Materials Literature
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Current methods to promote growth of cultured neurons use two-dimensional (2D) glass or polystyrene surfaces coated with a charged molecule (e.g. poly-L-lysine (PLL)) or an isolated extracellular matrix (ECM) protein (e.g. laminin-1). However, these 2D surfaces represent a poor topological approximation of the three-d…
Hydrophobic layered double hydroxide particles with a single layer structure have been successfully synthesised in a reverse microemulsion system; atomic force microscopy has proven a powerful tool for the study of these delicate nanoparticles.
Giant clusters: Metal-assisted hydrolysis of 2,6-bis(2-pyridylcarbonyl)pyridine with Co(O2CMe)2⋅4 H2O in hot DMF yielded an icosanuclear CoII complex containing the triply deprotonated bis(gem-diol) form of the ligand and exhibiting superparamagnetic relaxation of its magnetization. The picture shows the central Co–O…
Abstract The effects of inter‐yarn friction on the ballistic performance of woven fabric armour are investigated in this paper. Frictional sliding between yarns is implemented in a computational model of the fabric that takes the form of a network. Yarn crimp and its viscoelastic properties are taken into account. Bal…
Our ab initio calculations of CO adsorption on several low and high miller index surfaces of Cu show that the adsorption energy increases as the coordination of the adsorption site decreases from 11 to 6, in qualitative agreement with experimental observations. On each surface the adsorption energy is also found to de…
Sculpted SERS-active substrates are prepared by assembling a closed packed monolayer of uniform polystyrene colloidal particles (diameter 350 to 800 nm) onto an evaporated gold surface and then electrodepositing gold through this template to produce films with controlled thicknesses, measured as fractions of the spher…
The evolution of the thermopower EuCu{2}(Ge{1-x}Si{x}){2} intermetallics, which is induced by the Si-Ge substitution, is explained by the Kondo scattering of conduction electrons on the Eu ions which fluctuate between the magnetic 2+ and non-magnetic 3+ Hund's rule configurations. The Si-Ge substitution is equivalent…
Recently, magnetic order in highly oriented pyrolytic graphite (HOPG) induced by proton broad- and microbeam irradiation was discovered. Theoretical models propose that hydrogen could play a major role in the magnetism mechanism. We analysed the hydrogen distribution of pristine as well as irradiated HOPG samples, whi…
We computed by a Monte Carlo method derived from the Solid on Solid model, the evolution of a polycrystalline thin film deposited on a substrate during thermal treatment. Two types of substrates have been studied: a single crystalline substrate with no defects and a single crystalline substrate with defects. We obtain…
The superconductor YB6 has the second highest critical temperature Tc among the boride family MBn. We report measurements of the specific heat, resistivity, magnetic susceptibility and thermal expansion from 2 to 300 K, using a single crystal with Tc = 7.2 K. The superconducting gap is characteristic of medium-strong…
The growth of GaMnAs by molecular beam epitaxy is typically performed at low substrate temperatures $(\ensuremath{\sim}250\phantom{\rule{0.2em}{0ex}}\ifmmode^\circ\else\textdegree\fi{}\mathrm{C})$ and high As overpressures, leading to the incorporation of excess As and Mn interstitials, which quench optical signals su…
The local structure of the low-temperature ordered phase of the negative thermal expansion (NTE) material has been investigated by reverse Monte Carlo (RMC) modeling of neutron total scattering data. We obtain, for the first time, quantitative measurements of the extent to which the and polyhedra move as rigid units,…
We report indications of a phase transition in carbonaceous MgB2 above 9 GPa at 300 K after stress relaxation by laser heating. The transition was detected using Raman spectroscopy and X-ray diffraction. The observed changes are consistent with a second-order structural transition involving a doubling of the unit cell…
Exchange anisotropy in ferromagnet/antiferromagnet (FM/AF) films is usually introduced along the cooling field or FM magnetization direction. Here we investigate the dependence of the exchange anisotropy, loop bifurcation, and reversal mechanism on the cooling field direction using vector magnetometry. Three types of…
Doped semiconductors are intrinsically homogeneous media. However, by applying an external magnetic field that has a spatially periodic variation, doped semiconductors can behave extrinsically like conventional photonic crystals. We show this possibility theoretically by calculating the photonic band structures of a d…
We investigated photoluminescence (PL) from reliable and reproducible Sb-doped p-type ZnO films grown on n-Si (100) by molecular-beam epitaxy. Well-resolved PL spectra were obtained from completely dopant-activated samples with hole concentrations above 1.0×1018cm−3. From free electron to acceptor transitions, accepto…
Continuous-wave, time-integrated, and time-resolved photoluminescence experiments are used to study the excitonic optical recombinations in wurtzite $\mathrm{Zn}\mathrm{O}∕{\mathrm{Zn}}_{0.78}{\mathrm{Mg}}_{0.22}\mathrm{O}$ quantum wells of varying widths. By comparing experimental results with a variational calculati…
New hydrophobic, tetradentate nitrogen heterocyclic reagents, 6,6'-bis-(5,6-dialkyl-1,2,4-triazin-3-yl)-2,2'-bipyridines (BTBPs) have been synthesised. These reagents form complexes with lanthanides and crystal structures with 11 different lanthanides have been determined. The majority of the structures show the lanth…
Bring in the substitute! Zn1−xCoxO nanowires are prepared by using a solution-based synthetic route. Structural, optical, and spectroscopic characterizations indicate that the cobalt atoms substitute the zinc cations in the host lattice as a result of the cobalt doping (the picture shows prepared Co-doped ZnO nanowire…
Recently, we demonstrated that PbSe nanocrystal quantum dots can efficiently produce multiple electron-hole pairs (excitons) in response to a single absorbed photon. To address the generality of this carrier-multiplication phenomenon to other materials, we perform a comparative study of multiexciton generation in PbSe…