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Telomerization of vinylidene fluoride with methanol. Elucidation of the reaction process and mechanism by a structural analysis of the telomers

Michel Duc、Bruno Améduri、Bernard Boutevin 等 5 位作者1998-07-01Macromolecular Chemistry and Physics

Telomerization of vinylidene fluoride (VDF) with methanol was investigated to synthesize fluorinated telomers bearing a functional end-group. Improvements of the conversion of VDF were attempted by using different radical initiators and reaction processes. The solvent effect on the reaction yield was also studied. Rad…

Fiber-reinforced polymer compositesSilicone and Siloxane Chemistry

Calculation of intergranular stresses based on a large-strain viscoplastic self-consistent polycrystal model

Ricardo A. Lebensohn、P.A. Turner、J. W. Signorelli 等 5 位作者1998-07-01Modelling and Simulation in Materials Science and Engineering

We present here an extension of the viscoplastic self-consistent (VPSC) polycrystal model for the calculation of the intergranular Cauchy stresses in an aggregate. This method, which is based on the self-consistent treatment of incompressible aggregates proposed in 1987 by Molinari et al , is formulated using the incl…

Rock Mechanics and ModelingMicrostructure and mechanical propertiesComposite Material Mechanics

Copper Oxide Thin Films Prepared from Copper Dipivaloylmethanate and Oxygen by Chemical Vapor Deposition

Toshiro Maruyama1998-07-01Japanese Journal of Applied Physics

Polycrystalline copper oxide thin films have been prepared from copper dipivaloylmethanate and oxygen by an atmospheric-pressure chemical vapor deposition method at a reaction temperature of 300°C. The deposition at oxygen partial pressure ( p 0 ) ≦2.13 kPa forms single-phase Cu 2 O with [100] oriented polycrystalline…

Physics of Superconductivity and MagnetismZnO doping and propertiesCopper-based nanomaterials and applications

Liquid crystalline materials for light-emitting diodes

G. Lüssem、Joachim H. Wendorff1998-07-01Polymers for Advanced Technologies

Liquid crystalline materials display unique properties which can be exploited in organic light-emitting diodes. Characteristic features of liquid crystals are the anisotropy of electronic properties, a strong coupling to external fields as well as a tendency to form spontaneously homogeneous monodomain films. It is fo…

Liquid Crystal Research AdvancementsSemiconductor Lasers and Optical DevicesSynthesis and properties of polymers

Changes in cell, matrix compartment, and fibrillar collagen volumes between growth‐plate zones

Kenneth J. Noonan、Ernst B. Hunziker、Julie Nessler 等 4 位作者1998-07-01Journal of Orthopaedic Research®

To define the contributions of changes in cell, matrix compartment, and fibrillar collagen volumes to longitudinal bone growth, we measured the differences in cell, pericellular/territorial matrix and interterritorial matrix volumes, and fibrillar collagen concentrations between the upper proliferative and lower hyper…

Bone health and osteoporosis researchOsteoarthritis Treatment and MechanismsCollagen: Extraction and Characterization

FTIR, UV−Vis, and HRTEM Study of Au/ZrO2 Catalyst: Reduced Reactivity in the CO−O2 Reaction of Electron-Deficient Gold Sites Present on the Used Samples

F. Boccuzzi、G. Cerrato、Francesco Pinna 等 4 位作者1998-07-01The Journal of Physical Chemistry B

A Fourier transform infrared (FTIR), UV−vis, and high-resolution transmission electron microscopy (HRTEM) study of fresh and used Au/ZrO 2 catalyst is reported. FTIR data show that on a fresh sample CO is adsorbed on regular gold metallic sites, while on the used sample the adsorption sites are bidimensional gold clus…

Catalytic Processes in Materials ScienceCatalysis and Oxidation Reactionsnanoparticles nucleation surface interactions

Mixed-Valent Diruthenium Long-Chain Carboxylates. 2. Magnetic Properties

Fabio D. Cukiernik、Dominique Luneau、Jean‐Claude Marchon 等 4 位作者1998-07-01Inorganic Chemistry

The magnetic properties of several mixed-valent diruthenium long-chain carboxylates of general formula Ru(2)(RCO(2))(4)X (X = Cl, DOS, or RCO(2), DOS = dodecyl sulfate, and RCO(2) = linear aliphatic carboxylate or dialkoxy- or trialkoxybenzoate) were studied in the temperature range 6-400 K. All of the compounds exhib…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

The Effect of Talc on Cell Nucleation in Extrusion Foam Processing of Polypropylene with CO2 and Isopentane

Chul B. Park、Lewis K. Cheung、Seungwon Song1998-07-01Cellular Polymers

The effect of talc on cell nucleation of polypropylene (PP) foam was investigated. Branched high-melt-strength PP was used to reduce bubble coalescence during extrusion foam processing. When isopentane was used as a blowing agent, bubble nucleation was dominated by the talc concentration, and the isopentane content di…

Phase Equilibria and ThermodynamicsInjection Molding Process and PropertiesPolymer Foaming and Composites

MOCVD layer growth of ZnO using DMZn and tertiary butanol

B. Hahn、G. Heindel、E. Pschorr-Schoberer 等 4 位作者1998-07-01Semiconductor Science and Technology

Highly conductive polycrystalline ZnO films have been grown by metal organic chemical vapour deposition (MOCVD) using dimethylzinc (DMZn), dimethylzinc-triethylamine (DMZn-TEN) and tertiary butanol (tBuOH) as precursors. When (DMZn-TEN) is used the efficiency of the zinc precursors is reduced by the formation of gas-p…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Raman signature of polyamorphism in triphenyl phosphite

