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Investigation of Surface Structures of Dispersed V2O5 on CeO2−SiO2, CeO2−TiO2, and CeO2−ZrO2 Mixed Oxides by XRD, Raman, and XPS Techniques

Benjaram M. Reddy、Pandian Lakshmanan、Ataullah Khan2004-10-01The Journal of Physical Chemistry B

The techniques of X-ray diffraction (XRD), Raman spectroscopy (RS), and X-ray photoelectron spectroscopy (XPS) were employed to investigate dispersion and structural characteristics of V 2 O 5 /CeO 2 −MO 2 (M = Si 4+, Ti 4+, and Zr 4+ ) catalysts calcined at different temperatures from 773 to 1073 K. The CeO 2 −MO 2 (…

Radioactive element chemistry and processingCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

Deformation mechanisms and mechanical properties of modified polypropylene/wood fiber composites

Velichko Hristov、St. Vasileva、Marina Krumova 等 5 位作者2004-10-01Polymer Composites

Abstract Mechanical properties and deformation mechanisms of polypropylene (PP)/wood fiber (WFb) composites modified with maleated polypropylene as compatibilizer and styrene‐butadiene rubber (SBR) as impact modifier have been studied. The addition of maleated polypropylene to the unmodified polypropylene/wood fiber c…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Superparamagnetic iron oxide particles: contrast media for magnetic resonance imaging

Rüdiger Lawaczeck、M. Menzel、Hubertus Pietsch2004-10-01Applied Organometallic Chemistry

Abstract The mainstream magnetic iron oxide particles used as contrast media for magnetic resonance (MR) imaging are composed of a magnetic iron oxide core surrounded by a dextran or carboxydextran coat. The core size ranges from 2 nm to less than 10 nm, and the hydrodynamic diameter ranges from 20 nm to about 120 nm.…

Advanced MRI Techniques and ApplicationsCharacterization and Applications of Magnetic NanoparticlesNanoparticle-Based Drug Delivery

Macroporous Zeolitic Membrane Bioreactors

Yajun Wang、Frank Caruso2004-10-01Advanced Functional Materials

Abstract A simple and effective method is described for the fabrication of robust zeolitic membranes with three‐dimensional (3D) interconnected macroporous structures. The membranes were prepared by electrostatically seeding mesoporous silica sphere (MSS) self‐assembled films with silicalite‐1 nanoparticles, followed…

Polymer Surface Interaction StudiesElectrochemical sensors and biosensorsMesoporous Materials and Catalysis

Preparation of Hydroxyapatite Fibers by Electrospinning Technique

Yiquan Wu、Larry L. Hench、Jing Du 等 5 位作者2004-10-01Journal of the American Ceramic Society

Hydroxyapatite (Ca 10 (PO 4 ) 6 (OH) 2 , HA) fibers were prepared by electrospinning a precursor mixture of Ca(NO 3 ) 2 ·4H 2 O and (C 2 H 5 O) 3 PO with a polymer additive, followed by a thermal treatment. The X‐ray diffraction (XRD) analysis of the annealed composite fibers revealed that pure HA phase could be obtai…

Additive Manufacturing and 3D Printing TechnologiesBone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical Applications

UV aging of poly(propylene)/wood‐fiber composites

R. Seldén、Birgitha Nyström、Runar Långström2004-10-01Polymer Composites

Abstract The effect of accelerated UV‐aging on properties of PP/wood‐fiber composites has been studied. Plates containing 0, 25 and 50 wt% wood‐fibers were subjected to accelerated UV‐aging in a QUV weatherometer for up to 8 weeks. Stabilization against UV‐degradation was made by adding 3% of a UV stabilizer. The resu…

Polymer crystallization and propertiesFiber-reinforced polymer compositesNatural Fiber Reinforced Composites

New Freeze‐Casting Technique for Ceramics with Sublimable Vehicles

Kiyoshi Araki、John W. Halloran2004-10-01Journal of the American Ceramic Society

A new ceramic freeze‐casting technique capable of manufacturing near room temperature with a sublimable vehicle was accomplished. Fluid‐concentrated slurries of Al 2 O 3 powder in molten camphene (C 10 H 16 ) were prepared at 55°C. These slurries were quickly solidified (frozen) at room temperature to yield rigid soli…

Injection Molding Process and PropertiesGlass properties and applicationsAdvanced ceramic materials synthesis

Nanocarpet Effect: Pattern Formation during the Wetting of Vertically Aligned Nanorod Arrays

J.-G. Fan、David L. Dyer、G. Zhang 等 4 位作者2004-10-01Nano Letters

When a water droplet spreads on a vertically aligned nanorod surface, the nanorod array will deform into statistically percolated patterns. This nanocarpet effect has been investigated for Si nanorods. Three distinct morphologies were found: a center region due to the water droplet impact, a tilting region due to grav…

Nanomaterials and Printing TechnologiesFluid Dynamics and Thin FilmsSurface Modification and Superhydrophobicity

Measurement and prediction of diffusion coefficients of supercritical CO 2 in molten polymers

Surat Areerat、Eita Funami、Yusuke Hayata 等 5 位作者2004-10-01Polymer Engineering and Science

Abstract The solubility and diffusivity of supercritical carbon dioxide (sc‐CO 2 ) in low‐density polyethylene (LDPE), high‐density polyethylene (HDPE), polypropylene (PP), ethylene‐ethylacrylate copolymer (EEA) and polystyrene (PS) were measured at temperatures from 150°C to 200°C and pressures up to 12 MPa by using…

Polymer crystallization and propertiesPhase Equilibria and ThermodynamicsPolymer Foaming and Composites

Adsorption of S—S Containing Proteins on a Colloidal Silver Surface Studied by Surface-Enhanced Raman Spectroscopy

Edyta Podstawka、Yukihiro Ozaki、Leonard M. Proniewicz2004-10-01Applied Spectroscopy

We present a Raman and surface-enhanced Raman scattering (SERS) study of the following proteins containing S-S group(s): alpha chymotrypsin (alpha-CHT), insulin, lysozyme, oxytocin (OXT), Streptomyces subtilisin inhibitor (SSI), and trypsin inhibitor (STI). The SERS study is performed in order to understand the adsorp…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsProtein Interaction Studies and Fluorescence Analysis

Oxygen Diffusion in Yttria‐Stabilized Zirconia: A New Simulation Model

Ramanathan Krishnamurthy、Young‐Gui Yoon、David J. Srolovitz 等 4 位作者2004-10-01Journal of the American Ceramic Society

We present a multiscale modeling approach to study oxygen diffusion in cubic yttria‐stabilized zirconia. In this approach, we employ density functional theory methods to calculate activation energies for oxygen migration in different cation environments. These are used in a kinetic Monte Carlo framework to calculate l…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsCatalytic Processes in Materials Science

Extensional Viscosity of Coating Colors and its Relation With Jet Coating Performance

Arzate A.、Ascanio G.、Carreau P.J. 等 4 位作者2004-10-01Applied Rheology

An orifice flowmeter was used to measure the extensional viscosity of several non-pigmented fluids and paper coating colors containing calcium carbonate as pigment in the context of a jet coating application. The orifice flowmeter was first calibrated in terms of a dimensionless Euler number versus Reynolds number cur…

Patents

Fischer Peter、Kroger Martin2004-10-01Applied Rheology

Physical Properties of Polymers

Walter Richtering2004-10-01Applied Rheology

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Material Properties and ProcessingPolymer Nanocomposites and PropertiesPolymer crystallization and properties

Rheological Studies of Interferon Creams

Zumalacárregui Lourdes、Vázquez Miguel、Estévez Tania 等 5 位作者2004-10-01Applied Rheology

The determination of flow curves and the apparent viscosity curves at 28°C of creams containing human leukocyte alpha interferon as active principle is presented in this paper. These creams are used for the treatment of papiloma virus and herpes simplex. It is demonstrated that their behaviour corresponds to a thixotr…

Nanocompósitos de matriz polimérica: estratégias de síntese de materiais híbridos

A. Catarina C. Esteves、Ana Barros‐Timmons、Tito Trindade2004-10-01Química Nova

Associating the well known advantages of hybrid materials to the wide potential of nanomaterials, the new and featuring class of polymer nanocomposites turned into one of the most intensively researched areas. This review highlights recent developments in the field of the synthesis of polymer based nanocomposites. Imp…

Mesoporous Materials and CatalysisPolymer Nanocomposites and Properties