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Energy and Photoinduced Electron Transfer in a Wheel-Shaped Artificial Photosynthetic Antenna-Reaction Center Complex

Gerdenis Kodis、Yuichi Terazono、Paul A. Liddell 等 9 位作者2006-01-24Journal of the American Chemical Society

Functional mimics of a photosynthetic antenna-reaction center complex comprising five bis(phenylethynyl)anthracene antenna moieties and a porphyrin-fullerene dyad organized by a central hexaphenylbenzene core have been prepared and studied spectroscopically. The molecules successfully integrate singlet-singlet energy…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

Drop dynamics on chemically patterned surfaces

H. Kusumaatmaja、J. Leopoldes、A. Dupuis 等 4 位作者2006-01-24arXiv

We compare numerical and experimental results exploring the behaviour of liquid drops moving across a surface patterned with hydrophobic and hydrophilic stripes. A lattice Boltzmann algorithm is used to solve the hydrodynamic equations of motion of the drops allowing us to investigate their behaviour as the stripe wid…

Materials ScienceSoft Condensed Matterphysics.flu-dyn

Anomalous electronic correlations in ground state momentum density of Al$_{97}$Li$_3$

J. Kwiatkowska、B. Barbiellini、S. Kaprzyk 等 6 位作者2006-01-24arXiv

We report high resolution Compton scattering measurements on an Al$_{97}$Li$_3$ disordered alloy single crystal for momentum transfer along the [100], [110] and [111] symmetry directions. The results are interpreted via corresponding KKR-CPA (Korringa-Kohn-Rostoker coherent potential approximation) first principles co…

Materials ScienceStrongly Correlated Electrons

Focused ion beam preparation of atom probe specimens containing a single crystallographically well-defined grain boundary

F. Pérez-Willard、D. Wolde-Giorgis、T. Al-Kassab 等 7 位作者2006-01-24arXiv

Needle-shaped atom probe specimens containing a single grain boundary were produced using the focused ion beam (FIB) of a dual-beam FIB/SEM (scanning electron microscope) system. The presented specimen preparation approach allows the unprecedented study of a grain boundary which is well characterised in its crystallog…

Materials Science

Three real-space discretization techniques in electronic structure calculations

T. Torsti、T. Eirola、J. Enkovaara 等 16 位作者2006-01-24arXiv

A characteristic feature of the state-of-the-art of real-space methods in electronic structure calculations is the diversity of the techniques used in the discretization of the relevant partial differential equations. In this context, the main approaches include finite-difference methods, various types of finite-eleme…

Materials Science

Composite Silica Spheres with Magnetic and Luminescent Functionalities

Verónica Salgueiriño、Miguel A. Correa‐Duarte、M. Spasova 等 5 位作者2006-01-24OpenAlex

Abstract A new class of highly fluorescent, photostable, and magnetic core/shell nanoparticles in the submicrometer size range has been synthesized from a modified Stöber method combined with the layer‐by‐layer (LbL) assembly technique. Luminescent magnetic nanoparticles are prepared via two main steps. The first step…

Quantum Dots Synthesis And PropertiesPhotonic Crystals and ApplicationsPolymer Surface Interaction Studies

Physical Metallurgy of Titanium Alloys

Vydehi Arun Joshi2006-01-24OpenAlex

Titanium metal was first discovered by the English chemist William Gregor in 1971 in the black magnetic sand ilmenite, and the metal was named “titanium” after the titans of Greek mythology, a symbol of power and strength [1]. Titanium is the fourth-most-abundant metal in the Earth’s crust, the other three being alumi…

Aluminum Alloy Microstructure PropertiesAdvanced Welding Techniques AnalysisTitanium Alloys Microstructure and Properties

Preparation and characterisation of tractable regioregular head‐to‐tail poly(3‐alkylthiophene)s with ferrocene substituents

Ahmed Iraqi、David F. Pickup2006-01-23Polymer International

Abstract The preparation of a new ferrocene functionalised regioregular head‐to‐tail poly(3‐alkylthiophene) is presented. The polymer was obtained by post‐modification of a regioregular head‐to‐tail poly[3‐(6‐bromohexyl)thiophene] polymer and full functionalisation was achieved. The polymer is fully soluble in common…

Organic Electronics and PhotovoltaicsConducting polymers and applications

Thermal Stability of Nanocrystalline Sm 2 O 3 and Sm 2 O 3 –MgO

H. Sieger、J. Suffner、Horst Hahn 等 5 位作者2006-01-23Journal of the American Ceramic Society

Nanocrystalline Sm 2 O 3 and Sm 2 O 3 –MgO powders have been prepared by spray pyrolysis of aqueous precursor solutions containing citric acid as a complexant. Synthesized powders consist of hollow spheres with thin shells. The two‐phase samples exhibit an improved microstructural stability compared with pure Sm 2 O 3…

Advanced ceramic materials synthesisMicrowave Dielectric Ceramics SynthesisMagnesium Oxide Properties and Applications

One-dimensional diffusion of colloids in polymer solutions

Cheng‐Ying Chou、B. Eng、M. Robert2006-01-23The Journal of Chemical Physics

For colloid-polymer systems confined in one-dimensional channels, the diffusion of the colloidal particles is obtained by tracking individual particles using enhanced video microscopy and digital image analysis. For short times, the diffusion is normal, of the Fickian type, with mean-squared displacement varying linea…

Material Dynamics and PropertiesTheoretical and Computational PhysicsRheology and Fluid Dynamics Studies

Three homeotropically aligned nematic liquid crystals: Comparison of ultrafast to slow time-scale dynamics

