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Experimental and theoretical characterisation of sonochemical cells. : Part 2: cell disruptors (Ultrasonic horns) and cavity cluster collapse

Peter R. Birkin、Douglas G. Offin、T.G. Leighton2005-01-01Physical Chemistry Chemical Physics

Cavitation theory is used to predict the acoustic pressure at the boundary of the inertial/non inertial threshold for a range of bubble sizes. The sound field generated from a commonly employed sonoelectrochemical cell is modelled. The model is tested with a calibrated hydrophone far from the transducer to avoid spati…

Ultrasound and Hyperthermia ApplicationsCombustion and Detonation ProcessesUltrasound and Cavitation Phenomena

New photoactive hybrid organic–inorganic materials based on titanium-oxo-PHEMA nanocomposites exhibiting mixed valence properties

O. Kameneva、A. I. Kuznestov、Л. А. Смирнова 等 9 位作者2005-01-01Journal of Materials Chemistry

Transparent monoliths made of new interpenetrating networks based on titanium-oxo-poly(hydroxyethyl methacrylate) (PHEMA) nanocomposites are obtained through one pot synthesis with low shrinking and show a strong laser-induced darkening activity.

Catalysis and Oxidation ReactionsAerogels and thermal insulationSilicone and Siloxane Chemistry

Review: Multiscale Thermal Modeling in Nanoelectronics

Sanjiv Sinha、K.E. Goodson2005-01-01International Journal for Multiscale Computational Engineering

Subcontinuum phonon conduction phenomena impede the cooling of field-effect transistors with gate lengths less than 100 nm, which degrades their performance and reliability. Thermal modeling of these nanodevices requires attention to a broad range of length scales and physical phenomena, ranging from continuum heat di…

Semiconductor materials and devicesAdvancements in Semiconductor Devices and Circuit DesignThermal properties of materials

Vanadium Alloys for Fusion Blanket Applications

T. Muroga2005-01-01MATERIALS TRANSACTIONS

Vanadium alloys are attractive candidate structural materials for breeding blanket of fusion reactors because of their low activation properties and high temperature strength. Studies on various blanket designs are being carried out using vanadium alloys as structural materials and liquid lithium or molten salt Flibe…

Magnetic confinement fusion researchFusion materials and technologiesNuclear Materials and Properties

Investigation of solubility of microcrystalline cellulose in aqueous NaOH

Yen-Ning Kuo、Juan Hong2005-01-01Polymers for Advanced Technologies

A cost-effective and environmentally friendly method to dissolve microcrystalline cellulose (MCC) has been utilized. A detailed investigation of the effects of cellulose amount and solvent (aqueous NaOH) concentration on MCC solubility has been presented. In the experiments, NaOH solutions with concentrations ranging…

Advanced Cellulose Research StudiesLignin and Wood ChemistryMaterial Properties and Processing

Plasma treatment of polyurethane coating for improving endothelial cell growth and adhesion

S. De、Rohit Sharma、Steve Trigwell 等 7 位作者2005-01-01Journal of Biomaterials Science Polymer Edition

The advantage of helium plasma treatment in enhancing endothelial cell growth and adhesion on polyurethane film coated on glass substrate is demonstrated with experimental data. Human coronary artery endothelial cell (HCAE) growth and attachment was studied on (1) bare glass substrate, used as control, (2) coated glas…

Reconstructive Surgery and Microvascular TechniquesElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposite Synthesis and Irradiation

Electrical Conduction Properties of Sr-Doped LaPO[sub 4] and CePO[sub 4] under Oxidizing and Reducing Conditions

Naoto Kitamura、Koji Amezawa、Yoichi Tomii 等 7 位作者2005-01-01Journal of The Electrochemical Society

Electrical conduction properties of Sr-doped and Sr-doped under and conditions were investigated with conductivity measurements. Conductivities of Sr-doped were at under wet reducing conditions and were close to those under wet oxidizing conditions. It was found from the H/D isotope effect on conductivity that the mat…

