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Effect of dye doping on the charge carrier balance in PPV light emitting diodes as measured by admittance spectroscopy

I. N. Hulea、R. F. J. van der Scheer、H. B. Brom 等 6 位作者2003-06-27arXiv

Dye doping is a promising way to increase the spectral purity of polymer light-emitting diodes (LEDs). Here we analyze the frequency and field dependence of the complex admittance of Al-Ba-PPV-PEDOT-ITO LEDs with and without dye. We compare the charge carrier mobilities of pristine and dye-doped double-carrier and hol…

Materials ScienceSoft Condensed Matter

Radiation pattern of a classical dipole in a photonic crystal: photon focusing

Dmitry N. Chigrin2003-06-27arXiv

The asymptotic analysis of the radiation pattern of a classical dipole in a photonic crystal possessing an incomplete photonic bandgap is presented. The far-field radiation pattern demonstrates a strong modification with respect to the dipole radiation pattern in vacuum. Radiated power is suppressed in the direction o…

Materials ScienceSoft Condensed Matter

Schrodinger Equation for Nanoscience

J. Marciak-Kozlowska、M. Kozlowski2003-06-27arXiv

The second order (in time) Schrodinger equation is proposed. The additional term (in comparison to Schrodinger equation) describes the interaction of particles with vacuum filled with virtual particle-antiparticle pairs (zitterbewegung). Key words: Schrodinger equation; Nanoscience; Zitterbewegung.

Materials Science

The One-Dimensional Boltzmann Equation for the Heat Transport Induced by Ultra-Short Laser Pulses

J. Marciak-Kozlowska、M. Kozlowski2003-06-27arXiv

In this paper the Boltzmann transport equation for thermal processes induced by ultra-short laser pulses is formulated and solved. For thermal process where the duration of the laser pulse (femtoseconds - attoseconds) is shorter than the relaxation time, the solution of Boltzmann equation differs from the solution of…

Materials Science

Experimental Demonstration for the Morphological Evolution of Crystals Grown in Gel Media

Yuya Oaki、Hiroaki Imai2003-06-27Crystal Growth & Design

The morphological evolution of the inorganic crystals (Ba(NO 3 ) 2, NH 4 Cl, H 3 BO 3, and K 2 Cr 2 O 7 ) was demonstrated in various kinds of organic gel media (agar, gelatin, pectin, and poly (vinyl alcohol)). As the gel density increased, the morphology grown in the gel matrix remarkably changed from polyhedral sin…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

A statistic for local intensity differences: robustness to anisotropy and pseudo-centering and utility for detecting twinning

Jennifer E. Padilla、Todd O. Yeates2003-06-27Acta Crystallographica Section D Biological Crystallography

A new approach to analyzing macromolecular single-crystal X-ray diffraction intensity statistics is presented. Instead of considering reflections in resolution shells, differences between local pairs of reflection intensities are taken and normalized separately. When the two reflections to be compared (having intensit…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

The Assembly of Coated Nanocrystals

Luis M. Liz‐Marzán、Paul Mulvaney2003-06-27The Journal of Physical Chemistry B

The formation of nanostructured materials through the assembly of nanocrystals is described, focusing in particular on silica and other metal oxide coated core particles. The preparation and optical characterization of core−shell materials are reviewed, and some of the unique properties of core−shell materials are pre…

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesPhotonic Crystals and Applications

Relation between Eu2 and Ce3 f d-transition energies in inorganic compounds

P. Dorenbos2003-06-27OpenAlex

Data available on the fd-transition energies of Ce 3+ in inorganic compounds are compared with those of Eu 2+ in the same compounds. Despite differing charge compensating defects, clear correlation was found. The redshift of absorption, the Stokes shift of emission, the centroid shift of the 5d configuration and the t…

Luminescence Properties of Advanced MaterialsRadioactive element chemistry and processingNuclear materials and radiation effects

Dry Reforming of Ethane on Trimetallic Perovskites LaCoxFe1-xO3: Characterizations and Reactivity

Gerardo Rodríguez、L. Bedel、Anne‐Cécile Roger 等 6 位作者2003-06-26ACS symposium series

Performances of LaCo x Fe 1-x O 3 perovskites as catalysts in dry reforming of ethane have been studied. Depending on x, the crystalline structure of the perovskite can be either orthorhombic or rhombohedral. The catalytic activity of the perovskite is tightly linked to its structure. If x ≤ 0.5 the reducing catalytic…

Catalytic Processes in Materials ScienceMagnetic and transport properties of perovskites and related materialsCatalysis and Oxidation Reactions

A possibility of achieving a high carrier mobility in quasi-one-dimensional organic crystals

Anatolie Casian、Alexander A. Balandin、V. Dusciac 等 5 位作者2003-06-26OpenAlex

We theoretically investigate the modulation of carrier mobility in quasi-one dimensional organic crystals that consist of linear chains of conducting molecules. Two major electron-phonon interaction mechanisms are included in our model. It is shown that under certain conditions, the interplay of these two mechanisms m…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic and Molecular Conductors Research

Investigation results on semiconducting glaze and polymer insulators removed from a heavy contamination condition in China

