Materials Literature
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Creep resistance is a major requirement for the use of magnesium in automotive powertrain components that are currently made of aluminium or cast iron. This paper summarises various new magnesium alloys that have been developed in recent years for elevated temperature applications. The alloy development basis, mechani…
Metal nanoshells are a novel type of composite spherical nanoparticle consisting of a dielectric core covered by a thin metallic shell which is typically gold. Nanoshells possess highly favorable optical and chemical properties for biomedical imaging and therapeutic applications. By varying the relative the dimensions…
Les biocomposites mineraux sont soit naturels, comme les structures squelettiques, soit artificiels, comme divers implants et de nouveaux biomateriaux. Dans les deux cas, leurs parties organiques sont des cristaux liquides ou des analogues stabilises, etroitement apparentes a ces etats intermediaires de la matiere, et…
Single crystals of the high-temperature modification of zinc catena-polyphosphate, beta-Zn(PO(3))(2), were grown from a melt and quenched from 1093 K to room temperature. The structure was solved from single-crystal X-ray diffraction data and is built of corrugated (PO(3))( infinity ) polyphosphate chains, which exten…
The solubilities of the disodium salt hemiheptahydrate of ceftriaxone in different concentrations of methanol in water at (25, 35, and 45) °C are measured by using a gravimetrical method. The densities of the saturated solution are also determined with a digital densimeter (Anton Paar, model DMA 45) at corresponding t…
Dans le present article de revue, nous discutons les mecanismes de debut d'interaction entre un medicament et SiO 2 sous contraintes mecaniques, sur la base de changements dans les especes radicalaires, de formation de liaisons pontantes et de mise en ordre a courte distance. L'indomethacine (IM) a ete utilisee comme…
Experimental, methodical and theoretical studies dealing with phase equilibria and phase structures of polymer blends are generalised. The general and specific features of the change in solubility of polymers with changes in the molecular mass and copolymer composition and upon the formation of three-dimensional cross…
Ag 4 I 4 nanoclusters have been synthesized in half of the sodalite cavities of fully K + -exchanged zeolite A. An additional KI molecule is retained in each large cavity as part of a near square planar K 4 I 3+ cation. A single crystal of Ag 12 -A, prepared by the dynamic ion-exchange of Na 12 -A (LTA) with aqueous 0…
The characteristic features of the structures and properties of crown-substituted porphyrinates and phthalocyaninates are considered. Interactions of these compounds with alkali metal salts yield supramolecular ensembles. The factors determining the architecture of such ensembles are described. The bibliography includ…
Lithium intercalation into the oxide slabs of the cation-deficient n = 2 Ruddlesden-Popper oxysulfide Y(2)Ti(2)O(5)S(2) to produce Li(x)Y(2)Ti(2)O(5)S(2) (0 < x < 2) is described. Neutron powder diffraction measurements reveal that at low levels of lithium intercalation into Y(2)Ti(2)O(5)S(2), the tetragonal symmetry…
In this study, poly-beta-hydroxybutyrate (PHB) production by the Bacillus subtilis 25 and Bacillus megaterium 12 strains was investigated in nutrient broth medium at different incubation times (between 6 h and 48h). The best PHB production and all yields of these strains were determined. The produc…
An electron probe X-ray microanalysis (EPMA) technique, using an energy-dispersive X-ray detector with an ultrathin window, designated a low-Z particle EPMA, has been developed. The low-Z particle EPMA allows the quantitative determination of concentrations of low-Z elements, such as C, N, and O, as well as chemical e…
Steady-state isotopic transient kinetic analysis (SSITKA) coupled with temperature-programmed surface reaction (TPSR) methods and using in situ mass spectroscopy and DRIFTS have been applied for the first time to study essential mechanistic aspects of the NO/H 2 /O 2 reaction at 140 °C under strongly oxidizing conditi…
The state-of-the-art of research dealing with the development and perfection of metal corrosion inhibitors in aqueous solutions is analysed. The main mechanisms involved in formation of protective layers on metals by inhibitors are discussed. Ways of creating mixed corrosion inhibitors with high protective properties…
We report the synthesis of highly luminescent CdTe/ZnS and CdHgTe/ZnS core/shell semiconductor nanocrystals (NCs). A hybrid of two synthesis routes leads to novel nanocrystal compositions and small core/shell sizes (4-5 nm) that emit in the far-red and near-infrared regions. These particles exhibit higher resistance t…
The crystalline structures of superionic high temperature copper selenides Cu$_{2-x}$Se ($0 \le x \le 0.25$) produced by Mechanical Alloying were investigated using X-ray diffraction (XRD) technique. The measured XRD patterns showed the presence of the peaks corresponding to the crystalline superionic high temperature…
A coupled continuum-discrete numerical model is presented to study the synthesis of TiC nanosized aggregates during a self-propagating combustion synthesis (SHS) process. The overall model describes the transient of the basic mechanisms governing the SHS process in a two-dimensional micrometer size geometry system. At…
We have investigated the local atomic structure of amorphous TM-Ti alloys (TM = Co, Ni, Cu) produced by Mechanical Alloying by means of EXAFS analyses on TM and Ti K-edges. Coordination numbers and interatomic distances for the four alloys where found and compared. EXAFS results obtained indicated a shortening in the…
Three amorphous Co$_x$Nb$_{100-x}$ alloys, Co$_{25}$Nb$_{75}$, Co$_{57}$Nb$_{43}$ and Co$_{80}$Nb$_{20}$, were produced by Mechanical Alloying starting from the elemental powders. Their magnetic properties were determined using an alternating gradient force magnetometer (AGFM), and the remanent magnetizations, saturat…
Interchain interactions modulate the frequency of emission from a cationic water-soluble conjugated polymer. The polymer, PFPB, is obtained by a Suzuki copolymerization of p-phenylenebisboronic acid with a 95:5 mixture of 2,7-dibromo-9,9-bis(6'-bromohexyl)fluorene and 4,7-dibromo-2,1,3-benzothiadiazole, followed by qu…