Materials Literature
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With the surge of research in quantum information, the issue of producing entangled states has gained prominence. Here, we show that judiciously bringing together two systems of strongly interacting electrons with vastly differing ground states-the gapped BCS superconductor and the Luttinger liquid-can result in quant…
Optical excitations in hexagonal nanonetwork materials, for example, Boron-Nitride (BN) sheets and nanotubes, are investigated theoretically. The bonding of BN systems is positively polarized at the B site, and is negatively polarized at the N site. There is a permanent electric dipole moment along the BN bond, whose…
An extremal model for the plasticity of amorphous materials is studied in a simple two-dimensional anti-plane geometry. The steady-state is analyzed through numerical simulations. Long-range spatial and temporal correlations in local slip events are shown to develop, leading to non-trivial and highly anisotropic scali…
The Josephson current in the presence of a precessing spin between various types of superconductors is studied. It is shown that the Josephson current flowing between two spin-singlet pairing superconductors is not modulated by the precession of the spin. When both superconductors have equal-spin-triplet pairing state…
A simple experimentally accessible realization of current rectification by molecules (molecular films) bridging metal electrodes is described. It is based on the spatial asymmetry of the molecule and requires only one resonant conducting molecular level (pi-orbital). The rectification, which is due to asymmetric coupl…
We have investigated a single crystal of CeAgSb2 using low field ac-susceptibility, thermal expansion and magnetostriction measurements in the temperature range 1.5K to 90K. The ac-susceptibility exhibits a sharp peak at 9.7K for both B//c and B perp c due to the magnetic ordering of the Ce moment. The thermal expansi…
In the process of molecular dynamics simulation studies of gold nanowires an interesting structure is discovered. This is a finite double-wall nanowire with a large empty core similar to single-wall and double-wall carbon nanotubes. The structure of the 16-10 gold nanotube is studied at the room temperature. An invest…
The good performance of the GW approximation for band-structure calculations in solids was long taken as a sign that the sum of self-energy diagrams is converged and that all omitted terms are small. However, with modern computational resources it has now become possible to evaluate self-consistency and vertex correct…
We present measurements of the magnetic susceptibility and of the thermal expansion of a ${\mathrm{LaCoO}}_{3}$ single crystal. Both quantities show a strongly anomalous temperature dependence. Our data are consistently described in terms of a spin-state transition of the ${\mathrm{Co}}^{3+}$ ions with increasing temp…
Amorphous B−C−N ceramics were produced by thermolysis of poly(borosesquicarbodiimide) of idealized formula [B 2 (NCN) 3 ] n at 1100 °C in an argon atmosphere. Their structure was investigated by X-ray and neutron diffraction. Wide-angle diffraction showed that the ceramics consist of an amorphous structure with hexago…
Semiempirical Hartree-Fock techniques are widely used to study properties of long ring-structured chains, although these types of systems were not included in the original parametrization ensembles. These techniques are very useful for an ample class of studies, and their predictive power should be tested. We present…
A generalized Ginzburg-Landau-Devonshire free energy has been used to describe the influence of imperfect surface layers or interface layers in ferroelectric thin films. The natural boundary condition has been employed in solving the polarization profile, which can reflect a more realistic situation compared to the pr…
The IR spectra of O3 adsorbed on polycrystalline (high surface area) MgO are reported and assigned. Two distinct groups of absorptions in the 1160–970 and 1730–1170 cm−1 spectral regions were observed. The bands falling in the first region, fully reversible upon decreasing the O3 pressure, are grouped into two doublet…
Three aspects of the esterification reaction of silica surfaces with alcohols that are relevant for the synthesis of functional materials have been studied: surface coverage, hydrolytic stability, and the introduction of functional groups. The chemisorption of alcohols on silica can be described by the Langmuir adsorp…
We have investigated the adsorption, decomposition and oxidation of methanol on a well-defined supported Pd model catalyst, utilizing a combination of molecular beam methods, reflection absorption IR spectroscopy (RAIRS) and temperature-programmed desorption (TPD). The Pd model catalyst is prepared under ultrahigh-vac…
Core-shell ensembles of citrate-stabilized gold nanoparticles (20-80 nm) on submicron silica cores (330-550 nm) have been prepared by electrostatic self-assembly with shell packing densities as high as phi = 0.55.
Abstract A new triphenylamine‐containing aromatic diamine, N , N ′‐bis(4‐aminophenyl)‐ N , N ′‐diphenyl‐1,4‐phenylenediamine, was prepared by the condensation of N , N ′‐diphenyl‐1,4‐phenylenediamine with 4‐fluoronitrobenzene, followed by catalytic reduction. A series of novel aromatic polyamides with triphenylamine u…
The synthesis of a series of polymeric Eu(III) complexes with polyester ligands, along with supporting emission spectra, luminescence lifetimes, and, for a Eu block copolymer film, atomic force microscopy (AFM) data, is presented. Dibenzoylmethane was derivatized with a hydroxyl initiator site (dbmOH, 1) for tin octoa…
This paper reports a computational method, the quantized elastic deformational model, that can reliably describe the conformational flexibility of a protein in the absence of the amino acid sequence and atomic coordinates. The essence of this method lies in the fact that, in modeling the functionally important conform…
Superconducting MgB2 thin films were prepared on 50-micrometer-thick, flexible polyamide Kapton-E foils by vacuum co-deposition of Mg and B precursors with nominal thickness of about 100 nm and a special ex-situ rapid annealing process in an Ar or vacuum atmosphere. In the optimal annealing process, the Mg-B films wer…