Materials Literature
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The dc conductivity of poly(3-alkyl thiophenes) (P3ATs) and their cocrystals are measured in the temperature range of -130 to 150 degrees C. Both solvent-cast films and the melt-cooled films are used. The former exhibit a sharp increase followed by a decrease in conductivity, whereas the latter show only a sigmoidal i…
The electronic states and local structures of photomagnetic CuMo cyanides, ${\mathrm{Cu}}_{2}\mathrm{Mo}{(\mathrm{C}\mathrm{N})}_{8}∙{\mathrm{H}}_{2}\mathrm{O}$ and ${\mathrm{Cs}}_{0.5}{\mathrm{Cu}}_{1.75}\mathrm{Mo}{(\mathrm{C}\mathrm{N})}_{8}∙1.5{\mathrm{H}}_{2}\mathrm{O}$, have been studied by Cu and Mo $K$-edge x-…
A current sensing atomic force microscope (CS-AFM) was used to probe the conducting homogeneity and band structures of fully doped polyaniline (PANI) films prepared from in situ chemical polymerization/deposition of aniline on indium tin oxide in various inorganic acids. The charge transport properties of PANI films d…
Emission and excitation spectra of single crystals of ${\mathrm{Lu}}_{2}{\mathrm{Si}}_{2}{\mathrm{O}}_{7}$ doped with ${\mathrm{Ce}}^{3+}$, ${\mathrm{Pr}}^{3+}$, ${\mathrm{Nd}}^{3+}$, ${\mathrm{Sm}}^{3+}$, ${\mathrm{Eu}}^{3+}$, ${\mathrm{Tb}}^{3+}$, and ${\mathrm{Yb}}^{3+}$ were measured in the VUV and UV ranges in or…
At a low temperature of 450 degrees C, ZnS nanoribbons have been synthesized on Si and KCl substrates by a simple chemical vapor deposition (CVD) method with a two-temperature-zone furnace. Zinc and sulfur powders are used as sources in the different temperature zones. X-ray diffraction (XRD), selected area electron d…
The 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the -NC-Fe-CN-Mn- heterometallic structure, has been shown to exhibit light-induced excited spin-state trapping effects. After illumination, anti-ferromagnetic coupling was observed between the iron(II) (S = 2) and manganese(II) (S = 5/2) ions.
Abstract A quantitative model is described and verified to predict the growth of oil droplets by coalescence on a single nanofiber. The model considers a stream of fluid carrying many tiny droplets of a different fluid. The mechanisms by which the tiny droplets are captured by a drop growing on a fiber are considered.…
Fabrication conditions of microporous thermoplastic polyurethane to be used in small-diameter vascular grafts are studied. Porosity variations due to various factors such as concentration of PU solution, composition of coagulation bath, effect of coagulant temperature, and effect of dissolved air in PU solution are di…
ZnO nanostructures with different morphologies have been achieved by simple thermal evaporation of mixed powders of ZnS, graphite and SnO 2 at 1050 °C in a flowing Ar atmosphere. Branched nanobelts and wide nanosheets of ZnO were formed on Si wafers at a temperature of 700 and 500 °C, respectively. As for the branched…
The efficiency of the photochemical ring-opening of chromenes (or benzopyrans) depends on the vibronic transition selected by the chosen excitation wavelength. In the present work, ab initio CASPT2//CASSCF calculations are used to determine the excited-state ring-opening reaction coordinate for 2H-chromene (C) and 2,2…
Abstract Red phosphorus was combined with metallic oxides Fe 2 O 3 and MgO to improve the fire properties of recycled PET. Both Fe 2 O 3 and MgO act as co‐synergist agents at a total loading of 5 wt%. The analysis by diffraction X of the char formed during combustion shows that transformation of Fe 2 O 3 to Fe 3 O 4 o…
Abstract For Abstract see ChemInform Abstract in Full Text.
3-, 4-, and 2-ferrocenylazobenzenes, 1, 2, and 3, respectively, and several derivatives of 1 were synthesized, and their photoisomerization behaviors were examined. The molecular structures of 1 and its derivatives, 2-chloro-5-ferrocenylazobenzene (5) and 3-ferrocenyl-4'-hydroxylazobenzene (11), were determined by X-r…
We present the first observations of dc electric-field-induced rotational motion of finite particles in liquid crystals. We show that the electrorotation is essentially identical to the well-known Quincke rotation, which in liquid crystals triggers an additional translational motion at higher fields. In the smectic ph…
Zinc oxide films with ordered lamellar structures can be electrochemically produced by interfacial surfactant templating. This method utilizes amphiphile assemblies at the solid-liquid interface (i.e., the surface of a working electrode) as a template to electrodeposit inorganic nanostructures. To gain the ability to…
Equiatomic and near-equiatomic nickel-titanium alloys exhibit a shape-memory effect and superelasticity. However, the properties of such alloys are extremely sensitive to the precise nickel-titanium ratio and the addition of alloying elements. High corrosion resistance is necessary for biomedical applications, especia…
1H NMR, (13)C NMR, and EPR spectra of six-coordinate ferric porphyrin complexes [Fe(Por)L2]ClO4 with different porphyrin structures are presented, where porphyrins (Por) are planar 5,10,15,20-tetraphenylporphyrin (TPP), ruffled 5,10,15,20-tetraisopropylporphyrin (TiPrP), and saddled 2,3,7,8,12,13,17,18-octaethyl-5,10,…
Using a one-dimensional system, we demonstrate a wide variety of wave propagation phenomena possible in nonlinear left-handed media. These include effective second-harmonic generation where the fundamental wave and the second-harmonic wave are badly mismatched. We also observe parametric instabilities accompanying int…
We report on the growth of nominally undoped p-type ZnO films on Si(111) substrates by pulsed-laser deposition. Hall effect measurements show that the undoped ZnO films change from n-type to p-type material when the oxygen pressure changes from 6×10−5to3×10−4Torr during growth. Ti∕Au contacts produce ohmic behavior to…
Fine control of gold nanoparticle shape can be achieved by varying the pH of the reaction medium in the presence of gold nanorods, which acted as seeds. Under various pH (3.6–9.6) values of the reaction medium, different shapes of gold nanostructural architectures, from rectangle-, ‘dogbone’- and peanut-like outlines…