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In Situ Depositing Silver Nanoclusters on Silk Fibroin Fibers Supports by a Novel Biotemplate Redox Technique at Room Temperature

Qun Dong、Huilan Su、Di Zhang2005-08-25The Journal of Physical Chemistry B

Evolvement of bioinspired approaches for the construction of well-ordered nanostructures is a crucial intersection of branches of materials science and biotechnology. In this paper, floriated clusters of silver nanocrystallites, which consist of polycrystalline grains about 5 nm in diameter, have been successfully pre…

Gold and Silver Nanoparticles Synthesis and ApplicationsSilk-based biomaterials and applicationsNanocluster Synthesis and Applications

Exothermic water dissociation on the rutileTiO2(110)surface

Philip J. D. Lindan、Changjun Zhang2005-08-25Physical Review B

There has been a long-running debate among theorists and experimentalists on the precise nature of water adsorption at the $\mathrm{Ti}{\mathrm{O}}_{2}(110)$ surface. Some experimentalists argue that dissociative adsorption occurs only at defect sites (O vacancies) and therefore at low coverages. Although there is no…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Energy-resolved electron-spin dynamics at surfaces of p-doped GaAs

H. C. Schneider、J. -P. Wuestenberg、O. Andreyev 等 10 位作者2005-08-25arXiv

Electron-spin relaxation at different surfaces of p-doped GaAs is investigated by means of spin, time and energy resolved 2-photon photoemission. These results are contrasted with bulk results obtained by time-resolved Faraday rotation measurements as well as calculations of the Bir-Aronov-Pikus spin-flip mechanism. D…

Materials Science

Fast and Stable Photochromic Oxazines

Massimiliano Tomasulo、Salvatore Sortino、Andrew J. P. White 等 4 位作者2005-08-25The Journal of Organic Chemistry

We have designed and synthesized two photochromic compounds incorporating fused indoline and benzooxazine fragments. Variable-temperature 1H NMR spectroscopy demonstrates that their central [1,3]oxazine ring opens thermally with free energy barriers ranging from 14 to 19 kcal mol(-1). The ring-opened species reverts r…

Photochromic and Fluorescence ChemistrySynthesis of Indole DerivativesPolydiacetylene-based materials and applications

Interactions of spin waves with a magnetic vortex

J. P. Park、P. A. Crowell2005-08-25arXiv

We have investigated azimuthal spin-wave modes in magnetic vortex structures using time-resolved Kerr microscopy. Spatially resolved phase and amplitude spectra of ferromagnetic disks with diameters from 5 $μ$m down to 500 nm reveal that the lowest order azimuthal spin wave mode splits into a doublet as the disk size…

Materials Science

Electron spin-orbit splitting in InGaAs/InP quantum well studied by means of the weak antilocalization and spin-zero effects in tilted magnetic fields

S. A. Studenikin、P. T. Coleridge、G. Yu 等 4 位作者2005-08-25arXiv

The coupling between Zeeman spin splitting and Rashba spin-orbit terms has been studied experimentally in a gated InGaAs/InP quantum well structure by means of simultaneous measurements of the weak antilocalization (WAL) effect and beating in the SdH oscillations. The strength of the Zeeman splitting was regulated by…

Mesoscale and Nanoscale PhysicsMaterials Science

Adsorption and diffusion of Pt and Au on the stoichiometric and reducedTiO2rutile (110) surfaces

Hakim Iddir、Serdar Öğüt、Nigel D. Browning 等 4 位作者2005-08-25Physical Review B

A comparative ab initio pseudopotential study of the adsorption and migration profiles of single neutral Pt and Au atoms on the stoichiometric and reduced $\mathrm{Ti}{\mathrm{O}}_{2}$ rutile (110) surfaces is presented. Pt and Au behave similarly with respect to (i) most favorable adsorption sites, (ii) the large inc…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Microwave Synthesis of Supported Au and Pd Nanoparticle Catalysts for CO Oxidation

Garry Glaspell、Lindsay Fuoco、M. Samy El‐Shall2005-08-25The Journal of Physical Chemistry B

We report the microwave synthesis and characterization of Au and Pd nanoparticle catalysts supported on CeO2, CuO, and ZnO nanoparticles for CO oxidation. The results indicate that supported Au/CeO2 catalysts exhibit excellent activity for low-temperature CO oxidation. The Pd/CeO2 catalyst shows a uniform dispersion o…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingNanomaterials for catalytic reactions

High Frictional Anisotropy of Periodic and Aperiodic Directions on a Quasicrystal Surface

Jeong Young Park、D. Frank Ogletree、Miquel Salmerón 等 7 位作者2005-08-25Science

Strong friction anisotropy is found when the twofold surface of an atomically clean aluminum-nickel-cobalt quasicrystal slides against a thiol-passivated titanium-nitride tip. Friction along the aperiodic direction is one-eighth as much as that along the periodic direction. This anisotropy, which is about three times…

Microstructure and mechanical propertiesForce Microscopy Techniques and ApplicationsQuasicrystal Structures and Properties

A Review of Heat Transfer Issues in Hydrogen Storage Technologies

Jinsong Zhang、Timothy S. Fisher、P. Veeraraghavan Ramachandran 等 5 位作者2005-08-25ASME Journal of Heat and Mass Transfer

Significant heat transfer issues associated with four alternative hydrogen storage methods are identified and discussed, with particular emphasis on technologies for vehicle applications. For compressed hydrogen storage, efficient heat transfer during compression and intercooling decreases compression work. In additio…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsSpacecraft and Cryogenic Technologies

