Materials Literature
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By analyzing the NMR line shape, the transformation of a spatially spin-modulated magnetic structure in BiFeO 3 into an ordinary spatially uniform structure of the LaFeO 3 orthoferrite in Bi 1− x La x FeO 3 solid solutions is studied. The measurements are made using a spin-echo technique at temperatures of 77 and 4.2…
Using X-ray induced photoelectron spectroscopy, the influence of Brønsted acids, namely sulfuric, nitric, and hydrochloric acid on the electronic properties of single-walled carbon nanotubes (SWCNTs) was investigated. Doping effects were monitored by changes in binding energy of the C 1s core level of the nanotubes. F…
Heat conduction of finite-length single-walled carbon nanotubes (SWNTs) was simulated by the molecular dynamics method with Tersoff-Brenner bond order potential. Temperature at each end of an SWNT was controlled by the phantom technique, and the thermal conductivity was calculated with Fourier’s law from the measured…
A new strategy to build caged-compounds is presented. The approach is based on heterolytic photocleavage of a metal-ligand bond in a coordination compound. A ruthenium polypyridine complex, containing the neurocompound 4-amino pyridine (4AP) is used as the core of the phototrigger. The biomolecule is released by irrad…
Many organisms from a wide variety of taxa produce amorphous calcium carbonate (ACC), despite the fact that it is inherently unstable and relatively soluble in its pure state. These properties also make it difficult to detect and characterize ACC. Raman spectroscopy is a particularly useful method for investigating AC…
Abstract Divalent and multivalent metallic compounds catalyze the flame retardancy performance of intumescent systems based on ammonium polyphosphate (APP) and pentaerythritol (petol) in poly(propylene) (PP). The catalytic effect is shown by increases in the oxygen index (OI) and UL‐94 ratings. The effect is exerted b…
A hybrid electrochemical capacitor using and as active material for the positive and the negative electrode, respectively, has been designed. The electrodes have been individually tested in a mild aqueous electrolyte (0.1 M to define the adequate balance of active material in the capacitor as well as the working volta…
—Composites of polycarbonate (PC) with multi-wall carbon nanotubes (MWNT) of different concentrations are prepared by diluting a PC based masterbatch containing 15 wt% MWNT using melt mixing in a DACA-Micro Compounder (4 g scale). Electrical resistivity measurements indicate that the percolation of MWNT is reached bet…
Molecular crystals including salts undergo gas–solid, solid–solid, thermal, photochemical and catalyzed reactions if the crystal lattice allows for long-range anisotropic molecular migrations, if the product phase can form fast enough and if crystal disintegration provides fresh surface. This ingenious three-step soli…
The influence of grain boundaries on heat transfer through polycrystalline alumina has been investigated between 20° and 500°C. The thermal conductivities of small‐grained porous ceramics and large‐grained dense ceramics have been measured using the laser‐flash technique. Two methods have been developed to assess the…
The synthesis of water-soluble Mn doped ZnS nanocrystals with MPA (3-mercaptopropionic acid) as stabilizer is described. The coordination of Zn ion with MPA helps efficient doping of Mn and thus makes the process reproducible as compared to the common co-precipitation method. To obtain a high luminescent intensity, po…
The paper reports the designing and development of conducting polyaniline composites which show a shielding effectiveness of 4–58 dB against electromagnetic interference at 101 GHz range, depending upon the loading of the conducting polyaniline in polystyrene and polymethylmethaacrylate matrix. The composites can be u…
In this study, we investigated that how the crystalline structure of cellulose in cotton linters changed during soda, sulfate and organosolve pulping processes by using X-ray diffraction and FT-IR spectroscopy. It was defined that crystalline structure of cellulose in cotton linters was more effected in organosolve pu…
A novel sonochemical approach has been developed to prepare hierarchical porous titania spheres in the presence of a triblock copolymer; it was found that textural meso- and macro-porosity could enhance the photocatalytic activity of mesoporous TiO2.
Amorphous manganese oxide deposits with nanostructures (denoted as were electrochemically deposited onto graphite substrates from 0.16 M with pH 5.6 by means of the potentiostatic, galvanostatic, and potentiodynamic techniques. The maximum specific capacitance of deposits plated in different modes, measured from cycli…
Abstract Natural fiber‐reinforced biodegradable polyester composites were prepared from biodegradable polyesters and surface‐untreated or ‐treated abaca fibers (length ca. 5 mm) by melt mixing and subsequent injection molding. Poly(butylene succinate)(PBS), polyestercarbonate (PEC)/poly(lactic acid)(PLA) blend, and PL…
The surface properties, porosities, and adsorption capacities of activated carbons (AC) are modified by the oxidation treatment using concentrated H 2 SO 4 at temperatures 150−270 °C. The modified AC was characterized by N 2 adsorption, base titration, FTIR, and the adsorption of iodine, chlorophenol, methylene blue,…
Journal URL: http://www.societyofglasstechnology.org.uk/cgi-bin/open.cgi?page=journal&sessionid=85597106; http://www.ingentaconnect.com/content/sgt/pcg; http://www.societyofglasstechnology.org.uk/cgi-bin/open.cgi?page=%20PC/PC-00a&sessionid=85597106
Atomic-scale computer simulation has been used to study the thermally activated atomic transport of self-interstitial atoms (SIAs) in the form of planar clusters in pure Cu and f-Fe. There is strong evidence that such clusters are commonly formed in metals during irradiation with high-energy particles and play an impo…
Highly ordered mesoporous cerium oxides, composed of nanocrystalline pore walls and exhibiting high thermal stability even at 973 K, were synthesized using mesoporous silica templates with hexagonal p6mm and cubic Ia3d symmetries.