Materials Literature
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We characterized the energy band dispersion near the Fermi level in single-walled carbon nanotubes using low-temperature scanning tunneling microscopy. Analysis of energy-dependent standing wave oscillations, which result from quantum interference of electrons resonantly scattered by defects, yields a linear energy di…
We describe a new chiral tubule-forming lipid in which the C-O-P phosphoryl linkage of the archetypal tubule-forming molecule, 1,2-bis(10,12-tricosadiynoyl)-sn-glycero-3-phosphocholine, "DC(8,9)PC", is replaced by a C-P linkage. Tubule formation with this phosphonate analogue proceeds under the same mild conditions as…
A computational approach to the study of magnetism in molecular crystals is outlined, and applications are presented for three purely organic nitronyl nitroxide (NN) crystals: WILVIW ( p - N -methylpyridiniumNN + ·I - ), TOLKEK (α-2-hydroNN), and KAXHAS (β- p -nitrophenylNN). Data from ab initio electronic structure c…
We report, for the first time, evidence of near-field energy transfer among CuCl quantum cubes using an ultrahigh-resolution near-field optical microscopy and spectroscopy in the near UV region at 15 K. The sample was high-density CuCl quantum cubes embedded in a NaCl matrix. Measured spatial distributions of the lumi…
The new cyano complexes of formulas PPh(4)[Fe(III)(bipy)(CN)(4)] x H(2)O (1), [[Fe(III)(bipy)(CN)(4)](2)M(II)(H(2)O)(4)] x 4H(2)O with M = Mn (2) and Zn (3), and [[Fe(III)(bipy)(CN)(4)](2)Zn(II)] x 2H(2)O (4) [bipy = 2,2'-bipyridine and PPh(4) = tetraphenylphosphonium cation] have been synthesized and structurally cha…
We propose a general approach to the description of the long-ranged elastic interaction in the nematic colloids, based on the symmetry breaking of the director field. The type of the far-field interaction between particles immersed in a nematic host is determined by the way the symmetry is broken in the near-field reg…
Sr 2 CoMoO 6 perovskite has been prepared in polycrystalline form by thermal treatment, in air, of previously decomposed citrate precursors. This material has been studied by X-ray (XRD) and neutron powder diffraction (NPD), thermal analysis, and magnetic, magnetotransport, and Hall effect measurements. At room temper…
Amorphous carbon networks are used to test various levels of theoretical approaches to molecular dynamics simulations. The density-functional theory as implemented in the Car-Parrinello method, nonorthogonal tight-binding method, the environment-dependent interaction potential (EDIP), and the Brenner potential are com…
We investigate the frustrated magnetic interactions in cubic transition metal oxides with orbital degeneracy. The $e_g$ orbitals order easier and their ordering explains the $A$-type antiferromagnetic phase in KCuF$_3$ and LaMnO$_3$. In $t_{2g}$ systems the magnetic order changes at a transition from an orbital liquid…
We report electrical measurements showing the degradation processes of LaMnO$_{3-y}$ (LaMnO) in LaMnO/normal metal interface in both point contact and planar-type junctions. Immediately after the preparation of the interface, the degradation process was followed by measuring the evolution of the junction resistance ve…
To study materials phenomena simultaneously at various length scales, descriptions in which matter can be coarse grained to arbitrary levels, are necessary. Attempts to do this in the static regime (i.e. zero temperature) have already been developed. In this letter, we present an approach that leads to a dynamics for…
We report the room temperature solution synthesis of alkyl protected silicon nanocrystals. The nanocrystals are of unusually uniform tetrahedral morphology and of a limited size distribution. The nanocrystals were characterized by transmission and scanning electron microscopy as well as atomic force microscopy.
Three series of tensile relaxation tests are performed on isotactic polypropylene at room temperature in the vicinity of the yield point. In the first series of experiments, injection-molded samples are used without thermal pre-treatment. In the second and third series, prior to testing the specimens are annealed at 1…
The interface between biological molecules and novel nanomaterials is important to developing new types of miniature devices for biological applications. Here, the streptavidin/biotin system is used to investigate the adsorption behavior of proteins on the sides of single-walled carbon nanotubes (SWNTs). Functionaliza…
We report on the epitaxial growth of a group-IV ferromagnetic semiconductor, Mn(x)Ge(1-x), in which the Curie temperature is found to increase linearly with manganese (Mn) concentration from 25 to 116 kelvin. The p-type semiconducting character and hole-mediated exchange permit control of ferromagnetic order through a…
Three-ring polycyclic aromatic hydrocarbons (PAHs), and phenanthrene (Phe) in particular, are the main pollutants found in the waste flue gases from organic material combustion in energy generation processes. Quantitatively, the most abundant gaseous contaminant emitted in these processes is CO 2 . Therefore, the aim…
Penta- and hexa-coordinated silicon is rare, occurring as a transient species in some glasses, nonaqueous organosilicon solutions and organosilicon gels such as silicone, and is stable at high pressures within the earth in dense phases such as stishovite. The stable form expected in aqueous solution is quadra-coordina…
Protein crystals crack when they are soaked in a solution with ionic strength sufficiently different from the environment in which they grew. It is demonstrated for the case of tetragonal lysozyme that the forces involved and the mechanisms that lead to the formation of cracks are different for hypertonic and hypotoni…
Abstract This article focuses on the mechanical and rheological properties of virgin and recycled high‐impact polystyrene (HIPS) materials and describes our progress in evaluating the viability of reusing postconsumer and virgin polymer blends of HIPS from electronics equipment housings. Plastics reuse challenges are…
In the search for macromolecular crystallization conditions, the precipitant is probably the most important variable, such that when problematic crystals are encountered there is always the question of whether an alternative precipitant might resolve the problem. During an effort to obtain high-quality crystals of sev…