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Surface Treatment of Polymeric Fine Powders by CF4 Plasma in a Circulating Fluidized Bed Reactor

Soon Hwa Jung、Soung Hee Park、Sang Done Kim2004-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

A low-pressure plasma surface treatment of polymeric powders was carried out in a circulating fluidized bed (CFB) reactor (10 mm-I.D. × 800 mm-high) with CF4 glow discharge. The effects of solid circulation rate, treatment time and radio frequency (rf) power of plasma on fluorination of high-density polyethylene (HDPE…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsRecycling and Waste Management Techniques

Phase Transformation and Magnetic Property of Heusler Type Co<SUB>2</SUB>NiGa Alloys

Mitsutaka Sato、Teiko Okazaki、Yasubumi Furuya 等 5 位作者2004-01-01MATERIALS TRANSACTIONS

We studied the phase transformation of a new Heusler type ferromagnetic shape memory alloy, Co2NiGa, by using an Acoustic Elastometer method. The alloy displays large magnetostriction, caused by the magnetic-field-induced rearrangement of martensite twin boundary. The ribbon samples produced by rapidly solidified melt…

Magnetic and transport properties of perovskites and related materialsShape Memory Alloy TransformationsCreativity in Education and Neuroscience

Effect of fluorinated ammonium counterions upon the reversibility in E–Z photoisomerization of azobenzene ion pair films

Osamu Ohtani、Tsuyoshi Furukawa、Ryo Sasai 等 7 位作者2004-01-01Journal of Materials Chemistry

Alternate light illumination of ion-pairs of (3-perfluorooctanecarboxamido)propyltrimethylammonium azobenzene-4-carboxylate (FOAM–AzoB) at 340 and >440 nm was found to initiate a reversible photoisomerization between the E- and Z-azobenzene chromophores in multi-lamella films. This was in sharp contrast to the case of…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

The influence of P+, B+, and N+ ion implantation on the luminescence properties of the SiO2: nc-Si system

D. I. Tetelbaum、О. Н. Горшков、В. А. Бурдов 等 8 位作者2004-01-01Physics of the Solid State

The possible mechanisms of the influence of implanted impurities of Group III and V elements on the luminescence properties of a system consisting of silicon nanocrystals in SiO 2 are considered and generalized. The effect of boron and nitrogen ion implantation on the photoluminescence intensity is investigated experi…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsIon-surface interactions and analysis

Effect of Y-Ce Complex Modification on Thermal Fatigue Behavior of High Cr Cast Hot Working Die Steels

Qing Jiang、Hongyu Liang、Hang Sui2004-01-01ISIJ International

The effect of Y-Ce complex modification on the thermal fatigue (TF) behavior of cast hot working die steels was investigated and the mechanism of Y-Ce action was discussed. The experimental result showed that TF behavior of the steel modified by Y-Ce complex modification under thermal cycling temperatures of 650-25°C…

Microstructure and Mechanical Properties of SteelsHigh Temperature Alloys and CreepMetal Alloys Wear and Properties

Dielectric Properties of Rare Earth Cobaltates, LnCoO3(Ln ═ La, Pr, Nd), Across the Spin-State Transition

L. Sudheendra、Md. Motin Seikh、A. R. Raju 等 5 位作者2004-01-01Ferroelectrics

Dielectric properties of the rare earth cobaltates, LnCoO3 (Ln = La, Pr and Gd), have been measured over the 85–300 K range at different frequencies. The dielectric constants increase markedly across the low-spin to intermediate-spin state transitions of the Co3+ ions. The temperature variation of the loss-tangent dat…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Developing seamless shaped woven medical products

Kenneth E. Anderson、Abdel‐Fattah M. Seyam2004-01-01Journal of Medical Engineering & Technology

Currently, the cutting and sewing process is utilized to produce medical products with tailored shape, which leads to a number of adverse consequences due to seams. These drawbacks have prompted us to undertake research to develop new methods by which seamless tubular woven products with inherent shape could be produc…

Additive Manufacturing and 3D Printing TechnologiesTextile materials and evaluationsCrafts, Textile, and Design

Synthesis and structure of the trinuclear complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2 and the binuclear complex Mn2(μ-OOCBut)4[OC(But)OHNEt3]2 with the ‘Chinese lantern’ structure

E.V. Amel'chenkova、T.O. Denisova、С.Е. Нефедов2004-01-01Mendeleev Communications

The treatment of the product of a thermal reaction of manganese(II) acetate tetrahydrate and trimethylacetic acid with triethylamine under reflux results in the unusual complex Mn3(μ,η2-OOCBut)4(μ-OOCBut)2[OC(But)OHNEt3]2, which, according to X-ray diffraction analysis, incorporates a linear Mn3 metal skeleton and fou…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Improvement to reflective dielectric film color pictures

Joshua Kvavle、Cara Bell、Justin Henrie 等 5 位作者2004-01-01Optics Express

This paper presents methods used to improve reflective dielectric film color pictures. These changes include improvements in color purity, increased brightness, and elimination of any light absorption within the film layers. The color picture is fabricated by varying the silicon dioxide film thicknesses across a silic…

Optical Coatings and Gratings

New cationic clathrate: synthesis and structure of [Si40P6]I6.5

Kirill Kovnir、Alexei N. Uglov、Julia V. Zaikina 等 4 位作者2004-01-01Mendeleev Communications

The [Si40P6]I6.5 cationic clathrate possessing the type-I clathrate structure with a minimal known unit-cell volume and a remarkably high vacancy concentration in the guest sublattice was synthesised.

