Materials Literature
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Molecular dynamics simulations have been carried out to study the structure of a model liquid crystalline dendrimer (LCDr) in solution. A simplified model is used for a third generation carbosilane LCDr in which united atom Lennard-Jones sites are used to represent all heavy atoms in the dendrimer with the exception o…
Electron paramagnetic resonance measurements were carried out to probe the structure of Mn2+ in ZnO nanocrystals with different surface conditions, modified by an annealing process. Changes in the spectra by the annealing treatment indicate the existence of three Mn2+ centers. The first is a sextet signal SI with g=2.…
The structure of praseodymium germanium sulfide, Pr4Ge3S12, has been determined in the course of the determination of the amount of contamination of the title compound by the starting products. Its structure was assumed to be isostructural with the structure of La4Ge3S12. One Pr atom lies on a threefold axis.
Single crystals of K1−xTi1−xNbxOPO4 and K1−xTi1−xSbxOPO4 solid solutions are grown and their dielectric properties, electrical conductivity, and nonlinear optical properties are studied. Maximal content of these dopants x is found to be 0.11 for Nb and 0.23 for Sb. This doping leads to the creation of the additional p…
To clarify the factors that determine the structural relaxations in silica glass, the influence of fictive temperature on the relaxation process was investigated. It was found that the relaxations at different heat-treatment temperatures are enhanced with a rise in the fictive temperature. The structural relaxation is…
Journal Article Is SEM Noise Gaussian? Get access M Satya Prasad, M Satya Prasad EM Facility, University of Tennessee, Knoxville, TN 37996-0810 Search for other works by this author on: Oxford Academic Google Scholar David C Joy David C Joy Oak Ridge National Laboratory, Oak Ridge, TN 37831-6064 Search for other works…
Die Einführung organischer Substituenten ist eine wichtige Voraussetzung für den biologischen Einsatz von Polyoxometallaten. Modelle hierfür sind die Organozinnderivate α1- und α2-[P2W17O61{Sn(CH2)2CO2H}]7− (siehe Bild), die mit Alkoholen, Aminen sowie C-geschützten Aminosäuren gekuppelt werden können.
Er 3+ – Yb 3+ codoped TiO2 films were prepared on fused silica by sol–gel processes. The Yb3+ codoping effect on the physical characteristics and ∼1.54 μm photoluminescence (PL) properties of Er3+-doped TiO2 films was investigated. Maximum ∼1.54 μm PL intensity occurs in Er3+ (5 mol %)–Yb3+(30 mol %) codoped TiO2 samp…
Erbium biphthalocyanine (HErPc2) nanorods or nanowires were encapsulated in the cavities of MWCNTs simply by the capillary filling method. The length and the diameter of the nanowires can be easily tailored by the MWCNTs mold, capillary filling time, and the concentration of HErPc2. When the optical, electronic, and m…
The effect of spherical and sphero-cylindrical fillers on the order–disorder transition (ODT) of a symmetric diblock copolymer melt is investigated. Self-consistent equations describing the copolymer density distribution in the presence of fillers are derived. Using these equations, we calculate the excess free energy…
Heterostereocomplexes between d-PLA and l-peptides, obtained by spontaneous precipitation from acetonitrile solution, were characterized by thermal analysis and microscopic techniques. Differential scanning calorimetry showed two transition endotherms, one for the alpha form that melts at 178 degrees C and one for the…
We have investigated deformation luminescence phenomena and the constituent phases of SrMgAl6O11:Eu. The deformation luminescence is clearly visible to the naked eye in air, and the luminescence intensity is the highest among the materials reported. Using x-ray diffraction the constituent phases of SrMgAl6O11:Eu are d…
Thin films containing boron, carbon, and oxygen were synthesized by plasma-enhanced chemical vapor deposition (PE-CVD). When the thin films were exposed to humid atmosphere, nano- or micro-scale boric acid structures were observed to grow spontaneously. Depending on the relative humidity, temperature, and exposure tim…
Photobleaching of organic optical materials can be used to structure the surface layer for integrated optics applications. Linear optical properties and absorption were studied in 4-N, N-dimethylamino-4′-N′-methyl stilbazolium tosylate (DAST) organic crystals within the absorption band from 260–700 nm in order to dete…
The behavior of species in the gas phase and their effects on the etching characteristics of organic film with the lower dielectric constant (low-k) were investigated in 500 MHz ultrahigh frequency (UHF) plasma using N2/H2 and N2/NH3 gases. The absolute H and N radical densities and NH3 molecule density in etching pla…
Abstract The graft copolymerization of acrylonitrile (AN) onto Cassia tora gum (CTG) was carried out in an aqueous medium with a ceric ammonium nitrate (CAN)–nitric acid initiation system. The percentage grafting and percentage grafting efficiency were determined as functions of the concentrations of CAN, nitric acid,…
In this letter, we report the formation of bulk samples of silica-based glass containing Si nanocrystals (Si-ncs) by pyrolysis of a preceramic precursor. The starting precursor is a sol–gel-derived polysiloxane containing only Si–H groups which leads, after annealing in a controlled atmosphere in the range 1000–1200 °…
The title compound, a new polymorphic phase of iron diphosphate, was prepared by solid-state reaction. This compound crystallizes in the monoclinic space group P 2 1 / c with a = 4.4668(6) Å, b = 9.896(1) Å, c = 5.2077(7) Å, β = 97.516(2)°, V = 228.22(5) Å 3, and Z = 2. The structure is characterized by the arrangemen…
Tb 3+ -doped Lu2O3 sintered ceramics were prepared in vacuum and in air. It was shown that the vacuum-sintered disks are able to store energy when irradiated with 300-nm or shorter photons. A small part of the stored energy could be recovered with 980-nm light. A much more significant amount of the stored energy could…
A novel method is introduced to estimate surface coverage and the equation of state of insoluble surfactant on droplets, involving measurement of interfacial tension on a single parent drop and progressively subdivided generations of daughter drops. This has enabled quantitative decomposition of the dilution, tip-stre…