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X-ray resonant magnetic scattering from structurally and magnetically rough interfaces in multilayered systems I. Specular reflectivity

D. R. Lee、D. Haskel、Y. Choi 等 7 位作者2003-05-09arXiv

The theoretical formulation of x-ray resonant magnetic scattering from rough surfaces and interfaces is given for specular reflectivity. A general expression is derived for both structurally and magnetically rough interfaces in the distorted-wave Born approximation (DWBA) as the framework of the theory. For this purpo…

Materials Science

X-ray resonant magnetic scattering from structurally and magnetically rough interfaces in multilayered systems II. Diffuse scattering

D. R. Lee、C. S. Nelson、J. C. Lang 等 7 位作者2003-05-09arXiv

The theoretical formulation of x-ray resonant magnetic scattering from rough surfaces and interfaces is given for the diffuse (off-specular) scattering, and general expressions are derived in both the Born approximation (BA) and the distorted-wave Born approximation (DWBA) for both single and multiple interfaces. We a…

Materials Science

Enhancement of ferromagnetism in uniaxially stressed dilute magnetic semiconductors

Yuri Semenov、V. A. Stephanovich2003-05-09Physical review. B, Condensed matter

We predict a different mechanism of enhancement of ferromagnetic phase transition temperature ${T}_{c}$ in uniaxially stressed diluted magnetic semiconductors (DMS) of p type. Our prediction is based on comparative studies of both Heisenberg (inherent to undistorted DMS with cubic lattice) and Ising (which can be appl…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Rational design of organic electro-optic materials

Larry R. Dalton2003-05-09Journal of Physics Condensed Matter

Quantum mechanical calculations are used to optimize the molecular first hyperpolarizability of organic chromophores and statistical mechanical calculations are used to optimize the translation of molecular hyperpolarizability to macroscopic electro-optic activity (to values of greater than 100 pm V −1 at telecommunic…

Organic Electronics and PhotovoltaicsMolecular Junctions and NanostructuresNonlinear Optical Materials Research

Single-file Diffusion of Atomic and Colloidal Systems: Asymptotic Laws

Markus Kollmann2003-05-09Physical Review Letters

We present a general derivation of the non-Fickian behavior for the self-diffusion of identically interacting particle systems with excluded mutual passage. We show that the conditional probability distribution of finding a particle at position x(t) after time t, when the particle was located at x(0) at t=0, follows a…

Material Dynamics and PropertiesTheoretical and Computational PhysicsAdvanced Thermodynamics and Statistical Mechanics

Ambient-temperature incorporated hydrogen in Nb:SrTiO3 single crystals

Jiyan Dai、W. P. Chen、G. K. H. Pang 等 8 位作者2003-05-08Applied Physics Letters

Electrolysis of water has been implemented to inject hydrogen into the SrTiO3 single crystal doped with 1 wt % of Nb. Direct evidence of OH− group formation in the Nb:SrTiO3 single crystal has been obtained by Fourier-transform infrared (FTIR) analysis, showing an intensity increase of the absorption at a wave number…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Crystalline structure and thermal behavior of nylon‐10,14

Yongjin Li、Deyue Yan、Guosheng Zhang2003-05-08Journal of Polymer Science Part B Polymer Physics

Abstract The structure and morphology of a novel polyamide, nylon‐10,14, and its lamellar crystals from dilute solution were examined by transmission electron microscopy and wide‐angle X‐ray diffraction (WAXD). Both the electron‐diffraction pattern and WAXD data demonstrated that nylon‐10,14 adopts the structure of a…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Characterization and Catalytic Properties of Titanium-Pillared Clays Prepared at Laboratory and Pilot Scales: A Comparative Study

J.L. Valverde、Antonio de Lucas、Fernando Dorado 等 8 位作者2003-05-08Industrial & Engineering Chemistry Research

The textural and structural characteristics and the acid properties of Ti-pillared montmorillonites prepared at bench scale (1 kg per batch level) have been compared with those prepared at laboratory scale (a few grams). The pillared clays have been examined by X-ray diffraction and characterized by different techniqu…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Miscibility of polysulfone blends with poly(1‐vinylpyrrolidone‐co‐styrene) copolymers and their interaction energies

J. H. Kim、Yongshin Kim、Chang Keun Kim 等 5 位作者2003-05-08Journal of Polymer Science Part B Polymer Physics

Abstract The miscibility of polysulfone (PSf) with various hydrophilic copolymers was explored. Among these blends, PSf gave homogeneous mixtures with poly(1‐vinylpyrrolidone‐ co ‐styrene) [P(VP–S)] copolymers when these copolymers contained 68–88 wt % 1‐vinylpyrrolidone (VP). Miscible PSf blends with P(VP–S) copolyme…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesRheology and Fluid Dynamics Studies

Structure and phase stability of the CdTiO3–PbTiO3 system

D. Y. Suárez-Sandoval、Peter K. Davies2003-05-08Applied Physics Letters

The formation of solid solutions in the CdTiO3–PbTiO3 system has been examined using x-ray diffraction (XRD) and differential scanning calorimetry. The XRD data showed two solid-solution ranges for the (Pb1−xCdx)TiO3 system at 1170 °C; orthorhombic on the cadmium-rich side and tetragonal on the lead-rich side, separat…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Molecular Recognition of Polymers by Cyclodextrin Vesicles

