Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Flow experiments in growing protein crystals were conducted to clarify the influence of the solution flow on the crystal quality. Lysozyme crystals grown under various flow velocities were analyzed by using synchrotron radiation to assess the quality. As a result, the crystals grown under forced flow were of better qu…
Abstract A mean‐field model for charged dendrimers has been elaborated and applied to Astramol dendrimers of 5 th generation in salt‐free solution. The free energy of a dendrimer molecule was minimized with respect to the dendrimer size and to the profile of counterion distribution. The model of highly stretched freel…
Room-temperature Er-related electroluminescence (EL) properties have been investigated in Er,O-codoped GaAs (GaAs:Er,O) light-emitting diodes grown by organometallic vapor phase epitaxy. Under forward bias, characteristic emission due to a luminescence center consisting of Er coordinated by O and As was clearly observ…
The fracture of commercial pure titanium in acid and neutral fluoride solutions has been examined by a sustained tensile-loading test and hydrogen thermal desorption analysis. It was found that the fracture of titanium occurred in neutral 2.0% NaF solution as well as in 2.0% acidulated phosphate fluoride (APF) solutio…
The surface plasmon enhanced hyper-Rayleigh scattering light collected from an aqueous solution of gold nanorods is reported. A non negligible part of the signal is attributed to a photoluminescence background attributed to the electron hole recombination following multiphoton excitation of d-valence band electrons in…
We observed superparamagnetism in Co-ion-implanted anatase TiO2 thin films on SrTiO3 (001) substrates. After postannealing under oxygen pressure of 1.0×10−6 Torr, the blocking temperature increased with increasing annealing temperature. Eventually, the 600 °C-annealed sample became ferromagnetic at room temperature. T…
The effects of a commercially available porous glass substrate (Corning Porous Glass No.7930) on the heterogeneous nucleation of proteins [hen egg-white lysozyme (HEWL), thaumatin and apoferritin] have been investigated in order to develop an improved method to facilitate the nucleation of protein crystals. It was fou…
The influence of different donors such as Nb, Ta, Sb, and V on nonlinear current (I)-voltage (V) relations of tin dioxide ceramics is investigated. The room-temperature resistivity (ρ), nonlinear coefficient (α), breakdown electric field (EB) and barrier height (ΦB) are calculated as a function of donor content. The p…
Gold-nanoparticle/organic films were prepared via layer-by-layer self-assembly using dodecylamine-stabilised Au-nanoparticles and poly(propyleneimine) (PPI) dendrimers of generation one to five (G1-G5) or hexadecanedithiol (HDT) as linker compounds. TEM and FE-SEM images revealed that the bulk of the films consisted o…
We carried out in situ resistivity measurements on macroscopic oriented ropes of single wall carbon nanotubes in a transmission electron microscope. We have found a minimum in the resistivity as a function of irradiation dose. This minimum is interpreted as a result of a twofold effect of the irradiation: the dominati…
Oligonucleotides have been synthesized on hydrogen-terminated Si(111) and porous silicon using surface hydrosilation of difunctional molecules (1,(omega)-dimethoxytritylundecenol) to produce a monolayer bearing suitable reactive groups to allow automated solid-phase DNA synthesis. The absence of an intervening oxide e…
A series of ligand stabilized gold nanoparticles with diameters close to 3 nm were studied as Langmuir monolayers at the air/water interface by synchrotron X-ray diffraction and reflectivity. Alkylthiols with different length and/or terminal functional group (hydrophilic or hydrophobic) were introduced into the ligand…
We developed a new protein crystallization method has been developed using a simplified counter-diffusion method for optimizing crystallization condition. It is composed of only a single capillary, the gel in the silicon tube and the screw-top test tube, which are readily available in the laboratory. The one capillary…
A time-resolved study of the formation of AuAg alloy nanoparticles during boiling of AgNO3 and HAuCl4 in the presence of sodium citrate has been performed by monitoring the UV-visible spectra of the solutions. This study reveals clear differences with respect to the formation of pure Au particles, and suggests that go…
We report on the magneto-optical properties of hexagonally arranged Ni nanowires embedded in anodic alumina templates. Due to the nanowire geometry, these samples show different response depending on the polarization orientation of the incident light, which leads to a high anisotropy of both their optical and magneto-…
We report a real-time observation of strain relaxation during in situ growth of SrTiO3 thin films by measuring the in-plane lattice constant at the film surface using reflection high-energy electron diffraction. The initial misfit strain in the SrTiO3 film is tensile on MgO and compressive on LaAlO3 as expected from t…
Thin films of gallium oxide were deposited by electron-beam evaporation on unheated substrates. Samples were deposited either without oxygen, or under an oxygen partial pressure of 5×10−4 mbar. The films were amorphous. Films deposited with oxygen were stoichiometric, whereas those deposited without oxygen were substo…
The direct growth of vertically aligned carbon nanotubes onto flexible plastic substrates using plasma-enhanced chemical vapor deposition is reported. We show that individual lines and dots of free-standing 20–50 nm diameter nanotubes can be grown onto chromium covered commercially available polyimide foil. The scalab…
New procedures are outlined that enable ARP/wARP to automatically build protein models with diffraction data extending to about 2.5 A. An overview of ongoing research is given and possible future advances are discussed.
Large databases that can be used in the search for new materials with specific properties remain an elusive goal in materials science. The problem is complicated by the fact that the optimal material for a given application is usually a compromise between a number of materials properties and the cost. In this letter w…