Jie Li、Irène Wang、M. D. Fayer2006-01-23The Journal of Chemical Physics

The dynamics of two nematic liquid crystals, 4-(trans-4(')-n-octylcyclohexyl)isothiocyanatobenzene and 4-(4-pentyl-cyclohexyl)-benzonitrile, are investigated as a function of temperature both in the homeotropically aligned nematic phase and in the isotropic phase using optical heterodyne-detected optical Kerr effect e…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

Poly(amide imide)s and poly(amide imide) composite membranes by interfacial polymerization

P.R. Buch、D Jagan Mohan、A.V.R. Reddy2006-01-23Polymer International

Abstract Novel amic acid diamines (AADs) (2‐carboxyterephthalamido‐bis(alkyl or aryl amine)s, H 2 NXNH(O)CC 6 H 3 (COOH)C(O)NHXNH 2 , where X is magnified image were synthesized by reacting trimellitic anhydride chloride with aromatic or aliphatic diamines in dimethylformamide at 5–10 °C. Poly(amide imide)s (P…

Epoxy Resin Curing ProcessesMembrane Separation and Gas TransportSynthesis and properties of polymers

Broadband dielectric study of the glass transition in poly(ethyleneglycol)-water mixture

Seiichi Sudo、Mayumi Shimomura、Katsuhiko Kanari 等 5 位作者2006-01-23The Journal of Chemical Physics

We performed broadband dielectric measurements of a polyethyleneglycol-water mixture in the frequency range between 10 GHz and 1 microHz and the temperature range between 300 and 133 K. One relaxation process is observed throughout the whole temperature range. The temperature dependence of the relaxation time clearly…

Material Dynamics and PropertiesGlass properties and applicationsThermodynamic properties of mixtures

Interlayer Aharonov-Bohm Interference in Tilted Magnetic Fields in Quasi-One-Dimensional Organic Conductors

Benjamin Cooper、Victor M. Yakovenko2006-01-23Physical Review Letters

Different types of angular magnetoresistance oscillations in quasi-one-dimensional layered materials, such as organic conductors (TMTSF)2X, are explained in terms of Aharonov-Bohm interference in interlayer electron tunneling. A two-parameter pattern of oscillations for generic orientations of a magnetic field is visu…

Quantum and electron transport phenomenaMagnetism in coordination complexesOrganic and Molecular Conductors Research

Synthesis and characterization of poly(urethane‐ester)s based on calcium salt of mono(hydroxybutyl)phthalate

R. Arun Prasath、S. Nanjundan、Tadeusz Pakuła 等 4 位作者2006-01-23Journal of Applied Polymer Science

Abstract Calcium‐containing poly(urethane‐ester)s (PUEs) were prepared by reacting diisocyanate (HMDI or TDI) with a mixture of calcium salt of mono(hydroxybutyl)phthalate [Ca(HBP) 2 ] and hydroxyl‐terminated poly(1,4‐butylene glutarate) [HTPBG 1000 ], using di‐ n ‐butyltin‐dilaurate as catalyst. About six calcium‐con…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingSilicone and Siloxane Chemistry

Patents for Paper Deacidification

Martina Cedzová、Ingrid Gállová、Svetozár Katuščák2006-01-23Restaurator International Journal for the Preservation of Library and Archival Material

SUMMARIES The brittle-paper problem, i.e. the acid-catalyzed decay of cellulose originating from the invention of alum-rosin sizing at the beginning and of wood as a raw material for papermaking in the middle of the 19 th century, has challenged chemists and technicians to search for remedies. Since the beginning of r…

Advanced Cellulose Research Studies

Study on the Graft Reaction of Poly(propylene) Fiber with Acrylic Acid

Wei Wang、Li Wang、Xu Chen 等 6 位作者2006-01-23Macromolecular Materials and Engineering

Abstract Summary: In this paper, the graft of poly(propylene) fiber with acrylic acid is investigated. The effects of grafting temperature, monomer concentration, and grafting time on the grafting degree of acrylic acid onto poly(propylene) fiber are discussed. In contrast to the conventional method of determining the…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsFiber-reinforced polymer composites

Effect of Zn, Sr, and Y Addition on Electrical Properties of PZT Thin Films

Abhishek Dalakoti、Amit Bandyopadhyay、Susmita Bose2006-01-23Journal of the American Ceramic Society

We have investigated methods to increase the efficiency of piezoelectric micromachined ultrasonic transducers (pMUTs). pMUTs are driven by a thin piezoelectric layer on a Si membrane. The efficiency of pMUTs can be increased using a film with better ferroelectric properties. We have used Zn, Sr, and Y doping on PZT‐ba…

Ferroelectric and Piezoelectric MaterialsUltrasound Imaging and ElastographyAcoustic Wave Resonator Technologies

Large room-temperature magnetoresistance in Pd-added manganites

Xiaobo Yuan、Yihua Liu、Chengjian Wang 等 4 位作者2006-01-23Applied Physics Letters

A series of La0.67(Ca0.65Ba0.35)0.33MnO3∕Pdx composites were synthesized using a sol-gel method followed by a conventional solid-state reaction route. The results show that the resistivity of the composites decreases dramatically with Pd addition, while the room-temperature magnetoresistance (MR) increases remarkably.…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

In situ epitaxial growth of TiO2 on RuO2 nanorods with reactive sputtering

Kai‐Wen Cheng、Yu-Tsun Lin、Chun‐Yu Chen 等 8 位作者2006-01-23Applied Physics Letters

In this work, TiO2 deposition on RuO2 nanorods with reactive sputtering was studied. The TiO2 deposition was performed in situ after the RuO2 nanorod deposition at the same substrate temperature of 450 °C. The morphology examination and structure analysis have indicated a uniform and pure rutile TiO2 deposition on RuO…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides