Materials Literature
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The temperature dependence of the overall rate constant for the C 3 H 7 O 2 + NO reaction and the rate constant for the minor branching channel resulting in the production of i -C 3 H 7 ONO 2 have been measured using the turbulent flow technique with high-pressure chemical ionization mass spectrometry for the detectio…
We apply first-principles calculations to study the electronic structure of boron nitride nanocones with disclinations of different angles θ=nπ/3. Nanocones with odd values of n present antiphase boundaries that cause a reduction of the work function of the nanocones, relative to the bulk BN value, by as much as 2 eV.…
We present a dynamic Monte-Carlo model involving lateral interactions and different adsorption sites (top, fcc and hcp). Using this model in combination with kinetic parameters from UHV experiments and lateral interactions derived from DFT calculations we have reproduced the ordering behavior of NO on Rh(111) during a…
Single crystals of Zn doped lithium ferrite have been obtained by an improved flux method. The magnetic anisotropy and Mössbauer spectra of the system (Fe1−x3+Znx2+)[Fe(3+x)/23+Li(1−x)/2+]O4 with 0⩽x⩽0.5 have been investigated. According to the single-ion model, the magnetic anisotropy constant K1 depends mainly on th…
Green, blue, and yellow cathodoluminescence (CL) have been obtained for thin-films of Ba2B5O9Cl doped with Tb3+, Tm3+, and Mn2+, respectively. These phosphor films were deposited by spray pyrolysis, and then activated in air at temperatures suitable for use on glass substrates. The CL characteristic peaks of the films…
Bi 1.5 ZnSb 1.5 O 7 dielectric ceramic with pyrochlore structure was investigated by impedance spectroscopy from 400 to 750 °C. Pyrochlore was synthesized by the polymeric precursor method, a chemical synthesis route derived from Pechini’s method. The grain or bulk resistance exhibits a sensor temperature characterist…
Co–Zr–B alloys have been produced by melt-spinning followed by heat treatments. The magnetic properties of the Co–Zr–B melt-spun ribbons depend on the annealing temperature. The maximum energy product of the optimally annealed Co–Zr–B melt-spun ribbons (BH)max=4.74 MGOe, is comparable to those of the hard ferrites. Th…
The high temperature electrical behavior of highly epitaxial CaCu3Ti4O12 thin films on (001) LaAlO3 have been systematically investigated with traditional four-probe dc and ac resistance measurement techniques and two-probe ac impedance spectroscopy. Both ac and dc resistance measurements reveal that the Arrhenius plo…
Abstract The dielectric properties and the structure of various metal–polymer composites, based on a polymer matrix of polyamide (PA), polyethylene (PE), polyoxymethylene (POM), or blend PE/POM filled with dispersed iron (Fe) particles, have been investigated in this work. In PE–Fe, PA–Fe, and POM–Fe composites the fi…
We have performed ab initio studies of the effect of substitutions on the phase stabilities of Ti1−xAlxN, x=0−1. The nonmetal substitutions studied include B, C, O, and Si. Metal substitutions studied include Sc, Zr, V, Cr, and Mn. The main objective has been to suggest substitutions that increase the thermal stabilit…
Abstract Triethyl citrate (TC) was added as a plasticizer to a blend of poly(lactic acid) (PLA) and starch in the presence of methylenediphenyl diisocyanate (MDI). As expected, TC improved the elongation at break and toughness and, at the same time, decreased the tensile strength and modulus. However, TC did not signi…
A systematic study of the optical properties of tetragonal Pb(Mg1/3Nb2/3)0.62Ti0.38O3 single crystals was calculated out at room temperature. It was found that the crystal is transparent in the visible region and rolls off in near 450 nm. The optical absorption edge is around 400 nm under both unpoled and poled condit…
Asymmetric metal–ferroelectric–metal (MFM) structures were manufactured by sol–gel deposition of a lead zirconate-titanate (PZT with Zr/Ti ratio 65/35) film on Pt-coated Si, with a Au top electrode. The average remnant polarization of 9 μC/cm2 and the coercive field of 39 kV/cm were obtained from the hysteresis loop m…
We report on the magnetic and structural properties of epitaxial metal organic chemical vapor deposition grown p-GaN:Mg/Al2O3 implanted with Co, Cr, and V ions at varying high doses at 350 °C. Magnetic and structural properties were investigated after a short anneal at 700 °C to remove implantation damage. Magnetic pr…
Atomic force microscopy and Kelvin probe experiments are applied to characterize hydrogen terminated patterns contacted with gold and aluminum on (100) diamond surfaces. On hydrogen terminated diamond the work function of 4.9 eV is detected, with an accuracy of about 0.1 eV. Taking into account the negative electron a…
On the basis of a new modified base-catalyzed sol−gel process and a careful investigation in the structure, this study systematically discussed the effects of the calcining temperature on the microstructure and luminescent properties of europium-doped strontium aluminates (SAO-E). A phase transformation from Sr 3 Al 2…
Fatigue-free and highly c-axis oriented Bi4−xPrxTi3O12 (BPrT, x=0.85) thin films were grown on Pt/TiO2/SiO2/Si (100) substrates using the method of metalorganic sol decomposition. The BPrT film capacitor with a top Pt electrode showed significantly improved values of the remanent polarization (Pr) and the nonvolatile…
The homologous series M(TCNQ) 2 (M = Mn(II), Fe(II), Co(II), and Ni(II); TCNQ = 7,7,8,8-tetracyanoquinodimethane) prepared from reactions of [M(CH 3 CN) 6 ][BF 4 ] 2 and [ n -Bu 4 N][BF 4 ] in CH 3 CN has been carefully analyzed from the perspective of synthetic issues and physical characterization, including complete…
Nanotechnology enables the fabrication of wire-grid polarizers (WGP) in the visible optical region. At oblique angles of incidence, WGP can be used as polarizing beam splitters (PBS). As such, they have the advantages of large numerical aperture and high-extinction ratios in both transmission and reflection. Because o…
This article studies transverse sound wave propagation in individual multiwall carbon nanotubes. The present model predicts that there exist (N-1) critical frequencies (within terahertz range) for an N-wall carbon nanotube. When the frequency is below all critical frequencies, vibrational mode is almost coaxial and th…