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Effect of photo‐initiators on melt degradation of polypropylene and starch‐filled polymer

Rouhollah Bagheri、Faranak Naimian2002-10-01Polymer International

Abstract Six series of the processed polypropylene (pp) samples containing 0.25–1 wt% photo‐initiators (PIs, four aromatic carbonyl, two ferric compounds) and also a series of 6 wt% corn‐starch‐filled pp containing 0.5 wt% of each PI, were prepared using a mixer in a closed system at 180 °C for 5 min. The melt flow in…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesMaterial Properties and Processing

Studies on hydrogen embrittlement of nitrogen containing austenitic alloys

Margitta Uhlemann、U.K. Chatterjee、S. Ningshen 等 5 位作者2002-10-01Materials Science and Technology

The influence of hydrogen on the mechanical properties of four austenitic CrNiMo and CrMn alloys with nitrogen contents up to 0.57 wt-% were investigated concerning their resistance against hydrogen embrittlement in correlation to nitrogen content, chemical composition, and hydrogen diffusivity and solubility. Tensile…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Vapor Bubbles in Flow and Acoustic Fields

Andréa Prosperetti、Yue Hao2002-10-01Annals of the New York Academy of Sciences

A review of several aspects of the interaction of bubbles with acoustic and flow fields is presented. The focus of the paper is on bubbles in hot liquids, in which the bubble contains mostly vapor, with little or no permanent gas. The topics covered include the effect of translation on condensation in a subcooled liqu…

Fluid Dynamics and MixingUltrasound and Cavitation PhenomenaParticle Dynamics in Fluid Flows

Hall-Petch behaviour of 316L austenitic stainless steel at elevated temperatures

K. K. Singh、S. Sangal、G. S. Murty2002-10-01Materials Science and Technology

The plastic deformation behaviour of two different batches (having differences in chemical composition) of 316L austenitic stainless steel has been explored in the 200-800°C temperature range as a function of grain size. The plastic behaviour is correlated with microstructural observations of annealed and deformed sam…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsHigh Temperature Alloys and Creep

Rigid segments of condensation polyetherurethanes

Anita Białkowska、ZYGMUNT WIRPSZA2002-10-01Polimery

On the basis of the changes of physical properties such as refractive index, dynamic viscosity, pH value (Table 1) and spectrum analysis (IR, l H NMR and 1 3 C NMR - Figs. 1-5) a probable reaction course (scheme A) and chemical structures of the products formed in the system consisting from urea (here: M), phenylsulfo…

Inorganic and Organometallic ChemistrySynthesis and properties of polymersSilicone and Siloxane Chemistry

Studies on hydrolytic degradation of epoxy‐polyester resins cured with glutaric anhydride

Jan Łukaszczyk、Katarzyna Jaszcz2002-10-01Polymers for Advanced Technologies

Abstract Biodegradable epoxy‐polyester resins were synthesized in two steps: (1) synthesis of the polyesters with allyl pendent groups; (2) epoxidation of allyl groups in the polyesters. Polyesters with allyl pendent groups were synthesized by melt copolymerization of succinic anhydride (SA) and allyl glycidyl ether (…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Utilisation of Egyptian industrial waste material in manufacture of refractory cement

M.F. Zawrah、N.M. Khalil2002-10-01British Ceramic Transactions

Egyptian calcium hydroxide byproduct, produced as a waste material during preparation of acetylene gas, causes various ecological problems. The present work had the aim of utilising this waste material as a source of calcium oxide in the production of refractory calcium aluminate cement. Two types of calcium aluminate…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisZeolite Catalysis and Synthesis

Ion Pairs between Maleonitriledithiolato Complex Dianions of Cobalt and Nickel and Macrocyclic Ligand Complex Dications of Nickel(II) — Control of Intrapair Interaction through Ligand Modification

Beata Nowicka、Georg Schmauch、Teiji Chihara 等 7 位作者2002-10-01Bulletin of the Chemical Society of Japan

Abstract The ion pairs {[Ni(cyclam)]2+[M(mnt)2]2−} (M = Co, Ni: 1a,b), {[Ni(tmc)]2+[M(mnt)2]2−} (M = Co, Ni: 2a,b) and the solvent complexes {[Ni(cyclam)(dmso)2]2+[M(mnt)2]2−} (M = Co, Ni, mnt2− = maleonitriledithiolato = (Z)1,2-dicyano-1,2-ethylenedithiolato, cyclam = 1,4,8,11-tetraazacyclotetradecane, tmc = 1,4,8,11…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchThermal Expansion and Ionic Conductivity

Determination of the second order susceptibility tensor in banana-shaped liquid crystals

J. A. Gallastegui、C. L. Folcia、J. Etxebarría 等 6 位作者2002-10-01Liquid Crystals

Optical second harmonic generation (SHG) measurements have been carried out on the B2 phases of three liquid crystal materials composed of conventional banana-shaped molecules (P-10-O-PIMB, P-8-O-PIMB and P-8-PIMB). Quantitative values of the second order susceptibilities dij have been deduced from SHG measurements at…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Chemical reactions and morphological stability at the Cu/Al 2 O 3 interface

Christina Scheu、Stephan Klein、Antoni P. Tomsia 等 4 位作者2002-10-01Journal of Microscopy

The microstructures of diffusion-bonded Cu/(0001)Al2O3 bicrystals annealed at 1000 degrees C at oxygen partial pressures of 0.02 or 32 Pa have been studied with various microscopy techniques ranging from optical microscopy to high-resolution transmission electron microscopy. The studies revealed that for both oxygen p…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesCopper Interconnects and Reliability

Self-Assembly of Organo-Sulfur, Selenium and Tellurium Compounds via π-π-Stacking and Hydrogen Bonding Interactions