Bart Jan Ravoo、Jean‐Christophe Jacquier、Gerhard Wenz2003-05-08Angewandte Chemie

Polyelektrolyte mit kleinen hydrophoben Substituenten werden durch Vesikel aus Cyclodextrinmolekülen gebunden. Maßgeblich hierfür ist der Einschluss der hydrophoben Substituenten der Polymere in die Cyclodextrinhohlräume an der Vesikeloberfläche (siehe Bild). Die molekulare Erkennung ist das Ergebnis eines empfindlich…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesHemoglobin structure and function

Drawing of ultrahigh molecular weight polyethylene fibers in the presence of supercritical carbon dioxide

Manuel García‐Leiner、John W. Song、Alan J. Lesser2003-05-08Journal of Polymer Science Part B Polymer Physics

Abstract The drawing behavior of ultrahigh molecular weight polyethylene fibers in supercritical carbon dioxide (scCO 2 ) is compared to that in air at different temperatures. The temperature substantially influences the drawing properties in air, whereas in scCO 2 , a constant draw stress and tensile strength are obs…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Effects of Calcium and Other Ionic Impurities on the Primary Nucleation of Burkeite

Bing Shi、W.J. Frederick、Ronald W. Rousseau2003-05-08Industrial & Engineering Chemistry Research

Primary nucleation of burkeite, which is a crystalline solid solution of sodium carbonate and sodium sulfate having the stoichiometry Na 2 CO 3 ·2Na 2 SO 4, was monitored using an on-line particle-size analyzer. Observations of unusual nucleation behavior led to explorations that identified specific impurities in the…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Thermally stimulated depolarization currents of crosslinked polyethylene relaxations in the fusion range of temperatures

I. Tamayo、J. Belana、J.C. Cañadas 等 6 位作者2003-05-08Journal of Polymer Science Part B Polymer Physics

Abstract With thermally stimulated depolarization currents, we researched the relaxations of crosslinked polyethylene as it is used in medium‐voltage cable insulation. Through conventional polarization two heteropolar peaks stand up in the spectra, at 80 and 105 °C. As the sample is annealed, a homopolar peak is devel…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Nanoporous Copper Silicates with One‐Dimensional 12‐Ring Channel Systems

Xiqu Wang、Lumei Liu、Allan J. Jacobson2003-05-08Angewandte Chemie International Edition

Exploring new channels: A range of alkali-metal copper silicates that contain double layers of silicate tetrahedra have been prepared, which contain straight 12-ring channels that are analogous to those found in LTL-type zeolites. The framework that defines the 12-ring channels is neutral and, consequently, only neutr…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Gas plasma etching of PEO/PBT segmented block copolymer films

M.B. Olde riekerink、M.B. Claase、G.H.M. Engbers 等 5 位作者2003-05-08Journal of Biomedical Materials Research Part A

A series of poly(ethylene oxide)/poly(butylene terephthalate) (PEO/PBT) segmented block copolymer films was treated with a radio-frequency carbon dioxide (CO(2)) or with argon (Ar) plasma. The effects of (preferential) etching on surface structure, topography, chemistry, and wettability were studied by scanning electr…

Polymer crystallization and propertiesPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Tuning the response of magnetic suspensions

M. Chen、Lizhong Sun、John E. Bonevich 等 6 位作者2003-05-08Applied Physics Letters

Electrochemical template synthesis of multilayer nanowires consisting of alternating ferromagnetic and nonmagnetic layers provides an approach to control the properties of magnetic particles in suspension. Copper/nickel multilayer nanowires were fabricated by electrochemical deposition from a solution containing both…

Multiferroics and related materialsAnodic Oxide Films and NanostructuresCharacterization and Applications of Magnetic Nanoparticles

Fabrication of a single-electron inverter in multiwall carbon nanotubes

Koji Ishibashi、Daiju Tsuya、Masaki Suzuki 等 4 位作者2003-05-08Applied Physics Letters

A single-electron inverter based on the Coulomb blockade effects has been fabricated in multiwalled carbon nanotubes, by using the Ar irradiation method for the tunnel barrier formation in the quantum dots. The device characteristics were measured at 2.6 K, and an indication of inverter-like transfer characteristics h…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Self-diffusion of Sn atoms inCu3Snprobed by quasielastic nuclear resonant scattering of synchrotron radiation

H. Thieß、Alfred Q. R. Baron、Daisuke Ishikawa 等 7 位作者2003-05-08Physical review. B, Condensed matter

We report on studies to determine the elementary diffusion jump of minority Sn atoms in the $\ensuremath{\gamma}$ phase of the intermetallic copper-tin alloy. The diffusionally accelerated decay from a crystalline ${\mathrm{Cu}}_{84}{\mathrm{Sn}}_{16}$ sample at elevated temperatures has been probed by quasielastic nu…

Microstructure and mechanical propertiesSemiconductor materials and interfacesCrystallography and Radiation Phenomena

Ultrasound–order director fluctuations interaction in nematic liquid crystals: A nuclear magnetic resonance relaxometry study

F. Bonetto、Esteban Anoardo、Rainer Kimmich2003-05-08The Journal of Chemical Physics

Field-cycling nuclear magnetic resonance relaxometry was used to study the spin-lattice relaxation dispersion of selected standard nematic liquid crystals at different temperatures, in presence and absence of a monochromatic ultrasonic field. It was found that sonication changes the relaxation dispersion and, in some…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesMolecular spectroscopy and chirality