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Solvent-Induced Crystallization of Syndiotactic Polystyrene: Thermodynamics and Morphology

Biswajit Ray、Said Elhasri、A. Thierry 等 5 位作者2002-11-14Macromolecules

The thermodynamic properties and the morphology of syndiotactic polystyrene solid samples exposed to solvents (benzene and toluene) are investigated. It is shown that, as far as the melting properties are concerned, there is no significant difference between these samples and solution-cast samples. This suggests that…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesAdvanced Physical and Chemical Molecular Interactions

Etching of Colloidal InP Nanocrystals with Fluorides: Photochemical Nature of the Process Resulting in High Photoluminescence Efficiency

Dmitri V. Talapin、Nikolai Gaponik、Holger Borchert 等 6 位作者2002-11-14The Journal of Physical Chemistry B

The photoluminescence efficiency of InP nanocrystals prepared via the dehalosilylation reaction between indium chloride and tris-(trimethylsilyl)phosphine in mixtures of trioctylphosphine and trioctylphosphine oxide can be drastically improved by etching with fluorine compounds, as proposed several years ago by Micic…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Density-functional theory of linear and nonlinear time-dependent molecular properties

Paweł Sałek、Olav Vahtras、Trygve Helgaker 等 4 位作者2002-11-14OpenAlex

We present density-functional theory for linear and nonlinear response functions using an explicit exponential parametrization of the density operator. The response functions are derived using two alternative variation principles, namely, the Ehrenfest principle and the quasienergy principle, giving different but nume…

Advanced Chemical Physics StudiesPorphyrin and Phthalocyanine ChemistryNonlinear Optical Materials Research

Plasmon resonances in large noble-metal clusters

Carsten Sönnichsen、T. Franzl、Tatjana Wilk 等 5 位作者2002-11-14OpenAlex

We investigate the optical properties of spherical gold and silver clusters with diameters of 20 nm and larger. The light scattering spectra of individual clusters are measured using dark-field microscopy, thus avoiding inhomogeneous broadening effects. The dipolar plasmon resonances of the clusters are found to have…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Researchnanoparticles nucleation surface interactions

On the origin of binding energy shifts of core levels of supported gold nanoparticles and dependence of pretreatment and material synthesis

Jörg Radnik、Christian Mohr、Peter Claus2002-11-14OpenAlex

X-ray photoelectron spectroscopy (XPS) investigations of supported nanoparticles smaller than 10 nm show a significant shift of the electron binding energy of core levels compared with the bulk values. In this work, such shifts were examined at differently supported and prepared gold nanoparticles for the 4f electron…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Broadband Modulation of Light by Using an Electro-Optic Polymer

Mark Lee、Howard E. Katz、Christoph Erben 等 7 位作者2002-11-14OpenAlex

A major challenge to increasing bandwidth in optical telecommunications is to encode electronic signals onto a lightwave carrier by modulating the light up to very fast rates. Polymer electro-optic materials have the necessary properties to function in photonic devices beyond the 40-GHz bandwidth currently available.…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchAcoustic Wave Resonator Technologies

Study of diluted magnetic semiconductor: Co-doped ZnO

Hyunjun Lee、Se‐Young Jeong、Chae‐Ryong Cho 等 4 位作者2002-11-14OpenAlex

We report on the high-temperature ferromagnetism in Co-doped ZnO films fabricated by the sol–gel method above 350 K. The lattice constant of c axis of wurtzite Zn1−xCoxO follows Vergard’s law for 0<x<0.25. For Zn1−xCoxO with x⩾0.25, a secondary phase is detected. The Zn1−xCoxO exhibits ferromagnetic beha…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsCopper-based nanomaterials and applications

Solid oxide fuel cells

R. Mark Ormerod2002-11-14OpenAlex

Despite being first demonstrated over 160 years ago, and offering significant environmental benefits and high electrical efficiency, it is only in the last two decades that fuel cells have offered a realistic prospect of being commercially viable. The solid oxide fuel cell (SOFC) offers great promise and is presently…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Modelling of the electric field in HVDC cables

Daniela Cârstea、Ion Cârstea2002-11-13OpenAlex

The scope of this paper is to present some aspects in modeling of electrical field in high-voltage direct-current (HVDC) cables. Some computation models for electrical fields are presented. Computation procedures are developed for DC cables with one and two imperfect dielectric insulation layers for capacitive and res…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaAerosol Filtration and Electrostatic Precipitation

Additional losses in massive copper conductor due to eddy-currents

G.J. Pavkov、S.S. Milovancev2002-11-132001 IEEE Power Engineering Society Winter Meeting. Conference Proceedings (Cat. No.01CH37194)