Luminescence Properties of Advanced MaterialsZeolite Catalysis and SynthesisCrystal Structures and Properties

Avoiding Cu Hillocks during the Plasma Process

Tsung-Kuei Kang、Wei‐Yang Chou2004-01-01Journal of The Electrochemical Society

When Cu wafers are exposed to plasma, hillocks are formed on the Cu wafer surface by a plasma cleaner with a surface wave plasma source. Plasma cleaning is divided into the initial stage and the rising temperature stage. Under a supply of gas and with the plasma power turned on, the H radicals first restore native cop…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Effect of Thermal Annealing on Structural Properties and Electrochemical Performance of Carbon Films with Porous Microstructure

Gregory K. Kiema、Michael J. Brett2004-01-01Journal of The Electrochemical Society

Carbon films that are highly porous and have large surface area can be used in electroanalysis, supercapacitors, and energy storage devices. We have previously fabricated and characterized as-deposited porous carbon thin film electrodes formed by a relatively new film fabrication technique called glancing angle deposi…

Graphene research and applicationsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Phase Relations and Distribution of Some Minor Elements in Cu-Fe-As System Saturated with Carbon at 1473 K

Leandro Voisin、Hector M. Henao、Kimio Itagaki2004-01-01MATERIALS TRANSACTIONS

As a fundamental study to develop a new process for eliminating detrimental elements and for recovering valuable ones from secondary Cu-Fe base alloys with a considerably high content of arsenic, both the phase relations in a miscibility gap of the Cu-Fe-As system saturated with carbon and the distribution of some min…

Metallurgical Processes and ThermodynamicsAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

Unusual chromic and doping behavior of ether substituted polythiophenes

Yu Wang、William B. Euler、Brett L. Lucht2004-01-01Chemical Communications

Poly[3-(oligoethylene oxide)-4-methylthiophene] is doped by HCl in aqueous solution in the absence of oxygen and undergoes dramatic solvatochromism in water-ethanol mixtures.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Thermal Cross‐Linking of Poly(Vinyl Methyl Ether). I. Effect of Cross‐Linking Process on the Viscoelastic Properties

Samy A. Madbouly、Toshiaki Ougizawa2004-01-01Journal of Macromolecular Science Part B

Thermal cross‐linking of poly(vinyl methyl ether) (PVME) in the absence of cross‐linking agent, was detected rheologically. The linear viscoelastic properties of PVME were found to be greatly changed by the onset of the cross‐linking process. The viscoelastic material functions, such as dynamic shear moduli, G′ and G″…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Low-temperature sintering of BaZrO3 and BaCeO3 barrier materials

A. V. Orlov、A. L. Vinokurov、O.A. Shlyakhtin 等 4 位作者2004-01-01Mendeleev Communications

BaCe0.99Y0.01O3–δ ceramics with a density over 95% was obtained by free sintering at 1000 ̊C using a combination of a fine precursor powder with a melt-forming sintering aid.

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Fatigue Strength of Ferritic Ductile Cast Iron Hardened by Super Rapid Induction Heating and Quenching

Yoshitaka Misaka、Kazuhiro Kawasaki、Jun Komotori 等 4 位作者2004-01-01MATERIALS TRANSACTIONS

To clarify the effects of Super Rapid Induction Heating and Quenching (SRIHQ) on fatigue properties of Ferrite Ductile Cast Iron (FDI), rotational bending fatigue tests were carried out on specimens treated with four types of heating cycle. Results showed that; (i) the SRIHQ process generated a thin dark gray area aro…

Microstructure and Mechanical Properties of SteelsSurface Treatment and Residual StressMetal Alloys Wear and Properties

A crystallographic, EPR and theoretical study of the Jahn–Teller distortion in [CuTp 2 ] (Tp − = tris{pyrazol-1-yl}hydridoborate)

C.A. Kilner、Eric J. L. McInnes、M.A. Leech 等 9 位作者2004-01-01Dalton Transactions

Crystals of the title compound (1) contain two independent, centrosymmetric half-molecules per asymmetric unit. While both of these show Jahn-Teller elongated six-coordinate geometries, the lengths of the elongated Cu-N bonds in the two molecules differ by 0.117(2) A at 30 K. The structure of one of these molecules (m…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Combinatorial pulsed laser deposition and thermoelectricity of (La1−xCax)VO3composition-spread films

Quinjiao Wang、Kenji Itaka、Hideki Minami 等 5 位作者2004-01-01Science and Technology of Advanced Materials

La1–xCaxVO3 composition-spread film library was fabricated by combinatorial pulsed laser deposition and their thermoelectric properties were evaluated paralelly by the multi-channel probes of Seebeck coefficient and electric conductivity. Concurrent X-ray analysis verified the formation of solid soluted films in the f…

Magnetic and transport properties of perovskites and related materialsTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

The structure of poly(ethylene oxide)8 : NaBPh4 from a single crystal oligomer and polycrystalline polymerElectronic supplementary information (ESI) available: powder diffraction data for PEO8 : NaBPh4. See http://www.rsc.org/suppdata/cc/b3/b311800b/

Edward Staunton、Alasdair M. Christie、Yuri G. Andreev 等 5 位作者2004-01-01Chemical Communications

We show that the structure of a polymer electrolyte may be solved by growing single crystals of an oligomeric (short chain) complex which provided an adequate starting model for refinement of the equivalent polymeric structure using powder diffraction: the efficacy of this method has been demonstrated by determining f…

Zeolite Catalysis and SynthesisChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography