Materials Literature
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The current imperfect understanding about the adsorption behavior of heavy metals on hydroxyaluminum (HyA)‐ and hydroxyaluminosilicate (HAS)‐interlayered phyllosilicates led us to conduct this study. We examined the adsorption behavior of Cd, Zn, and Pb on synthetically prepared HyA– and HAS–montmorillonite (Mt) compl…
The facile creation of oriented single crystal colloidal assemblies directly on a silicon substrate and conversion to a high refractive index contrast photonic crystal is reported here. The route unveiled has great potential for applications in optoelectronics. The Figure displays the sharp boundary between colloidal…
The products and oxidative polycondensation reaction conditions of salicylaldehyde (SA) with air oxygen and sodium hypochloride (NaOCl) were studied. In this reaction, NaOCl was observed to be more active than O2 and their optimum reaction conditions were determined. Oligosalicylaldehyde (OSA) was synthesized from the…
PURPOSE: We evaluated the safety of a gadolinium (Gd) contrast agent in hemodialysis patients. MATERIAL AND METHODS: Seventy hemodialysis patients underwent contrast-enhanced MR examination. After the examination, the patients were hemodialyzed on a usual schedule, i.e., 3 times per week at 4 h each session. The hemod…
Regular arrays of metallic nanoparticles are formed by these authors using a novel technique involving electron-beam induced cluster formation in the transmission electron microscope (TEM). Nucleation is initiated in the cavities between crystalline bacterial surface layers deposited on a solid support, as schematical…
A coating system based on different combinations of natural magnetite and carbon black filled epoxy resin has been developed. The influence of filler concentration and the ordering of the layers in the absorbing structure on the coefficients of attenuation and reflection of the electromagnetic waves in the frequency r…
Nanocrystalline (nc) materials are characterized by a typical grain size of 1-100nm. The uniaxial tensile deformation of computer-generated nc samples, with several average grain sizes ranging from 5.38 to 1.79nm, is simulated by using molecular dynamics with the Finnis-Sinclair potential. The influence of grain size…
The molecular mobility of polystyrene (PS) chains near the surface of carbon fibers was investigated. The glass transition temperature of very thin coatings deposited on carbon fibers was measured by supported DMTA in order to probe the properties of the thermoplastic interphase. Depending on the fiber impregnation me…
Abstract Infrared and Raman spectra of magnesia cement, Mg 2 (OH) 3 Cl · 4 H 2 O (phase 3), were observed at room temperature. The formation process of phase 3 was investigated from the change in OH − stretching vibrations by comparison with those of phase 5. Broad infrared bands were observed at ∼1300 cm −1 (H system…
Recent development of diamond field emitter cathodes and devices fabricated from molding process is presented. Practical modifications involving the sp2 content, surface treatment, boron doping, and tip sharpening to further enhance diamond field emission are discussed. A new fabrication process for achieving ultrasha…
New efficient mechanisms of long-wavelength excitation of short-wavelength luminescence in a system of rare-earth impurity ions are proposed. The model studied involves a multilevel system of electronic states of a rare-earth ion interacting with the long-wavelength emission that is in resonance with one or several tr…
Benzylated fibre (BzF) was produced from fibres of oil palm empty fruit bunches (EFBs) using benzyl chloride in an etherification reaction for 2 h at two reaction temperatures, 100°C and 110°C. Estimates based on X-ray diffraction data show decreases of approximately 15 and 17%, respectively, in the crystallinity of c…
Abstract Raman spectra of two spin‐transition polymers, [Fe(NH 2 trz) 3 ](ClO 4 ) 2 and [Fe(Htrz) 3 ](ClO 4 ) 2 , where NH 2 trz=4‐NH 2 ‐1,2,4‐triazole and Htrz=1‐H‐1,2,4‐triazole, were investigated. The low‐temperature high‐spin to low‐spin phase transition of [Fe(NH 2 trz) 3 ](ClO 4 ) 2 is reported. The increasing i…
The microstructural features and tensile creep behavior of Al 2 O 3 doped with Nd 2 O 3 at levels ranging from 100 to 1000 ppm (Nd:Al atomic ratio) were systematically investigated. Compositional mapping, using both high‐resolution scanning transmission electron microscopy and secondary ion mass spectroscopy revealed…
Various aspects of in situ formation of Al 2 O 3 –SiC composites by the self‐propagating high‐temperature synthesis (SHS) technique have been investigated using thermal analyses (TG/DTA) of a powder mixture (4Al, 3SiO 2 , 3C) and pellets in an argon atmosphere at different heating rates. Both the reaction initiation a…
Ordered mesoporous carbons have recently been synthesized using ordered mesoporous silica templates. The synthesis procedure involves infiltration of the pores of the template with appropriate carbon precursor, its carbonization, and subsequent template removal. The template needs to exhibit three-dimensional pore str…
To understand and control hydrogen induced cracking and stress corrosion cracking, the processes of hydrogen absorption, diffusion and trapping are of interest. Fundamentals of these processes are described and of the determination of permeation coefficient, diffusivity and solubility of H in iron and steels, using th…
There are apparently conflicting observations about the influence of seawater temperature on the immersion corrosion of copper-nickel alloys, with both increases and decreases in temperature having been observed. During the 1980s, ASTM sponsored a worldwide corrosion study, which included 90:10 copper-nickel (UNS C070…
In support of the Federal Aviation Administration's Catastrophic Failure Prevention Program, SRI International has identified advanced materials and is developing shielding concepts to protect critical aircraft components from uncontained engine debris. Full-scale fragment impact tests on a commercial aircraft fuselag…
Results of the dielectric studies of nine members of the nBT (4-n-alkyl-4'-thiocyanatobiphenyl, n= 2-10) homologous series in the crystal E (E) and isotropic (I) phases are presented. The dependence of the static permittivity ∊s in the isotropic phase, the longitudinal relaxation times τis and τ∥, and the activation e…