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A green-emitting CdSe/poly(butyl acrylate) nanocomposite

M. Peres、L. C. Costa、A.J. Neves 等 10 位作者2005-07-28Nanotechnology

CdSe/poly(butyl acrylate) nanocomposites were synthesized by in situ miniemulsion polymerization. The hybrid nanomaterial is very stable and presents a bright green photoluminescence at 2.29 eV under ultraviolet excitation. With the excitation conditions used the intensity of the emission band keeps nearly constant fr…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Interfacial debond of shape memory alloy composites

Chi-kin Poon、Limin Zhou、Wei Jin 等 4 位作者2005-07-28Smart Materials and Structures

A theoretical model for the prediction of interfacial behaviour is successfully developed for composites with pre-strained shape memory alloy (SMA) fiber. A two-cylinder model with a thin SMA fibre surrounding by epoxy matrix is employed for a pull-out test. The material constants and thermomechanical properties of th…

Innovative concrete reinforcement materialsShape Memory Alloy TransformationsInnovations in Concrete and Construction Materials

Ferromagnetic order in the electron-doped systemLa1−xCexCoO3

D. Fuchs、P. Schweiss、P. Adelmann 等 5 位作者2005-07-28Physical Review B

Highly electron-doped cobaltites of the system ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ce}}_{x}\mathrm{Co}{\mathrm{O}}_{3}\phantom{\rule{0.3em}{0ex}}(0.1\ensuremath{\leqslant}x\ensuremath{\leqslant}0.4)$ are synthesized by the growth of epitaxial thin films using pulsed laser deposition. Ferromagnetic order is obser…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsIron-based superconductors research

A Macrothermodynamic Approach to the Limit of Reversible Capillary Condensation

Philippe Trens、Nathalie Tanchoux、Anne Galarneau 等 8 位作者2005-07-28Langmuir

The threshold of reversible capillary condensation is a well-defined thermodynamic property, as evidenced by corresponding states treatment of literature and experimental data on the lowest closure point of the hysteresis loop in capillary condensation-evaporation cycles for several adsorbates. The nonhysteretical fil…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisAerogels and thermal insulation

The Anorthite–Diopside System: Structural and Devitrification Study. Part II: Crystallinity Analysis by the Rietveld–RIR Method

Luisa Barbieri、Federica Bondioli、Isabella Lancellotti 等 7 位作者2005-07-28Journal of the American Ceramic Society

The crystallization behavior of 10 binary glasses belonging to the CaO–MgO–Al 2 O 3 –SiO 2 quaternary system and two glasses corresponding to anorthite and diopside composition was investigated by X‐ray diffraction, thermal, and thermomechanical analyses, and scanning electron microscopy. Particular emphasis is laid o…

Glass properties and applicationsRecycling and utilization of industrial and municipal waste in materials productionNuclear materials and radiation effects

Large-scale controlled synthesis of silica nanotubes using zinc oxide nanowires as templates

Yujin Chen、Xinyu Xue、Taihong Wang2005-07-28Nanotechnology

We report on the controlled synthesis of silica nanotubes on a large scale using ZnO nanowires as templates. The ZnO nanowires are first coated with a uniform silica layer by a sol–gel method. Then silica nanotubes are obtained after removal of ZnO nanowires in diluted hydrochloric acid solution. The thickness of the…

Advanced Photocatalysis TechniquesGas Sensing Nanomaterials and SensorsMesoporous Materials and Catalysis

Formation of Polyelectrolyte Multilayer Architectures with Embedded DMPC Studied in Situ by Neutron Reflectometry

Christophe Delajon、Thomas Gutberlet、Roland Steitz 等 5 位作者2005-07-28Langmuir

The coupling of lipid molecules to polymer components in a planar biomimetic model membrane made of a lipid bilayer (dimyristoylphosphatidylcholine) supported by polyelectrolyte multilayers is studied. The polyelectrolyte support was prepared by layer-by-layer deposition of positively charged poly(allylamine hydrochlo…