Advanced Battery Materials and TechnologiesAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

End functionalised liquid crystalline bent-core molecules and first DAB derived dendrimers with banana shaped mesogenic units

Dorota KardasPresent address Agricultural、Marko Prehm、Ute Baumeister 等 7 位作者2005-01-01Journal of Materials Chemistry

New series of non-symmetric bent-core compounds with a terminal carboxylic function as well as its benzyl esters and pentafluorophenyl esters have been synthesised. For most pentafluorophenylesters and for a benzylester with fluorine atoms in the ortho positions to the alkoxy chain different types of columnar ribbon p…

Liquid Crystal Research AdvancementsDendrimers and Hyperbranched PolymersPhotochromic and Fluorescence Chemistry

Purification and Characterization of an Esterase Hydrolyzing Monoalkyl Phthalates from Micrococcus sp. YGJ1

Kiyofumi MARUYAMA2005-01-01The Journal of Biochemistry

An esterase that specifically hydrolyzes medium-chain (C(3)-C(5)) monoalkyl phthalates was purified from phthalate-grown Micrococcus sp. YGJ1. The enzyme activity was split into two fractions by hydrophobic chromatography on Phenyl Sepharose, and the enzymes were purified to homogeneity from each fraction. The purifie…

biodegradable polymer synthesis and propertiesEffects and risks of endocrine disrupting chemicalsChromium effects and bioremediation

Ultra-fine (.ALPHA.+.THETA.) Duplex Structure Formed by Cold Rolling and Annealing of Pearlite

Tadashi Furuhara、Teruyasu Mizoguchi、T. Maki2005-01-01ISIJ International

The ferrite (α)+cementite (θ) microduplex structure formed by heavy cold rolling and annealing of pearlite was studied in an Fe-1.4Cr-1.0C (mass%) alloy. Cold-rolled pearlite structure is inhomogeneous consisting of three components; (1) irregularly bent lamellae (IBL), (2) coarse lamellae with shear band (CLS) and (3…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced materials and composites

Two-dimensional organization of [ZnGe3S9(H2O)]4– supertetrahedral clusters templated by a metal complex

Nanfeng Zheng、Xianhui Bu、Pingyun Feng2005-01-01Chemical Communications

Under the structure-directing effect of a metal complex formed in situ, supertetrahedral [ZnGe3S6(H2O)(S3)(1/2)]1- clusters alternate with tetrahedral Zn(H2O)(S3)(1/2)1- units to form a two-dimensional wide bandgap semiconductor that shows photocatalytic activity for H2 production from aqueous solution.

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Fluorides and Related Compounds

Synthesis and photophysical characterization of a subphthalocyanine fused dimer–C 60 dyad

Rodrigo S. Iglesias、Christian G. Claessens、Tomás Torres⊗ 等 5 位作者2005-01-01Chemical Communications

Photophysical studies of a newly synthesized fused subphthalocyanine dimer-C60 revealed a complex cascade of energy transfer events to succeed the initial SubPc dimer photoexcitation.

Porphyrin and Phthalocyanine ChemistryFullerene Chemistry and ApplicationsLuminescence and Fluorescent Materials

Structure of nanocrystalline GaN from X-ray diffraction, Rietveld and atomic pair distribution function analyses

Valeri Petkov、Milen Gateshki、Jung‐Il Choi 等 5 位作者2005-01-01Journal of Materials Chemistry

The three-dimensional structure of nanocrystalline GaN has been studied by X-ray diffraction, Rietveld and atomic pair distribution function (PDF) analyses. The material is of very limited structural coherence, yet possess a well-defined atomic arrangement resembling the wurtzite structure. The study demonstrates the…

Boron and Carbon Nanomaterials ResearchMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Highly efficient recycling of a “sandwich” type polyoxometalate oxidation catalyst using solvent resistant nanofiltration