Alain Hédoux、Y. Guinet、Marc Descamps1998-07-01Physical review. B, Condensed matter

The polyamorphism of triphenyl phosphite has been investigated from a low-frequency Raman-scattering study. Interesting features about glaciation processes have been revealed from a study of the boson peak and an analysis of the Raman susceptibility in the glacial and crystalline states. The very close correspondence…

Material Dynamics and PropertiesClay minerals and soil interactionsQuantum Electrodynamics and Casimir Effect

Factors influencing the flow and hardness of materials with ultrafine grain sizes

Minoru Furukawa、Zenji Horita、Minoru Nemoto 等 5 位作者1998-07-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Ultrafine grain sizes were introduced into an Al-3wt%Mg solid solution alloy and a commercial Al-Mg-Li-Zr alloy through intense plastic straining by equalchannel angular (ECA) pressing at room temperature and at 673 K respectively. Tensile testing of pressed samples at room temperature revealed markedly different stre…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesHigh-Velocity Impact and Material Behavior

Microbial Reduction of Structural Iron in Clays—A Renewable Source of Reduction Capacity

Vibeke Ernstsen、Will P. Gates、Joseph W. Stucki1998-07-01Journal of Environmental Quality

Abstract The ability of microorganisms to reduce structural Fe in minerals has become recognized as an important mechanism in the oxidation of pollutants in soils and sediments. To better understand the factors controlling the concentration of Fe(II) in natural deposits, samples of clayey till from sites near Havrebje…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Porous silicon in crystalline silicon solar cells: a review and the effect on the internal quantum efficiency

L. Stalmans、Jef Poortmans、H. Bender 等 8 位作者1998-07-01Progress in Photovoltaics Research and Applications

Crystalline silicon (c-Si) is the dominant semiconductor material in use for terrestrial photovoltaic cells and a clear tendency towards thinner, active cell structures and simplified processing schemes is observable within contemporary c-Si photovoltaic research. The potential applications of porous silicon and relat…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Reduction of inrush current in single-phase transformer using virtual air gap technique

Vincent Molcrette、Jean-Luc Kotny、Jean-Paul Swan 等 4 位作者1998-07-01IEEE Transactions on Magnetics

In this paper the authors present a technique based on the use of a virtual air gap in which equivalent thickness varies as a function of controllable parameters adapted to the configuration of the magnetic circuit and the associated control system. The principle is presented using a magnetic circuit similar to the tr…

Power Quality and HarmonicsMagnetic Properties and ApplicationsInduction Heating and Inverter Technology

Properties of various sputter-deposited Cu–N thin films

Dao-yuan Wang、Norio Nakamine、Yasunori Hayashi1998-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Compositions and structures of sputter-deposited Cu–N films are strongly dependent on the total sputtering pressure and on the content of nitrogen gas. The Cu–N films obtained can be classified into four categories: metallic Cu-rich Cu3N films with a positive temperature coefficient of resistivity (TCR), semiconductin…

Semiconductor materials and devicesCopper Interconnects and ReliabilityCopper-based nanomaterials and applications

Magnetoelectric effect and toroidal ordering in Ga2−xFexO3

Yu. F. Popov、A. M. Kadomtseva、G. P. Vorob’ev 等 7 位作者1998-07-01Journal of Experimental and Theoretical Physics

The field dependence of the magnetoelectric effect and longitudinal magnetostriction of Ga2−x FexO3 single crystals is studied in magnetic fields up to 200 kOe in the temperature range from 4.2 to 300 K. It is shown that the magnetoelectric effect in these materials is determined mainly by the toroidal moment T and is…

Multiferroics and related materialsGa2O3 and related materialsSmart Materials for Construction

Analysis of errors in thin-film optical parameters derived from spectrophotometric measurements at normal light incidence

Ivan A. Konstantinov、Tzewatanka Babeva、S Kitova1998-07-01Applied Optics

A comparative analysis is made of the errors in deriving the optical parameters (n, refractive index; k, absorption coefficient; d, film thickness) of thin films from spectrophotometric measurements at normal light incidence. The errors in determining n, k, and d by the (TR(f)R(b)), (TR(f)R(m)), (TR(b)R(m)), (TR(f)),…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

Reformulation of the fourier modal method for surface-relief gratings made with anisotropic materials

Lifeng Li1998-07-01Journal of Modern Optics

By the use of the correct Fourier factorization rules presented in an earlier paper by Li the Fourier modal method (FMM) for anisotropic surface-relief gratings is reformulated. The newly formulated FMM converges much faster than the old formulation when the permittivity contrast in the grating groove region is large.…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Hall effect inLa1−xSrxMnO3

A. Asamitsu、Y. Tokura1998-07-01Physical review. B, Condensed matter

The Hall effect and its systematic variation with doping level $(x)$ and temperature have been investigated for crystals of ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{MnO}}_{3}$ $(0.18<~x<~0.50)$ with perovskite structure. The ordinary Hall coefficient ${(R}_{H})$ at 4.2 K indicates that the carr…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Online monitors keep transformers in service

Thomas Leibfried1998-07-01IEEE Computer Applications in Power

The trend toward a deregulated global electricity market is raising utility cost consciousness. An important aspect of cost savings is equipment investment for the power transmission system, and power transformers are among the most expensive elements of a high voltage power system. Cost savings can be realized throug…

High voltage insulation and dielectric phenomenaWater Systems and OptimizationPower Transformer Diagnostics and Insulation