Berthold Kersting2002-10-01Zeitschrift für Naturforschung B

Abstract The crystal structures of 2-isopropyl-benzisothiazol-3-one-7-carboxylicacid isopropyl amide and of the corresponding selenium and tellurium derivatives have been determined. In contrast to the sulfur and selenium compounds, the tellurium derivative has an unprecedented three-dimensional network structure held…

Nonlinear Optical Materials ResearchOrganic and Molecular Conductors ResearchOrganic Chemistry Cycloaddition Reactions

An analysis of transformer excitation current under nonsinusoidal supply voltage

D.G. Ece、Hüseyin Akçay2002-10-01IEEE Transactions on Instrumentation and Measurement

In this paper, the effect of nonsinusoidal supply voltage on the core loss and the transformer excitation current is investigated. The time-domain waveform of the transformer excitation current is calculated for a worst-case harmonic composition of supply voltage.

Power Quality and HarmonicsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

A preliminary study for evaluation of skirt asymmetric drape

V. Sidabraite、Vitalija Masteikaitě2002-10-01International Journal of Clothing Science and Technology

Undesirable effect of asymmetric drape often occurs when cutting patterns of flared skirt on cross. Out of this reason garment seams twist toward the front or back or folds form different shapes on each side of the garment and this lowers garment aesthetic appearance. The new measuring procedure for asymmetric skirt d…

Mechanical Behavior of CompositesOptical measurement and interference techniquesTextile materials and evaluations

"HONEYCOMB FILMS": BIOINTERFACE FOR TISSUE ENGINEERING

Takehiro Nishikawa、Keiko Arai、Junko Hayashi 等 5 位作者2002-10-01International Journal of Nanoscience

We report that tissue-like structure can be formed when cells are cultured on a microporous polymer film (honeycomb film). The honeycomb films were fabricated by applying a moist air to a spread polymer solution containing biodegradable polymers (poly(L-lactic acid) (PLLA) and poly(ε-caprolactone) (PCL)) and an amphip…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Grain Growth of α‐SiAlON in the Calcium‐Doped System

Ya‐Wen Li、Pei‐Ling Wang、Wei‐Wu Chen 等 5 位作者2002-10-01Journal of the American Ceramic Society

Two calcium‐doped α‐SiAlON compositions (Ca 0.6 Si 10.2 Al 1.8− O 0.6 N 15.4 and Ca 1.8 Si 6.6 Al 5.4 O 1.8 N 14.2 ) were prepared by hot pressing at 1600° and 1500°C, respectively, for complete phase transformation from α‐Si 3 N 4 to α‐SiAlON. Both samples were subsequently fired at different temperatures for differe…

Bone Tissue Engineering MaterialsAdvanced ceramic materials synthesisGlass properties and applications

The Stability of Fe-Mg Chlorites in Hydrothermal Solutions: Ii. Thermodynamic Properties

Stephen U. Aja2002-10-01Clays and Clay Minerals

Abstract The hydrothermal stabilities of a low-Fe clinochlore and a high-Mg chamosite, in the presence of kaolinite, were investigated recently at T ⩽ 200°C and <mml:math xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mnf="http://cambridge.org/core/manifest" xmlns:cup="http://contentservices.cambridge.org" xmlns:mml…

Clay minerals and soil interactionsMine drainage and remediation techniquesChemical and Physical Properties in Aqueous Solutions

Small-angle x-ray scattering in a carbon-sulfur nanocomposite produced from bulk nanoporous carbon

É. A. Smorgonskaya、R. N. Kyutt、V. B. Shuman 等 6 位作者2002-10-01Physics of the Solid State

A new nanocomposite material containing approximately 50 vol % S is prepared by filling pores of bulk nanoporous carbon samples with sulfur. The initial nanoporous carbon samples are synthesized from polycrystalline α-SiC through the chemical reaction. A comparative investigation of small-angle x-ray scattering (SAXS)…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchX-ray Diffraction in Crystallography

ESR and Photo-ESR Study of Defects in CVD Diamond

Konstantin Iakoubovskii、A. Stesmans、Miloš Nesládek 等 4 位作者2002-10-01physica status solidi (a)

Two hydrogen and two Si-related defect centers were detected and characterized by electron spin resonance (ESR) in diamond films grown by chemical vapor deposition. Observation of hyperfine structure, combined with illumination and polishing treatments, suggests that the KUL2 and KUL9 ESR centers originate from two ch…

Semiconductor materials and devicesDiamond and Carbon-based Materials ResearchElectronic and Structural Properties of Oxides

Photochromic characteristics of monodisperse microcapsules containing azobenzene derivative-doped nematic liquid crystals

No-Hyung Park、Sung-Ll Park、Kyung‐Do Suh2002-10-01Liquid Crystals

Highly mono-sized dye-doped liquid crystal (LC) microcapsules were prepared by the solute codiffusion method for application in photoswitchable devices. Azobenzene derivatives, which can be photoisomerized by irradiation with UV (366 nm) and visible (433 nm) light, were used as a photoresponsive dichroic dye. The micr…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

Titanium dioxide photocatalysed oxidation of plasticisers in thin poly(vinyl chloride) films

Justin Searle、David Worsley2002-10-01Plastics Rubber and Composites Macromolecular Engineering

A closed system incorporating FTIR continuous monitoring and GC-MS sampling has been developed to study the generation under UVA illumination of volatile photodegradation products from model plasticised and TiO2 pigmented films. The presence of the plasticiser dibutyl adipate (DBA), at levels of 0-88 phr, has been sho…

Advanced Polymer Synthesis and CharacterizationMicroplastics and Plastic PollutionPolymer Science and PVC