Materials Literature
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In 2003, numerous advances were made in the area of inorganic polymer science. In the main group, highlights include the preparation of siloxane nanowires using gold nanoparticles, the addition polymerization inorganic multiple bonds, and the development of new σ- and π-conjugated polymers. Novel self-assembled cylind…
This book deals with the theory and experiment of the elementary process of bremsstrahlung, where photons are detected in coincidence with decelerated outgoing electrons. Such experiments allow for a more stringent check of the theoretical work. The main emphasis is laid on electron-atom bremsstrahlung and electron-el…
This article provides a short tutorial review of how laboratory powder diffraction methods can be used to establish a variety of "non-traditional" pieces of information about solid state materials-information beyond simple phase identification or structure determination at a specific temperature. The examples show how…
(SSC) porous electrodes supported on were studied using X-ray diffraction, scanning electron microscopy, impedance spectroscopy, and dc polarization. The addition of (LSGMC5) or (LSGMC11) into SSC improved its performance significantly. Two arcs could be identified in the impedance spectra of oxygen reduction over SSC…
Coaxial Zn/ZnO core–shell nanocable heterostructures with diameters ∼100 nm were synthesized via thermal reduction of ZnO by H2. The products were characterized by X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy and cathodoluminescence. In some of the samples, an epitaxial rela…
The new methacrylate-substituted manganese carboxylate cluster [Mn12O12{CH2C(CH3)COO}16(H2O)4] having single molecule magnetic (SMM) properties was synthesized and fully characterized by X-ray crystallography, LDI-TOF, fast atom bombardment (FAB) analyses and magnetic measurements. This cluster, containing sixteen pol…
The diffusion of Co, Fe and Ni in single crystalline yttria stabilized zirconia (YSZ) containing 9.5 mol% Y2O3 was studied in the temperature range between 1373 and 1673 K using secondary ion mass spectroscopy. Two different types of diffusion sources were used: thin oxide layers made by spin coating with a thickness…
Four coumarin (2-oxo-2H-1-benzopyran) containing liquid crystalline polymethacrylates possessing the same monomer formula but different linkage directions and/or construction directions of their mesogens into the same main-chain were prepared and investigated. Each of the four polymers exhibits a smectic A liquid crys…
The use of graft copolymer of maleic anhydride polypropylene (MAPP) as a coupling agent in jute-polypropylene composites improved the mechanical properties of the composites. The scanning electron microscope (SEM) observations for fractured surfaces of unmodified and modified jute-polypropylene composites confirmed th…
In this paper comparative investigations of microstructure and dielectric properties of BaTiO3 ceramics doped with 1.0 wt% of Nb2O5, MnCO3 and CaZrO3 have been done. BaTiO3 samples were prepared using conventional method of solid state sintering at 13000C for two hours. Two distinguish micro structural regions can be…
Barium titanate (BT) nano-particles with different diameters were prepared by Sol-Gel method. The particle diameter was determined by XRD, and the lattice constants of nano-particles were also determined by XRD. We also measured the lattice vibration for BT nano-particles by Raman scattering to discuss on the size eff…
X-Ray absorption spectroscopy was used to probe the coordination of different encrypted cations in the Preyssler anions [M(n+)P5W(30)O(110)]((15-n)-)(M(n+)= Sr2+, Am3+, Eu3+, Sm3+, Y3+, Th4+, U4+ in decreasing order of ionic radius, IR), hereafter abbreviated [M(n+)PA](15-n)-. The increase of the M-W distance and the…
The copper(II) complex Cu(2)L(OMe)(H(2)O)(3), [middle dot]3H(2)O [H(3)L = 2-(2-hydroxyphenyl)-1,3-bis[4-(2-hydroxyphenyl)-3-azabut-3-enyl]-1,3-imidazolidine] was obtained and recrystallised in methanol to yield crystals of [[Cu(2)L(OMe)]](2).2.5MeOH.4H(2)O, 1.2.5MeOH.4H(2)O. Its single X-ray study shows that it contai…
We have investigated the magnetic and electrical properties of iron nitride films containing both amorphous matrices and nanocrystalline grains. It is found that both the number and the size of the grains in the amorphous matrix increase as the film thickness increases. The grain is confirmed to have anε-Fe3N structur…
Supported Pd-P and Pd-N complexes prepared by a selective reaction of Pd-monomer precursors with SiO2, Al2O3 and TiO2 surfaces and characterized by EXAFS, XPS, XRF and gas analysis exhibited oxide surface-promoted catalysis for the catalytic intrahydroamination of 3-amino propanol vinyl ether to produce a cyclic amine.
The semiconductor properties of passive films formed on an Fe–18Cr alloy with various additive elements in a borate buffer solution were studied using electrochemical impedance spectroscopy and photoelectrochemical response. The photocurrent was plotted as a photoelectrochemical action spectrum that could be separated…
We have studied the lasing characteristics of a dye-doped nematic layer sandwiched by two polymeric cholesteric liquid crystal (CLC) films as photonic band gap (PBG) materials. The nematic layer acts as a defect layer, the anisotropy of which brings about the following remarkable optical characteristics: (1) reflectan…
ZrWMoO8 has been shown to undergo a phase transition at remarkably low temperatures in which oxygen atoms become dynamically disordered. The kinetics of this process have been studied by a variety of laboratory-based time and temperature dependent powder diffraction experiments. Oxygen mobility from temperatures as lo…
The influence of in-coating strontium chromate pigment dispersions on the kinetics and mechanism of HCl-induced filiform corrosion (FFC) affecting polyvinyl butyral coated AA2024 T3 aluminum alloy is studied using a scanning Kelvin probe. FFC initiation and propagation are detected by imaging time-dependent changes in…
A novel symmetric liquid crystalline compound with two chiral butyl lactate chains, (S,S)-bis[4-(1-butoxycarbonyl)ethyloxycarbonyltolanyl]fumarate (BisBLOCTF), was synthesized. This compound was found to exhibit a very unusual phase sequence involving several frustrated mesophases, namely smectic Q, TGBC, TGBA and blu…