Materials Literature
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To meet the goals of sustainability and to enable industrial ecology, green chemistry and engineering needs to be studied from a life-cycle perspective. When designed correctly, green chemistry and engineering can affect multiple stages of the life cycle of a product or process. Successful implementations of green che…
We describe a novel method to prepare monodisperse Pickering emulsions. We start with classical surfactant-stabilized oil-in-water emulsions, which are sheared and size fractionated to attain monodispersity. Then, the surfactant is removed by a dialysis method and simultaneously replaced by solid particles. We obtain…
The corrosion of mild steel in a seawater medium containing extracellular polymeric substances (EPS) produced by sulfate-reducing bacteria (SRB) was studied by electrochemical experiments and atomic force microscopy (AFM). Under anaerobic conditions, the corrosion of mild steel increased up to 5-fold in the presence o…
We have performed first-principles calculations on field emission (FE) from graphitic ribbons within the time-dependent density-functional theory. An important finding is that dangling bond states localized at clean edges are major contributors to FE current. H termination makes the FE current small due to the disappe…
Achiral banana-shaped molecules with dodecyloxy tail groups, P-12-O-PIMB, N-12-O-PIMB, and S-12-O-PIMB, have exhibited unusual smectic phases which possess chiral and helical structures. In this work, we mixed these banana-shaped molecules with the chiral molecule forming a chiral nematic liquid crystal and found an e…
We present numerical results on the transmission properties of the left-handed materials (LHMs) and split-ring resonators (SRRs). The simulation results are in qualitative agreement with experiments. The dependence of the transmission through LHMs on the real and imaginary part of the electric permittivity of the meta…
The unusual structural stability of gold nanowires at large separations of gold atoms is explained from first-principles quantum mechanical calculations. We show that undetected light atoms, in particular hydrogen, stabilize the experimentally observed structures, which would be unstable in pure gold wires. The enhanc…
The effect of random surface roughness on quantum size effect in thin films is discussed. The conductivity of quantized metal films is analyzed for different types of experimentally identified correlation functions of surface inhomogeneities including the Gaussian, exponential, power-law correlators, and the correlato…
Large-scale molecular dynamics of cascade production of the primary damage state are performed in fcc nanocrystalline Ni of average grain diameters of 5 and 12 nm. Primary knock-on atom kinetic energies of 5-30 keV are simulated. During the thermal spike phase, significant atomic motion towards the surrounding grain b…
High aspect ratio cadmium sulfide (CdS) quantum rods were synthesized at room temperature in the environment of water-in-oil microemulsions using a combination of two surfactants: the anionic bis(2-ethylhexyl) sulfosuccinate (AOT) and the zwitterionic phospholipid l -α-phosphatidylcholine (lecithin). These highly acic…
The size of in situ prepared silver nanoparticles and the overall metal concentration within poly(acrylic acid) (PAA) and poly(allylamine hydrochloride) (PAH) multilayer films are systematically controlled through multilayer processing conditions. Carboxylic acid groups in the PAH/PAA-based multilayers bind silver cat…
Abstract In the context of a European union‐supported network on “Reactive Surfactants for Heterophase Polymerization,” different polymerizable surfactants (surfmers) have been synthesized and engaged in the emulsion polymerization of styrene, butyl acrylate, and acrylic acid. The thermomechanical properties of films…
We consider the mode coupling theory (MCT) of glass transition for a binary fluid. The equations of nonlinear fluctuating hydrodynamics for the compressible fluid are obtained with a proper choice of slow variables which correspond to the conservation laws in the system. The resulting model equations are used to obtai…
Motivated by recent studies of colloidal systems at the effective one-component level, the validity of the first-order perturbation theory of classical systems of hard particles interacting via short-range potentials is investigated. The influence of the physical parameters on the accuracy of the perturbation theory i…
Homogeneous nanocrystalline (ZrO2)0.92(RE2O3)0.08 (RE = Y, Sc) with large specific surface areas and cubic structure were solvothermally synthesized from the urea coprecipitated (Zr,RE)-hydroxide gel or the gel-calcined oxide in water (or absolute ethanol) under mild conditions. Both the hydroxide and the oxide powder…
Abstract In this article, poly(ester ether) multiblock copolymer/organomontmorillonite hybrid nanocomposites were prepared via an intercalation polymerization process. The resulting hybrid nanocomposites were characterized by X‐ray diffraction, differential scanning calorimeter, and transmission electron microscopy. T…
In this work, we studied guest-host interactions between various dye molecules and the fifth-generation poly(propylene imine) (PPI-5) dendrimers in aqueous solutions using a surface plasmon resonance (SPR) sensor. The effect of the properties of guest and host molecules (e.g., charge and shape) and media (e.g., pH and…
By controlling the microstructure of the starting materials, i.e., by ball-milling a commercial hexagonal boron nitride (h-BN) to an amorphous boron nitride (a-BN), the subsequent high-pressure and high-temperature (HP−HT) induced phase transformation has been significantly facilitated. Namely, cubic boron nitride (c-…
Heat capacity of a thermotropic mesogen ANBC(22) ${(4}^{\ensuremath{'}}$-alkoxy-${3}^{\ensuremath{'}}$-nitrobiphenyl-4-carboxylic acid with 22 carbon atoms in alkyl chain) showing two cubic mesophases was measured by adiabatic calorimetry between 13 and 480 K. Excess enthalpies and entropies due to phase transitions w…
The Pd-mediated Glaser coupling of a zinc monoethynyl porphyrin and a magnesium monoethynyl porphyrin affords a mixture of three 4,4'-diphenylbutadiyne-linked dyads comprised of two zinc porphyrins (Zn-pbp-Zn), two magnesium porphyrins (Mg-pbp-Mg), and one metalloporphyrin of each type (Zn-pbp-Mg). The latter is easil…