While measuring the resistive losses in transformer windings, a great difference between the measurement results of additional losses was noticed due to the skin-effect at the transformer without box and the theoretical calculated results. In order to find the reason for the phenomenon, measurements of resistive losse…

Magnetic Properties and ApplicationsPower Transformer Diagnostics and InsulationNon-Destructive Testing Techniques

Numerical analysis of space charge distribution in polypropylene film under AC high field

Masayuki Fujii、M. Fukuma、T. Tokoro 等 6 位作者2002-11-13OpenAlex

AC dissipation current waveforms of polyethylene and polypropylene films show nonlinear distortion in AC high-field region. This non-linearity was supposed to be related to the behavior of AC space charge formation in the sample. However, the measurement of AC space charge distribution is not so easy due to the resolu…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

Photoluminescence in polymeric insulating materials (low density polyethylene and polypropylene) induced by ultraviolet photons

Toshihide Ito、T. Toyoda、Naoshi Hirai 等 4 位作者2002-11-13OpenAlex

For the polymeric insulating materials such as polypropylene (PP) and low density polyethylene (LDPE), the surface oxidization and chain scission that deteriorate the insulation performance are induced by the irradiation of the ultraviolet photons. Photochemical reactions are responsible for such oxidization and bond…

High voltage insulation and dielectric phenomena

Analysis of trapping parameters in surface layer of solid insulating materials

G.J. Zhang、X.R. Wang、Z. Yan2002-11-13OpenAlex

In this paper, we have investigated the trapping parameters in the surface layer of two kinds of insulating materials. The final aim is to construct the relationship between the surface microstructure of an insulating material and its flashover phenomena.

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationHigh-Voltage Power Transmission Systems

Partial discharge database: its benefits and limitations on assessment of stator insulation deterioration

Heng Zhu、V. Green、M. Šašić 等 4 位作者2002-11-13OpenAlex

PD test data on various generators and motors has been collected over 15 years using on-line partial discharge analyzers. A large PD test database has been established. The database provides an overall view of PD activity on rotating machines. Statistical analysis of the database provides a study of PD distribution wi…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

Power supply systems of microprocessor devices

Volodymyr Yaskiv、O. Gurnik、S. Moskalyk 等 4 位作者2002-11-13OpenAlex

New methods of switched power supplies and power supply system design for microprocessor devices, based on the use of modern high-frequency amorphous alloys with a rectangular hysteresis loop, are proposed. The basic technical solutions are described and the results of research are shown. The main technical data of mu…

Advanced DC-DC ConvertersInduction Heating and Inverter TechnologyAdvanced Materials and Semiconductor Technologies

High frequency methods for characterization of oxidized porous silicon

Rebecca L. Peterson、I.K. Itotia、R.F. Drayton2002-11-13OpenAlex

This paper compares insertion loss and T-resonator methods to characterize the electrical properties of oxidized porous silicon. The insertion method provided consistent dielectric and attenuation data on a range of conductive substrates, while the T-method was limited to low loss substrates. The estimated effective d…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Nondestructive maturity determination of durian by force vibration

S. Kongrattanaprasert、Somchai Arunrungrusmi、B. Pungsiri 等 5 位作者2002-11-13OpenAlex

This paper proposes a method for determining maturity levels of durian by using nondestructive vibration. The vibration is transferred directly through durian at a region between prickles located at the middle of durian. The measurement of frequency response from vibration of durian is performed by using laser Doppler…

Liquid Crystal Research AdvancementsPolysaccharides and Plant Cell WallsOptical Polarization and Ellipsometry

Surface flashover studies on precompressed pressboard insulation under superimposed AC/DC voltages

C. Viswantha、K. S. Dwarakanath、V. Sathya Nagakumar2002-11-13OpenAlex

The scale down models of pre-compressed mineral oil insulation system have been studied under surface flashover of the surface of insulation. The experimental investigations have been dealt with for conventional AC, DC and superimposed voltages of AC/DC at different electrode gap distances. Two types of models using c…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationHigh-Voltage Power Transmission Systems

Multiscale approaches to thermoelectric materials and devices

Ce‐Wen Nan、Junbo Wu、Jun Nan 等 5 位作者2002-11-13OpenAlex

Performance of thermoelectric materials and devices depends upon various features on different levels from microscopic to macroscopic scales. On the atomic scale, to find new multi-component compounds with complex electronic and crystal structures is a way to high-Z thermoelectric materials. On the nano-scale, quantum…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Optimisation of a numerical model for analysis of partial discharge phenomena in a flat cavity

R. Candela、R. Schifani、Pietro Romano2002-11-13OpenAlex

The failure probability of the insulation in HV components can be studied through partial discharge (PD) measurements to detect defects. A numerical model, previously developed by the authors for the simulation of PD activity in a spherical void embedded in epoxy resin, is implemented for a flat cavity under a diverge…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics