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Determination of U-oxidation states in the brannerite structure by electron energy-loss (EELS), x-ray photoelectron (XPS) and diffuse reflectance (DRS) spectroscopies.

Michael Colella、Zhaoming Zhang、Kim S. Finnie 等 6 位作者2003-07-24Microscopy and Microanalysis

M Colella, Z Zhang, KS Finnie, Y Zhang, KL Smith, EJ Buck; Determination of U-oxidation states in the brannerite structure by electron energy-loss (EELS),

Radioactive element chemistry and processingAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

Diamond deposition on modified silicon substrates: Making diamond atomic force microscopy tips for nanofriction experiments

G. Tanasa、O. Kurnosikov、C. F. J. Flipse 等 5 位作者2003-07-24Journal of Applied Physics

Fine-crystalline diamond particles are grown on standard Si atomic force microscopy tips, using hot filament-assisted chemical vapor deposition. To optimize the conditions for diamond deposition, first a series of experiments is carried out using silicon substrates covered by point-topped pyramids as obtained by wet c…

Diamond and Carbon-based Materials ResearchForce Microscopy Techniques and ApplicationsAdvanced Surface Polishing Techniques

Synthesis of conducting poly[di‐heteroaromatics] from pyrrole, indole, and carbazole, and their mixed hydroxamates, and studies of their metal complexes

Seyyed Hossein Hosseini、Aliakbar Entezami2003-07-24Journal of Applied Polymer Science

Abstract Compounds 1,1‐di‐( N ‐pyrrolyl)methane hydroxamic acid ( II ), 1,1‐di‐( N ‐indolyl)methane hydroxamic acid ( IV ), 1,1‐di‐( N ‐carbazolyl)methane hydroxamic acid ( VI ), 1‐( N ‐pyrrolyl)‐1‐( N ‐carbazolyl)methane hydroxamic acid ( VIII ), and 1‐( N ‐pyrrolyl)‐1‐( N ‐indolyl)‐methane hydroxamic acid ( X ) were…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Direct and specific heat study of magnetocaloric effect in La0.845Sr0.155MnO3

A. Szewczyk、M. Gutowska、K. Piotrowski 等 4 位作者2003-07-24Journal of Applied Physics

Magnetocaloric effect and specific heat of a La0.845Sr0.155MnO3 sample were measured over a temperature range of 4.2–300 K, to verify whether large entropy changes induced by magnetic field make possible the use of manganites for magnetic refrigeration and whether a magnetostrictive contribution to magnetocaloric effe…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsAdvanced Condensed Matter Physics

Kinetic pathways of carbon nanotube nucleation from graphitic nanofragments

Oleg A. Louchev、James Hester2003-07-24Journal of Applied Physics

A detailed analysis of nanotube (NT) nucleation from graphitic nanofragments by thermal vibration is given, outlining the role of activation energy barriers which may be significantly decreased by the interaction with amorphous carbon, fullerene-like, and carbonized metal catalyst nanoparticles. This analysis predicts…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Computer simulations of a liquid crystalline dendrimer in liquid crystalline solvents

Mark R. Wilson、Jaroslav Ilnytskyi、Lorna Stimson2003-07-24The Journal of Chemical Physics

Molecular dynamics simulations have been carried out to study the structure of a model liquid crystalline dendrimer (LCDr) in solution. A simplified model is used for a third generation carbosilane LCDr in which united atom Lennard-Jones sites are used to represent all heavy atoms in the dendrimer with the exception o…

Liquid Crystal Research AdvancementsAdvanced Polymer Synthesis and CharacterizationDendrimers and Hyperbranched Polymers

Magnetic resonance investigation of Mn2+ in ZnO nanocrystals

Huijuan Zhou、Detlev M. Hofmann、A. Hofstaetter 等 4 位作者2003-07-24Journal of Applied Physics

Electron paramagnetic resonance measurements were carried out to probe the structure of Mn2+ in ZnO nanocrystals with different surface conditions, modified by an annealing process. Changes in the spectra by the annealing treatment indicate the existence of three Mn2+ centers. The first is a sextet signal SI with g=2.…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Pr4Ge3S12: structure determination from high-resolution powder diffraction data

Robert B. Helmholdt、K. Goubitz、E.J. Sonneveld 等 4 位作者2003-07-24Acta Crystallographica Section E Structure Reports Online

The structure of praseodymium germanium sulfide, Pr4Ge3S12, has been determined in the course of the determination of the amount of contamination of the title compound by the starting products. Its structure was assumed to be isostructural with the structure of La4Ge3S12. One Pr atom lies on a threefold axis.

Rare-earth and actinide compoundsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Electrical and nonlinear optical properties of KTiOPO4 single crystals doped by Nb or Sb

В. И. Воронкова、V. K. Yanovskiǐ、T. Yu. Losevskaya 等 4 位作者2003-07-24Journal of Applied Physics

Single crystals of K1−xTi1−xNbxOPO4 and K1−xTi1−xSbxOPO4 solid solutions are grown and their dielectric properties, electrical conductivity, and nonlinear optical properties are studied. Maximal content of these dopants x is found to be 0.11 for Nb and 0.23 for Sb. This doping leads to the creation of the additional p…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsSolid-state spectroscopy and crystallography

Fictive-temperature dependence of structural relaxation in silica glass

Hiroshi Kakiuchida、Kazuya Saito、Akira J. Ikushima2003-07-24Journal of Applied Physics

To clarify the factors that determine the structural relaxations in silica glass, the influence of fictive temperature on the relaxation process was investigated. It was found that the relaxations at different heat-treatment temperatures are enhanced with a rise in the fictive temperature. The structural relaxation is…

Material Dynamics and PropertiesGlass properties and applicationsCultural Heritage Materials Analysis

Is SEM Noise Gaussian?