Lipid Membrane Structure and BehaviorPolymer Surface Interaction StudiesMolecular Junctions and Nanostructures

Improved Synthesis of 2,2‘-Dibromo-9,9‘-spirobifluorene and Its 2,2‘-Bisdonor-7,7‘-bisacceptor-Substituted Fluorescent Derivatives

Chih‐Long Chiang、Ching‐Fong Shu、Chin‐Ti Chen2005-07-28Organic Letters

Pure 2,2'-Dibromo-9,9'-spirobifluorene was synthesized by a method that did not involve troublesome dibromination of 9,9'-spirobifluorene or Sandmeyer reaction of 2,2'-diamino-9,9'-spirobifluorene. A series of donor-acceptor orthogonally substituted 9,9'-spirobifluorene was subsequently prepared showing rich variation…

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Dynamic magnetostrain properties of giant magnetostrictive alloy actuators for damping

Tianli Zhang、Chengbao Jiang、Xiaolong Liu 等 4 位作者2005-07-28Smart Materials and Structures

Giant magnetostrictive alloy (GMA) actuators are tending to replace piezoelectric actuators in many applications owing to their giant magnetostrain and fast response. In an active vibration control system using GMA actuators, the investigation of dynamic magnetostrain can supply the basis for the optimization of actua…

Magnetic Properties and ApplicationsMagnetic Bearings and Levitation DynamicsLaser and Thermal Forming Techniques

Growth of ZnO nanorods from a salt mixture

А. Н. Баранов、Г. Н. Панин、Tae Wong Kang 等 4 位作者2005-07-28Nanotechnology

ZnO nanorods have been synthesized by growth from salt mixtures with a solution-processed Zn-containing precursor at high temperatures. The salt composition and the size of the Zn-containing precursor particles play a key role in the synthesis of ZnO nanorods and define their size and properties. The mechanism of the…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesGa2O3 and related materials

X-ray absorption and photoelectron spectroscopy studies on graphite and single-walled carbon nanotubes: Oxygen effect

Mamatimin Abbas、Z. Y. Wu、Jun Zhong 等 9 位作者2005-07-28Applied Physics Letters

We have investigated the electronic states of highly oriented pyrolitic graphite and single-walled carbon nanotubes using x-ray absorption spectroscopy (XAS) before and after annealing treatment in ultrahigh vacuum, and observed that the small peak between π* and σ* features, which has been previously assigned to free…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Dynamic Sequential Layer-by-Layer Deposition Method for Fast and Region-Selective Multilayer Thin Film Fabrication

Hyong-Jun Kim、Kangwon Lee、Sameer Kumar 等 4 位作者2005-07-28Langmuir

We present a newly devised technique, the dynamic layer-by-layer (LbL) deposition method, that is designed to take advantage of the LbL deposition method and fluidic devices. Polyelectrolyte solutions are sequentially injected through the fluidic LbL deposition device to quickly build well-defined multilayer films on…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Strain mechanism for order-parameter coupling through successive phase transitions inPrAlO3

Michael A. Carpenter、Christopher J. Howard、Brendan J. Kennedy 等 4 位作者2005-07-28Physical Review B

High-resolution powder neutron diffraction data have been collected at $\ensuremath{\sim}50$ temperatures between 4.2 and 300 K for perovskites ${\mathrm{Pr}}_{1\ensuremath{-}x}{\mathrm{La}}_{x}{\mathrm{AlO}}_{3}$ with $x=0$, 0.05, 0.1, and 0.25. Structural and lattice parameter data extracted by Rietveld refinement h…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsSolid-state spectroscopy and crystallography

A Tetrameric Sugar-Based Azobenzene That Gels Water at Various pH Values and in the Presence of Salts

Aasheesh Srivastava、Subir Ghorai、Anup Bhattacharjya 等 4 位作者2005-07-28The Journal of Organic Chemistry