L. Wang、Y.S. Liu、Z. Liu 等 6 位作者2003-06-26IEEE PES Transmission and Distribution Conference and Exhibition

This paper describes the investigation results of semiconducting glaze porcelain and silicone rubber polymer insulators removed from the transmission line under a heavy contaminated condition, the suburbs of Tianjin in China for 5 years in order to evaluate the long-term reliability of these insulators. Specimen insul…

High voltage insulation and dielectric phenomena

Structural and electronic properties of Ge-Te clusters

Ramkumar Natarajan、Serdar Öğüt2003-06-26Physical review. B, Condensed matter

The atomic and electronic structures of IV-VI semiconductor clusters ${\mathrm{Ge}}_{n}{\mathrm{Te}}_{m}(n+m<~10)$ are investigated using a real-space higher-order finite-difference ab initio pseudopotential method. Langevin molecular dynamics coupled to a simulated annealing procedure allows us to find the geometr…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Green-function theory of confined plasmons in coaxial cylindrical geometries: Zero magnetic field

M. S. Kushwaha、B. Djafari-Rouhani2003-06-26Physical review. B, Condensed matter

A theoretical investigation is made of the plasmon propagation in the coaxial cylindrical geometries using Green function (or response function) theory in the absence of an applied magnetic field. The plasmon excitations in such multiple interface structures are characterized by the electromagnetic (EM) fields that ar…

Graphene research and applicationsQuantum and electron transport phenomenaSurface and Thin Film Phenomena

Molecular stability of chemically modified collagen triple helices

Camilla Giudici、Manuela Viola、Maria Enrica Tira 等 5 位作者2003-06-26FEBS Letters

Ionic residues influence the stability of collagen triple helices and play a relevant role in the spontaneous aggregation of fibrillar collagens. Collagen types I and II and some of their CNBr peptides were chemically modified in mild conditions with two different protocols. Primary amino groups of Lys and Hyl were N-…

Protein Hydrolysis and Bioactive PeptidesMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

Polyglycolide‐based blends for drug delivery: A differential scanning calorimetry study of the melting behavior

Kirsten J Dickers、Hiep Huatan、Ruth E. Cameron2003-06-26Journal of Applied Polymer Science

Abstract The melting behavior of polyglycolide (PGA) with eight other biodegradable polymers was investigated to determine whether forming a blend could be used as a method of lowering the melting point of PGA. Blends were prepared by melt processing in differential scanning calorimetry (DSC) pans and were then analyz…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Electronic Structure of Carbon Nanostripes

A. M. Shikin、S. A. Gorovikov、V. K. Adamchuk 等 5 位作者2003-06-26Physical Review Letters

Carbon nanostripes of graphene structure prepared on the stepped Ni(771) surface have been studied by angle-resolved photoemission. The electronic structure is anisotropic: parallel to the stripe direction, a graphite-type dispersion is measured, whereas the perpendicular direction displays two entangled band structur…

Graphene research and applicationsChemical and Physical Properties of MaterialsSurface and Thin Film Phenomena

In Situ Morphology of Cationic Flocculants Adsorbed on Surfaces and Their Interaction Forces Investigated by Atomic Force Microscopy

Tetsuya Arita、Yoichi Kanda、Hidenori Hamabe 等 6 位作者2003-06-26Langmuir

Images of typical cationic flocculants of high molecular weight, poly[2-(acryloyloxy)ethyl(trimethyl)ammonium chloride] (PATC), adsorbed on mica surface in situ in water were observed by tapping-mode atomic force microscopy (AFM) under various conditions. The corresponding interaction forces between surfaces were meas…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications

Complex Structures of Surface Relief Induced by Holographic Recording in Azo-Dye-Doped Elastomer Thin Films

Federica Ciuchi、A. Mazzulla、Giovanni Carbone 等 4 位作者2003-06-26Macromolecules

We report observations of unusual and complex structures recorded on the surface of azo-dye-doped elastomer thin films after irradiation with different interference light patterns. Periodic structures with a variety of topography are inscribed through holographic recording by both intensity light patterns and polariza…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesForce Microscopy Techniques and Applications

Electronic switching effect in phase-change memory cells

A. Pirovano、Andrea L. Lacaita、D. Merlani 等 6 位作者2003-06-26OpenAlex

A detailed investigation of the characteristic current-voltage (I-V) curve and electronic switching effect in chalcogenide-based phase-change memory devices is presented. An original bandgap model of both crystalline and amorphous chalcogenide and a physical picture of the fundamental effects involved in device operat…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesAdvanced Semiconductor Detectors and Materials

Novel Twin Corannulene: Synthesis and Crystal Structure Determination of a Dicorannulenobarrelene Dicarboxylate

Andrzej Syguła、Renata Sygula、Arkady Ellern 等 4 位作者2003-06-26Organic Letters

[reaction: see text] The dicorannulenobarrelene 1 was synthesized with the final step achieved by a nickel-mediated fourfold intramolecular coupling of dibromomethyl with bromomethyl groups. Low-temperature (1)H NMR spectra of 1 show a presence of three conformers with approximate populations of 0.82:0.13:0.05, in goo…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds