Materials Literature
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A 1,2-dithienylethene compound bearing bis(phosphine) groups (1o) represents a new class of photoresponsive ligands where there are steric and electronic differences between two photogenerated isomers. The coordination chemistry of this ligand class is demonstrated by preparing a gold(I) complex (2o) and a phosphine s…
A comparative study on the phase behaviour of highly charged colloidal spheres in a confining wedge geometry, Fontecha, Ana Barreira, Schöpe, Hans Joachim, König, Hans, Palberg, Thomas, Messina, René, Löwen, Hartmut
Gel to glass transformation of methyltriethoxysilane was investigated using infrared and Raman spectroscopies. The vibrational frequencies of the Si−O network are found to be a sensitive probe of the gel to glass transformation, which is measured to be at ca. 950 °C for this system, under the experimental conditions u…
We report electric field-induced modulation of absorption in PbS nanocrystal quantum dots across the spectral region 600–2000nm, encompassing the entire telecommunications band. The maxima in the electroabsorption spectra correspond with the positions of the first excitonic peak, confirming the predominance of exciton…
Purest green! CePO4:Tb/LaPO4 core/shell nanowires with enhanced green photoluminescence (PL) have been synthesized by a simple hydrothermal method (see the PL spectrum). The fact that lattice parameters of the LnPO4 family are similar and that their crystal structures are identical is utilized to ensure that defects i…
Diverse ZnO integrated nanostructures, constructed by epitaxial nanowalls and symmetric single-crystalline nanosheets, were successfully synthesized via a strain-assisted self-catalyzed process at a low temperature of 500°C. The nanostructures started with the growth of ZnO nanowires, nucleated on a rugged ZnO single-…
Nanoparticles of a novel organic zwitterionic Meisenheimer complex, N',N' ',N' ''-tri(isopropyl)-4-oxo-6-(isopropyliminio)-2-s-(2H)triazinespiro-1'-2',4',6'-trinitrocyclohexadienylide, were synthesized by reprecipitation in water under different conditions. While reprecipitation alone resulted in a suspension of amorp…
In this letter, the full set of elastic coefficients of LaPO4 monazite is presented based on the first-principles plane-wave pseudopotential total energy method. Mechanical parameters (bulk modulus, shear modulus, Young’s moduli, and Poisson’s ratio) are also presented and compared with experimental results for polycr…
Colloidal silica gels are shown to stiffen with time, as demonstrated by both dynamic light scattering and bulk rheological measurements. Their elastic moduli increase as a power law with time, independent of particle volume fraction; however, static light scattering indicates that there are no large-scale structural…
We study electrochemical p- and n-type doping in the well-known light-emitting polymer poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV). Doping reactions are characterized using cyclic voltammetry. Optical measurements including photoluminescence and UV/Vis/NIR transmission were performed on doped s…
The electronic structure, lattice dynamics, and the electron-phonon coupling (EPC) in hole $(p)$-doped and electron $(n)$-doped diamonds have been extensively investigated using ab initio methods with the virtual crystal approximation. The calculations of $p$-doped diamond correctly reproduced all the essential proper…
Liquid-liquid and liquid-vapor coexistence regions of various water models were determined by Monte Carlo (MC) simulations of isotherms of density fluctuation-restricted systems and by Gibbs ensemble MC simulations. All studied water models show multiple liquid-liquid phase transitions in the supercooled region: we ob…
The C, N, and O K-edge near-edge X-ray absorption fine structure spectra of the 22 most common proteinogenic alpha-amino acids in the zwitterionic form collected from solvent-free polycrystalline powder films in the partial electron yield mode are reported. Spectral features common to all amino acids, as well as disti…
Halt, abliefern! Fluoresceinmoleküle, die in den Poren eines Kern-Schale-Systems aus mesoporösen Siliciumoxid-Nanostäbchen und superparamagnetischen Eisenoxid-Nanopartikeln eingeschlossen sind, werden in Gegenwart eines externen Magnetfelds freigesetzt, doch nur als Antwort auf in Zellen produzierte Antioxidantien. Da…
MgB2 thin films were deposited on SiC buffered Si substrates by sequential electron beam evaporation of B-Mg bilayer followed by in-situ annealing. The application of a SiC buffer layer enables the maximum annealing temperature of 830 C. The Transmission Electron Microscopy analysis confirms the growth of a nanogranul…
Experiments and simulations have been performed to examine the finite-temperature behavior of Ga$_{17}{}^{+}$ and Ga$_{20}{}^{+}$ clusters. Specific heats and average collision cross sections have been measured as a function of temperature, and the results compared to simulations performed using first principles Densi…
We study step bunching under conditions of attachment/detachment limited kinetics in the presence of a deposition or sublimation flux, which leads to bunch motion. Analysis of the discrete step dynamics reveals that the bunch velocity is inversely proportional to the bunch size for general step-step interactions. The…
The electronic and geometrical properties of bulk americium and square and hexagonal americium monolayers have been studied with the full-potential linearized augmented plane wave (FP-LAPW) method. The effects of several common approximations are examined: (1) non-spin polarization (NSP) vs. spin polarization (SP); (2…
We study the mixed valence transition ($T$$_{v}$ $\sim$80 K) in EuNi$_{2}$(Si$_{0.2}$Ge$_{0.8}$)$_{2}$ using Eu 3$d-4f$ X-ray absorption spectroscopy (XAS) and resonant photoemission spectroscopy (RESPES). The Eu$^{2+}$ and Eu$^{3+}$ main peaks show a giant resonance and the spectral features match very well with atom…
We present a detailed study of the phonon modes of the monoclinic compound BiB3O6 based on polarized reflectivity measurements on single crystals. The spectra are analysed by means of a generalized Drude-Lorentz model, which allows us to resolve the modes of A and B symmetry.