A novel low-molecular mass tetrameric sugar derivative containing azobenzene core, 1, showed pronounced hydrogelation at micromolar concentration. Based on this observation, four related azobenzene based tetrameric sugar derivatives, 4-7, and three tetrameric sugar derivatives with a bis-terephthalamide core, 9-11, we…

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryPolydiacetylene-based materials and applications

Organic−Inorganic Hybrid Liquid Crystals: Thermotropic Mesophases Formed by Hybridization of Liquid-Crystalline Phosphates and Monodispersed α-Fe2O3 Particles

Kiyoshi Kanie、Atsushi Muramatsu2005-07-28Journal of the American Chemical Society

A novel organic-inorganic hybrid thermotropic liquid crystal (LC) is developed by the hybridization of an organic phosphate having a mesogenic core and monodispersed alpha-Fe2O3 particles with different shapes through the specific adsorption of the phosphate group to the surfaces parallel to the c-axis of the alpha-Fe…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Sintering Analysis of Undoped and Cobalt Oxide Doped Ceria Solid Solutions

Eva Jud、Christoph Huwiler、Ludwig J. Gauckler2005-07-28Journal of the American Ceramic Society

Pure and CoO 1– x ‐doped Ce 0.8 Gd 0.2 O 1.9 (CGO) have been analyzed with constant heating rate dilatometry. Doping changes the grain boundary structure of CGO resulting in enhanced mass transport and in increased densification rates. Significant changes in activation energies have been detected. While pure CGO exhib…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of Oxides

Partitioning and Assembly of Metal Particles and Their Bioconjugates in Aqueous Two-Phase Systems

Marcus R. Helfrich、Mahnaz El‐Kouedi、Mark R. Etherton 等 4 位作者2005-07-28Langmuir

The behavior of metal nanospheres and nanowires and their bioconjugates in aqueous two-phase systems (ATPS) is described. The ATPS used in this work comprised poly(ethylene glycol) (PEG), dextran, and water or aqueous buffer. Au and Ag nanospheres less than 100 nm in diameter partition between the PEG-rich and dextran…

Gold and Silver Nanoparticles Synthesis and ApplicationsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Giant field enhancement at carbon nanotube tips induced by multistage effect

Jianyu Huang、Krzysztof Kempa、Sung Ho Jo 等 5 位作者2005-07-28Applied Physics Letters

Recently, we have reported an extremely strong field emission from carbon nanotubes grown on carbon cloth, with the field-enhancement factor of up to 18 800. In this paper, we study the origins of this effect, by investigating field emission from individual carbon nanotubes, in a transmission electron microscope equip…

Carbon Nanotubes in CompositesGraphene research and applicationsMechanical and Optical Resonators

Nonlinear propagation of electromagnetic waves in negative-refraction-index composite materials

I. Kourakis、P. K. Shukla2005-07-28Physical Review E

We investigate the nonlinear propagation of electromagnetic waves in left-handed materials. For this purpose, we consider a set of coupled nonlinear Schrödinger (CNLS) equations, which govern the dynamics of coupled electric and magnetic field envelopes. The CNLS equations are used to obtain a nonlinear dispersion, wh…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsAdvanced Antenna and Metasurface Technologies

Nonlinear Magnetooptical Effects Caused by Piezoelectric Ferromagnetism in F43m-type Prussian Blue Analogues

Tomohiro Nuida、Tomoyuki Matsuda、Hiroko Tokoro 等 6 位作者2005-07-28Journal of the American Chemical Society

The second harmonic generation (SHG) and magnetization-induced SHG (MSHG) of AMA[MB(CN)6]-type (F3m) Prussian blue analogues (i.e., CsCo[Cr(CN)6].0.5H2O and RbMn[Fe(CN)6]) were observed. A large interaction between the nonlinear optical response and magnetic spins was observed in CsCo[Cr(CN)6].0.5H2O. These observatio…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies