physics Letters

This letter reports on the performance improvement of phase-change memory (PCM) cells by applying silicon-germanium (SiGe) alloys as resistive heating layers. The in situ doped polycrystalline Si0.75Ge0.25 films, lying under holes filled with a Ge2Sb2Te5 (GST) phase-change material in a pore-style configuration, promo…

Chalcogenide Semiconductor Thin FilmsTransition Metal Oxide NanomaterialsPhase-change materials and chalcogenides

Ferromagnetism on a paramagnetic host background: the case of rutile TM:TiO2single crystals (TM = Cr, Mn, Fe, Co, Ni, Cu)

L. Sangaletti、Maria Cristina Mozzati、Pietro Galinetto 等 7 位作者2006-07-31Journal of Physics Condensed Matter

Single crystals of TiO(2) rutile doped with Cr, Mn, Fe, Co, Ni, and Cu were grown with the flux method in a Na(2)B(4)O(7) melt. The samples, checked in their structural and phase homogeneity by x-ray diffraction and micro-Raman spectroscopy, were single-phase needle-shaped crystals several millimetres long. Paramagnet…

ZnO doping and propertiesMultiferroics and related materialsAdvanced Condensed Matter Physics

Orientation effect on microwave dielectric properties of Si-integrated Ba0.6Sr0.4TiO3 thin films for frequency agile devices

Hyun‐Suk Kim、Tae-Seon Hyun、Ho‐Gi Kim 等 6 位作者2006-07-31Applied Physics Letters

The effect of texture with (100) and (110) preferred orientations on dielectric properties of Ba0.6Sr0.4TiO3 (BST) thin films grown on SrO (9nm) and CeO2 (70nm) buffered Si substrates, respectively, was investigated. The coplanar waveguide (CPW) phase shifter using (100) oriented BST films on SrO buffered Si exhibited…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Magnetocaloric effect in potassium doped lanthanum manganite perovskites prepared by a pyrophoric method

Soma Das、T.K. Dey2006-07-31Journal of Physics Condensed Matter

The magnetocaloric effect (MCE) in fine grained perovskite manganites of the type La(1-x)K(x)MnO(3) (0<x<0.15) prepared by a pyrophoric method has been investigated. Potassium addition in lanthanum manganite enhances the Curie temperature (T(C)) of the system from 260.4 K (x = 0.05) to 309.7 K (x = 0.15). A large magn…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsThermal Expansion and Ionic Conductivity

Room temperature defect related electroluminescence from ZnO homojunctions grown by ultrasonic spray pyrolysis

Gaoming Du、Weifeng Liu、Jiming Bian 等 8 位作者2006-07-31Applied Physics Letters

ZnO homojunction light-emitting diode was grown on single-crystal GaAs (100) substrate by ultrasonic spray pyrolysis. This diode was comprised of N–In codoped p-type ZnO and unintentionally doped n-type ZnO film. Ohmic contact on n-type ZnO layer and GaAs substrate was formed by Zn∕Au and Au∕Ge∕Ni alloyed metal electr…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Thermal Degradation of Poly(1,3‐cyclohexadiene) and its Dehydrogenated Derivatives: Influence of a Controlled Microstructure

Itaru Natori、Shizue Natori2006-07-31Macromolecular Chemistry and Physics

Abstract Summary: The thermal degradation and carbonization of poly(1,3‐cyclohexadiene) (PCHD) with a controlled polymer chain, and its soluble dehydrogenated derivatives are reported for the first time. For PCHD, thermogravimetric (TG) analysis revealed a three‐stage thermal degradation. PCHD was completely decompose…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationFiber-reinforced polymer composites

Long-time behavior of the velocity autocorrelation function at low densities and near the critical point of simple fluids

R.F.A. Dib、Fouzia Ould-Kaddour、D. Levesque2006-07-31Physical Review E

Numerous theoretical and numerical works have been devoted to the study of the algebraic decrease at large times of the velocity autocorrelation function of particles in a fluid. The derivation of this behavior, the so-called long-time tail, generally based on linearized hydrodynamics, makes no reference to any specif…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

Surface activity and solubilization of a novel series of functional polyurethane surfactants

Dong Yang、Yong Jin、Deqing Wei2006-07-31Polymer International

Abstract Functional polyurethane surfactants (di‐block and tri‐block) were synthesized by addition polymerization of 2,4‐toluenediisocyanate with poly(propylene oxide) and monoallyl‐end‐capped poly(ethylene oxide). The chemical structure of the polyurethane surfactants was confirmed by Fourier transform infrared and 1…

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer composites and self-healing