Mahesh Prasad、David C. Joy2003-07-24Microscopy and Microanalysis

Journal Article Is SEM Noise Gaussian? Get access M Satya Prasad, M Satya Prasad EM Facility, University of Tennessee, Knoxville, TN 37996-0810 Search for other works by this author on: Oxford Academic Google Scholar David C Joy David C Joy Oak Ridge National Laboratory, Oak Ridge, TN 37831-6064 Search for other works…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Highly Efficient Peptide Bond Formation to Functionalized Wells‐Dawson‐Type Polyoxotungstates

Sébastian Bareyt、Stergios Piligkos、Bernold Hasenknopf 等 7 位作者2003-07-24Angewandte Chemie

Die Einführung organischer Substituenten ist eine wichtige Voraussetzung für den biologischen Einsatz von Polyoxometallaten. Modelle hierfür sind die Organozinnderivate α1- und α2-[P2W17O61{Sn(CH2)2CO2H}]7− (siehe Bild), die mit Alkoholen, Aminen sowie C-geschützten Aminosäuren gekuppelt werden können.

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Physical characteristics and infrared fluorescence properties of sol–gel derived Er3+–Yb3+ codoped TiO2

Chu‐Chi Ting、San‐Yuan Chen、Hsin‐Yi Lee2003-07-24Journal of Applied Physics

Er 3+ – Yb 3+ codoped TiO2 films were prepared on fused silica by sol–gel processes. The Yb3+ codoping effect on the physical characteristics and ∼1.54 μm photoluminescence (PL) properties of Er3+-doped TiO2 films was investigated. Maximum ∼1.54 μm PL intensity occurs in Er3+ (5 mol %)–Yb3+(30 mol %) codoped TiO2 samp…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsGlass properties and applications

Fabrication of Rare-Earth Biphthalocyanine Encapsulated by Carbon Nanotubes Using a Capillary Filling Method

Lei Cao、Hongzheng Chen、Hanying Li 等 7 位作者2003-07-24Chemistry of Materials

Erbium biphthalocyanine (HErPc2) nanorods or nanowires were encapsulated in the cavities of MWCNTs simply by the capillary filling method. The length and the diameter of the nanowires can be easily tailored by the MWCNTs mold, capillary filling time, and the concentration of HErPc2. When the optical, electronic, and m…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchPorphyrin and Phthalocyanine Chemistry

Effect of particle size and shape on the order–disorder phase transition in diblock copolymers

A. I. Chervanyov、Anna C. Balazs2003-07-24The Journal of Chemical Physics

The effect of spherical and sphero-cylindrical fillers on the order–disorder transition (ODT) of a symmetric diblock copolymer melt is investigated. Self-consistent equations describing the copolymer density distribution in the presence of fillers are derived. Using these equations, we calculate the excess free energy…

Material Dynamics and PropertiesTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

Heterostereocomplexes Prepared from d-Poly(lactide) and Leuprolide. I. Characterization

Joram Slager、Abraham J. Domb2003-07-24Biomacromolecules

Heterostereocomplexes between d-PLA and l-peptides, obtained by spontaneous precipitation from acetonitrile solution, were characterized by thermal analysis and microscopic techniques. Differential scanning calorimetry showed two transition endotherms, one for the alpha form that melts at 178 degrees C and one for the…

biodegradable polymer synthesis and propertiesSupramolecular Self-Assembly in MaterialsBiopolymer Synthesis and Applications

Intense visible light emission from stress-activated SrMgAl6O11:Eu

Morito Akiyama、Keiko Nishikubo、Kazuhiro Nonaka2003-07-24Applied Physics Letters

We have investigated deformation luminescence phenomena and the constituent phases of SrMgAl6O11:Eu. The deformation luminescence is clearly visible to the naked eye in air, and the luminescence intensity is the highest among the materials reported. Using x-ray diffraction the constituent phases of SrMgAl6O11:Eu are d…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsRadiation Detection and Scintillator Technologies

Boric Acid Nanotubes, Nanotips, Nanorods, Microtubes, and Microtips

Yan Li、Rodney S. Ruoff、Robert P. H. Chang2003-07-24Chemistry of Materials

Thin films containing boron, carbon, and oxygen were synthesized by plasma-enhanced chemical vapor deposition (PE-CVD). When the thin films were exposed to humid atmosphere, nano- or micro-scale boric acid structures were observed to grow spontaneously. Depending on the relative humidity, temperature, and exposure tim…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Photobleaching and optical properties of organic crystal 4-N, N-dimethylamino-4′-N′-methyl stilbazolium tosylate

Lukas Mutter、Mojca Jazbinšek、M. Zgonik 等 6 位作者2003-07-24Journal of Applied Physics

Photobleaching of organic optical materials can be used to structure the surface layer for integrated optics applications. Linear optical properties and absorption were studied in 4-N, N-dimethylamino-4′-N′-methyl stilbazolium tosylate (DAST) organic crystals within the absorption band from 260–700 nm in order to dete…

Liquid Crystal Research AdvancementsOrganic Light-Emitting Diodes ResearchNonlinear Optical Materials Research