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Heterogeneous reactions of HNO 3 with flame soot generated under different combustion conditions. Reaction mechanism and kinetics

M. S. Salgado Muñoz、Michel J. Rossi2002-01-01Physical Chemistry Chemical Physics

The reaction of HNO3 with decane (C10H22) soot generated in the laboratory has been studied in a Knudsen flow reactor. Two different types of soot were produced: Soot originating from a rich flame of decane and air (“grey” soot) and soot generated from a leaner flame of decane and air (“black” soot). Both HNO3 uptake…

Atmospheric chemistry and aerosolsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Mechanical and electrical propertiesof vapor-grown carbon fiber thermoplastic composites

Gary G. Tibbetts、Ioana C. Finegan、Choongyoong Kwag2002-01-01Molecular Crystals and Liquid Crystals

Vapor-Grown Carbon Fibers may be modified by surface or temperature treatment to be effective in reinforcing or adding conductivity to polymeric composites.

Fiber-reinforced polymer compositesSynthesis and properties of polymersTribology and Wear Analysis

Thermoelectric Properties of Hot-pressed Boron Suboxide (B<SUB>6</SUB>O)

Takaya Akashi、Tsuyoshi Itoh、Itaru Gunjishima 等 5 位作者2002-01-01MATERIALS TRANSACTIONS

Boron suboxide (B6O) sintered bodies were prepared by a solid state reaction and a hot pressing method. The thermoelectric properties of B6O were compared with those of B4C. The electrical conductivity was smaller than that of B4C, and the Seebeck coefficient was twice as large as that of B4C indicating p-type conduct…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsBoron and Carbon Nanomaterials Research

Irradiation Creep Behavior of Zr-Base Alloys

A Soniak、N. L'Hullier、J-P Mardon 等 6 位作者2002-01-01OpenAlex

This paper deals with the irradiation creep behavior of Zr-base alloys, both under normal operating and power transient conditions. The first part is devoted to the creep experiments, which were conducted in the OSIRIS or SILOE metallurgical test reactors using argon internally pressurized cladding tubes to simulate t…

Fusion materials and technologiesNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys

STUDY OF THE GREEN COTTON FIBRES

Alenka Pavko Čuden、Andrew F. Richards2002-01-01Acta chimica slovenica

Recent investigation of naturally coloured cottons have shown that brown cotton is very similar in morphology to white cotton while green cotton is different since it contains suberin. Suberin containing mainly bifunctional fatty acids can theoretically form a three dimensional network in the presence of glycerol, whi…

Dyeing and Modifying Textile FibersTextile materials and evaluations

Consequences of positive ions upon imaging in low vacuum scanning electron microscopy

J. P. Craven、F. S. Baker、B. L. Thiel 等 4 位作者2002-01-01Journal of Microscopy

The effects caused by an excess quantity of ionized gas molecules within the low vacuum, variable pressure and environmental scanning electron microscope (ESEM) are described with reference to mechanisms by which they can influence imaging conditions. These effects can include specimen charging, recombination and deve…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Control of the (111) Orientation in Copper Interconnection Layer

Tohru Hara、Kohji SAKATA、Yūji Yoshida2002-01-01Electrochemical and Solid-State Letters

This paper describes various parameters affecting to the (111) orientation in electroplating copper conductive layers. Control of this orientation is important because resistivity, stress, adhesion strength, and electromigration resistance of copper layer are affected largely by this orientation. This orientation cann…

Semiconductor materials and devicesCopper Interconnects and ReliabilitySemiconductor materials and interfaces

Aromatic core-modified expanded porphyrinoids with meso-aryl substitutents

Simi K. Pushpan、Tavarekere K. Chandrashekar2002-01-01Pure and Applied Chemistry

Abstract Porphyrins are the most widespread of all prosthetic groups found in Nature. The ubiquity of their functions in Nature led researchers around the globe to focus their attention on these highly colored macrocycles. The interdisciplinary interest generated by porphyrins resulted in the syntheses of modified por…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPorphyrin Metabolism and Disorders

A Mathematical Model for Initiation of Microbiologically Influenced Corrosion by Differential Aeration

Cristian Picioreanu、Mark C.M. van Loosdrecht2002-01-01Journal of The Electrochemical Society

A three-dimensional mathematical model was developed to investigate interactions between aerobic biofilms and a metal surface, and to clarify conditions under which the onset of localized corrosion caused by aerobic microorganisms is likely to occur. The model includes transport of seven chemical species by diffusion…

Corrosion Behavior and InhibitionWater Treatment and DisinfectionConcrete Corrosion and Durability

Orange‐ and Violet‐Emitting Long‐Lasting Phosphors

Jie Fu2002-01-01Journal of the American Ceramic Society

Orange phosphorescence from Eu 3+ ‐activated CaO and SrO and violet phosphorescence from Pb 2+ ‐activated SrO were clearly observed after the materials had been excited with ultraviolet light. The orange phosphorescence resulted from 5 D 0 to 7 F 1 transitions of the Eu 3+ ions and the violet from 3 P 0 to 1 S 0 trans…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesLuminescence and Fluorescent Materials

