Materials Literature
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Organometallic polycondensation gave zinc porphyrin (Por) polymers (e.g., (−Ar−Por-Ar−) n and (−C⋮C−Por-C⋮C−Ar−) n; Ar = arylene) having arylene or aryleneethynylene groups between the zinc porphyrin units. Polymers having long alkyl substituent(s) in the Ar unit were soluble in THF and chloroform, and gave M n and M…
Laser ablation deposition of highly oriented yttria stabilized zirconia (YSZ) films is important for various technological applications and depends critically on the selection of background environment, with low pressure oxygen being the most common choice. Here, the spatial-temporal distribution of YSZ plume chemistr…
We have experimentally observed that the optical absorption spectra of single-walled carbon nanotube (SWCNT) films change drastically and reversibly by pressure up to 4.1 GPa. The main absorption feature at 0.68 eV attributed to the interband optical transition in semiconducting nanotubes [chiral $(n,m)$ and zigzag $(…
In this article, we will report the low temperature Raman studies of Li0.12Na0.88NbO3 ceramics at the ferroelectric–ferroelectric phase transitions. The spectral pattern indicates the phase transition occurs at 200 K in the cooling process and at 280 K on heating. The observed spectra are discussed as they relate to t…
The aim of this work is to present an electrical study of the aging of conducting polyaniline–polystyrene (PANl–PSt) blends. Results concerning time dependence of the electrical conductivity of some samples artificially aged at different temperatures are presented. It is shown that the electrical conductivity decrease…
A force field for phosphoric acid is developed, on the basis of the reproduction of the experimental crystal structure by molecular dynamics (MD) simulations. The fit between calculated and experimental unit cell parameters, atomic positions, thermal motions, and hydrogen bond distances is satisfactory. Subsequently,…
Quasiparticle energies of AlN, GaN, ZnO, ZnS and ZnSe in the wurtzite structure have been calculated by the GW approximation with a full random phase approximation dielectric matrix instead of using plasmon pole approximation. The linear muffin tin orbital basis was used for this work and the d orbitals of the Zn and…
A phosphate glass embedded with PbSe semiconductor quantum dots (QDs) has been synthesized and investigated. Optical absorption spectra of PbSe spherical QDs have been studied both theoretically and experimentally. Theoretical analysis of the energy spectra and optical transitions has been carried out in the framework…
We study theoretically the collective orbital excitation called the orbital wave in the orbital ordered manganites. The dispersion relation of the orbital wave is strongly correlated with the static spin structure through the coupling between spin and orbital degrees of freedom. As a probe to detect the dispersion rel…
Development of long-range order in relaxor ferroelectrics [Pb(Mg 1/3 Nb 2/3 )O 3 ] 1- x -[PbTiO 3 ] x (PMN/ x PT) and Pb(Zn 1/3 Nb 2/3 )O 3 (PZN) has been investigated by neutron powder diffraction and birefringence along with transmission-electron and optical microscopies. The Rietveld analysis of PZN revealed that t…
We demonstrate the first three-dimensional simulations of bicontinuous spinodal decomposition of incompressible binary fluid mixtures in a confined geometry. We find that after an initial transient the thickness of a wetting layer L grows with time t as L ∼ t 1/3 by a diffusion process and later as L ∼ t by a hydrodyn…
Many layered metals such as quasi-two-dimensional organic molecular crystals show properties consistent with a Fermi-liquid description at low temperatures. The effective masses extracted from the temperature dependence of the magnetic oscillations observed in these materials are in the range, ${m}_{c}^{*}{/m}_{e}\ens…
Laser-induced chromism of amorphous WO3 thin films prepared by pulsed laser deposition (PLD) has been investigated. The original films could be colored from light brown to purple by a single pulse of KrF excimer laser irradiation at 248 nm and subsequently bleached to brown by a single pulse of Nd–yttrium–aluminum–gar…
Fullerenes and nanotubes are promising candidates in the development of nanodevices. Recently, a form of carbon nanotube torus structures has been observed. In this regard, we have investigated the geometries, electronic structures, and energetics of small carbon nanotube tori, using both the tight-binding and semiemp…
We present depolarized light scattering data of the glass former toluene as obtained from tandem Fabry–Perot interferometry and Raman scattering covering a frequency range 0.5 GHz<v<5000 GHz. A large temperature interval of the (supercooled) liquid (Tg=117 K<T<295 K) as well as of the glass…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTADDITION / CORRECTIONThis article has been corrected. View the notice.Porous Crystal Formation from Polyoxometalate Building Blocks: Single-Crystal Structure of [AlO4Al12(OH)12(H2O)24][Al(OH)6Mo6O18]2((OH)· 29.5H2OJung-Ho Son, Hyuk Choi, and Young-Uk KwonView Author In…
A cyclic version of the Entner-Doudoroff pathway is used by Pseudomonas aeruginosa to metabolize carbohydrates. Genes encoding the enzymes that catabolize intracellular glucose to pyruvate and glyceraldehyde 3-phosphate are coordinately regulated, clustered at 39 min on the chromosome, and collectively form the hex re…
The structural organization of nitridic ceramics in the system Si/B/N/C on an intermediate length scale is studied using 29 Si{ 11 B} rotational echo adiabatic passage double resonance (REAPDOR) and 11 B{ 29 Si} rotational echo double resonance (REDOR) NMR spectroscopy. The experiments are performed on a 100% 29 Si en…
X-ray photoelectron spectroscopy (XPS) and X-ray absorption near-edge structure (XANES) spectroscopy were used to characterize the oxygen species in perovskite-type La 1 - x Sr x CoO 3 - δ with x = 0 and 0.2. The XPS method used synchrotron radiation with variable excitation energies. XPS showed two kinds of oxygen sp…
Low-temperature resistivity of half-metals is investigated. To date it has been discussed that the one-magnon scattering process in half-metals is irrelevant for low-temperature resistivity, due to the fully spin-polarized electronic structure at the ground state. If one takes into account the non-rigid-band behavior…