Peter T. Witte、S. Roy Chowdhury、Johan E. ten Elshof 等 6 位作者2005-01-01Chemical Communications

A "sandwich" type polyoxometalate catalyst ([MeN(n-C8H17)3]12[WZn3(ZnW9O34)2]) was very efficiently recycled by nanofiltration with almost quantitative retention, using an alpha-alumina supported mesoporous gamma-alumina membrane.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Reactions

Mechanisms of chromia scale failure during the course of 15–18Cr ferritic stainless steel oxidation in water vapour

A. Galerie、S. Henry、Y. Wouters 等 6 位作者2005-01-01Materials at High Temperatures

Breakaway oxidation of 15–18 % Cr ferritic stainless steels occurring in water vapour is described in the temperature range 800–1000°C. The failure of the protective chromia scale leads to iron oxide(s) nodule formation with accelerated kinetics. Characterisation of the (Fe,Cr)2O3 initial oxide scale by Raman spectros…

High-Temperature Coating BehaviorsHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

An In Situ Synchrotron Radiation Grazing Incidence X-Ray Diffraction Study of Carbon Dioxide Corrosion

Roland De Marco、Zhong‐Tao Jiang、Bobby Pejcic 等 4 位作者2005-01-01Journal of The Electrochemical Society

An in situ surface study of the carbon dioxide corrosion of mild steel has been undertaken using the tandem technique of mixed potential/synchrotron radiation-grazing incidence X-ray diffraction (SR-GIXRD). Long-term monitoring of the mixed potential showed there was an initial shift toward cathodic potentials attribu…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

A new structural form for a decanuclear copper(ii) assembly

Vadapalli Chandrasekhar、Nagarajan Loganathan、Kandasamy Gopal 等 5 位作者2005-01-01Dalton Transactions

The synthesis and structure of a novel decanuclear copper(II) cage is reported. The assembly of the cage is facilitated by the cumulative coordinative interaction of tert-butyl phosphonate, 2-pyridylpyrazole and hydroxide ligands with copper(II) ions. Magnetic studies of this decanuclear copper(II) cage indicate compl…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Fabrication of porous ceramics with controlled pore size by colloidal processing

Yoshio Sakka、Fengqiu Tang、Hiroshi Fudouzi 等 4 位作者2005-01-01Science and Technology of Advanced Materials

Well-defined macroporous ceramics consisting of TiO2 and ZrO2 have been fabricated by two methods. One is via a template-assisted colloidal processing technique and the other is via a hetero-coagulation of template/ceramic particle colloidal processing. The former technique is as follows. Close-packed polymer spheres…

Mesoporous Materials and CatalysisBlock Copolymer Self-AssemblyElectrophoretic Deposition in Materials Science

Mechanical properties of collagen gels derived from rats of different ages

Ching-Chou Wu、Shinn‐Jyh Ding、Yao-Hsien Wang 等 5 位作者2005-01-01Journal of Biomaterials Science Polymer Edition

In a previous study, we found that different collagen gels produced using collagen fibrils extracted from 1-, 4- and 8-month-old rat tails essentially influenced the morphogenesis of epithelial cells. More importantly, the youngest collagen gel induces the highest level of cell apoptosis. The objective of this study w…

Bone Tissue Engineering MaterialsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Fabrication and characterization of Ti–Ni shape memory thin film using Ti/Ni multilayer technique

H. Cho、Hee Young Kim、Shuichi Miyazaki2005-01-01Science and Technology of Advanced Materials

Alloying process and shape memory properties of a Ti/Ni multilayer thin film fabricated by a dual d.c. magnetron sputter–deposition method were investigated, and compared with those of a Ti—Ni amorphous thin film fabricated by an alloy target sputter–deposition method. The multilayer thin film was made by depositing T…

Metal and Thin Film MechanicsShape Memory Alloy TransformationsHigh Entropy Alloys Studies