Preferential Dynamic Nucleation at Triple Junction in Copper Tricrystal During High-Temperature Deformation

Hiromi Miura、Sutandyo Andiarwanto、Keiichi Sato 等 4 位作者2002-01-01MATERIALS TRANSACTIONS

Preferential nucleation of dynamic grains at triple junction (TJ) was investigated in copper tricrystal during high-temperature deformation. The nucleation of the dynamic grains at the TJ was observed at much lower strain than the peak strain where dynamic recrystallization (DRX) extensively took place. Further strain…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesMetallurgy and Material Forming

Growth of Passivating CuBTA Films on Copper in Aqueous Chloride/Benzotriazole Solutions

Desmond Tromans、Guohua Li2002-01-01Electrochemical and Solid-State Letters

The growth of cuprous benzotriazole films (CuBTA), formed on Cu monocrystals and vapor deposited films under controlled potential conditions in 1 M 1-H benzotriazole, has been studied by measurement of electrical charge. Film growth follows a direct logarithmic relationship to ∼25 nm thickness and effects of crystallo…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsAnodic Oxide Films and Nanostructures

The mechanism of cathodic electrodeposition of epoxy coatings and the corrosion behaviour of the electrodeposited coatings

Vesna Mišković‐Stanković2002-01-01Journal of the Serbian Chemical Society

The model of organic film growth on a cathode during electrodeposition process proposes the current density-time and film thickness-time relationships and enables the evaluation of the rate contents for the electrochemical reaction of OH? ion evolution and for the chemical reaction of organic film deposition. The depe…

Corrosion Behavior and InhibitionConducting polymers and applicationsElectrodeposition and Electroless Coatings

Fabrication of a pure porous chitosan bead matrix: influences of phase separation on the microstructure

Il Juhn Roh、Ick Chan Kwon2002-01-01Journal of Biomaterials Science Polymer Edition

The material properties and the microstructure of the scaffold are important parameters that determine the suitability of a material for tissue growth and controlled drug release. Because of its non-toxic, biocompatible, biodegradable, and antithrombogenic nature, chitosan has generated enormous interest for such appl…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Observation of Two Kinds of Structural Phase Transitions in the Ba[sub 2]In[sub 2]O[sub 5] System

Takuya Hashimoto、Yohichi Ueda、Masashi Yoshinaga 等 6 位作者2002-01-01Journal of The Electrochemical Society

Structural phase transitions of Ba 2 In 2 O 5 at high temperatures were investigated by thermal gravimetric-differential thermal analysis (TG-DTA), dilatometry, and differential scanning calorimetry (DSC). It was revealed that there exist three phases in Ba 2 In 2 O 5 . At ∼910°C, a first-order structural phase transi…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Rh, Ru and Ir catalysts obtained by HT precursors: effect of the thermal evolution and composition on the material structure and use

Francesco Basile、Giuseppe Fornasari、Massimo Gazzano 等 4 位作者2002-01-01Journal of Materials Chemistry

The crystal structure refinements of six M/Mg/Al mixed oxides containing cations in the ratio M∶Mg∶Al = 5∶71∶24 (where M is Ru, Rh or Ir) have been carried out using both neutron and X-ray powder full pattern diffraction analysis. The samples were obtained by thermal decomposition of hydrotalcite-type anionic clays at…

Catalytic Processes in Materials ScienceLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Universal Features of the Fluid to Solid Transition for Attractive Colloidal Particles

Luca Cipelletti、V. Prasad、A. D. Dinsmore 等 6 位作者2002-01-01NASA Technical Reports Server (NASA)

Attractive colloidal particles can exhibit a fluid to solid phase transition if the magnitude of the attractive interaction is sufficiently large, if the volume fraction is sufficiently high, and if the applied stress is sufficiently small. The nature of this fluid to solid transition is similar for many different col…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesPickering emulsions and particle stabilization

Stator winding failures: contamination, surface discharge, tracking

J.H. Dymond、N. Stranges、Karim Younsi 等 4 位作者2002-01-01IEEE Transactions on Industry Applications

Stator winding failures are generally attributed to groundwall or turn insulation failures. The failure mechanism involves the gradual development of a weakness in the insulation. This weakness is usually caused by a trapped void that is continuously enlarging due to ever-increasing corona or partial discharge activit…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaAerosol Filtration and Electrostatic Precipitation

Completely monotone solutions of the mode coupling theory for mixtures

Thomas Franosch、Voigtmann, T.2002-01-01HZB Repository (Helmholtz-Zentrum Berlin für Materialien und Energie GmbH (HZB))

We establish that a mode-coupling approximation for the dynamics of multi-component systems obeying Smoluchowski dynamics preserves a subtle yet fundamental property: the partial density correlation functions are, considered as matrices, completely monotone, i.e., they can exactly be written as superpositions of decay…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesThermodynamic properties of mixtures