Large thermoelectric performance of heavily Nb-doped SrTiO3 epitaxial film at high temperature

Shingo Ohta、Takashi Nomura、Hiromichi Ohta 等 6 位作者2005-08-25OpenAlex

Carrier concentration dependence of the thermoelectric figure of merit, ZT of SrTiO3 at high-temperature (1000 K) is clarified using heavily Nb-doped SrTiO3 epitaxial films, which were grown on insulating (100)-oriented LaAlO3 single-crystalline substrates by a pulsed-laser deposition method. Carrier concentration, Ha…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

Electron Microprobe Analysis and Scanning Electron Microscopy in Geology

S. J. B. Reed2005-08-25OpenAlex

Originally published in 2005, this book covers the closely related techniques of electron microprobe analysis (EMPA) and scanning electron microscopy (SEM) specifically from a geological viewpoint. Topics discussed include: principles of electron-target interactions, electron beam instrumentation, X-ray spectrometry,…

Geophysical and Geoelectrical MethodsElectron and X-Ray Spectroscopy TechniquesChemical and Physical Properties of Materials

Polymer dispersed liquid crystals for high efficiency displays

Paul Drzaic2005-08-24OpenAlex

Polymer dispersed liquid crystal (PDLC) films serve as the basis for a variety of high-efficiency electro-optical effects. In the most general sense, as PDLC materials consists of micron-sized domains of a liquid crystal, with the domain size determined by a continuous polymer matrix running through the film. Dependin…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced Optical Imaging Technologies

Temporary extrusion failures in accelerated lifetime tests of copper interconnects

Y. Zhang、Jun-Ho Choy、Glenn H. Chapman 等 4 位作者2005-08-24IEEE Electron Device Letters

A novel electromigration failure mode was detected in 0.13-μm technology, copper dual damascene interconnects. Extrusions formed between the test lead and neighboring monitor lines, resulting in short-circuit failure. However, many of these extrusions were short lived, shrinking within a period of a minute to an hour.…

Metal and Thin Film MechanicsElectronic Packaging and Soldering TechnologiesCopper Interconnects and Reliability

Magnetic quantum oscillations of quasi-two-dimensional conductors with one-dimensional potential modulation

V. M. Gvozdikov2005-08-24Physical Review B

An analytic theory for the de Haas--van Alphen (dHvA) oscillations in layered conductors with a periodic one-dimensional (1D) potential within the planes is developed. The periodic modulation potential yields an additional factor $I(p)$ in the Lifshitz-Kosevich harmonic series which modulates the dHvA oscillation ampl…

Physics of Superconductivity and MagnetismQuantum and electron transport phenomenaOrganic and Molecular Conductors Research

Adaptive control of plants with unknown hystereses

Gang Tao、P.V. Kokotović2005-08-24OpenAlex

The authors present a parametrized hysteresis model and develop a hysteresis inverse. They then design adaptive controllers with an adaptive hysteresis inverse for plants with unknown hystereses. A novel adaptive controller structure is introduced which is capable of achieving a linear parametrization and a linear err…

Shape Memory Alloy TransformationsMagnetic Properties and ApplicationsPiezoelectric Actuators and Control

Multilayer Capsules with Cell‐like Topology: Fabrication and Spontaneous Loading of Various Substances in Aqueous and Ethanol Solutions

Weijun Tong、Wen‐Fei Dong、Changyou Gao 等 4 位作者2005-08-24Macromolecular Chemistry and Physics

Abstract Summary: Multilayer microcapsules are fabricated by layer‐by‐layer assembly of sodium poly(styrene sulfonate) (PSS) and poly(allylamine hydrochloride) (PAH) on porous CaCO 3 microparticles, followed by removal of the sacrificial template. Confocal microscopy (CLSM) reveals that the obtained capsules have poly…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Modular Rtg Technology Status

Robert F. Hartman2005-08-24OpenAlex

MOD-RTG represents the design configuration for the next generation of Radioisotope Thermoelectric Generator (RTG), aimed at improving specific power over current General Purpose Heat Source Radioisotope Thermoelectric Generators (GPHS-RTGs). As part of the MOD-RTG development program sponsored by the Office of Specia…

Graphite, nuclear technology, radiation studiesNuclear and radioactivity studiesAdvanced Energy Technologies and Civil Engineering Innovations

Fundamental structure of a Ni2MnGa intermediate phase having an orthorhombic lattice

Takuya Ohba、Naohiro Miyamoto、Koudai Fukuda 等 6 位作者2005-08-24Smart Materials and Structures

Ni 2 MnGa is one of the attractive ferromagnetic shape memory alloys. It is reported that the parent phase is of Heusler type and transforms into an intermediate phase above M s . As regards the crystal structure of the intermediate phase, it was previously reported that the fcc main reflection remained and additional…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsHeusler alloys: electronic and magnetic properties

Grain boundary sliding and migration in copper: Vacancy effect

P. Ballo、Jarmila Degmová、Vladimı́r Slugeň2005-08-24Physical Review B

We investigated the interaction between the vacancy and $\ensuremath{\Sigma}5$ (210)[001] symmetric tilt grain boundary during the sliding by taking copper as a model material. The geometry optimization was done by simulating an annealing process at elevated temperature. For interatomic interaction we used an empirica…

Microstructure and mechanical propertiesCopper Interconnects and ReliabilitySurface and Thin Film Phenomena