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Developments in understanding the formation, structure and properties of polymer networks

R. F. T. Stepto、J.I. Cail、D. J. R. Taylor 等 5 位作者2003-07-01Macromolecular Symposia

Abstract Two areas of networks modelling are described. The first is concerned with the application of a Monte‐Carlo (MC) algorithm to account fully for loop formation in RA 2 + R′B 3 and RA 2 + R′B 4 polymerisations. The resulting interpretation of experimental elastic moduli of HDI‐based polyurethane (PU) networks p…

Polymer Nanocomposites and PropertiesPolymer composites and self-healing

Molecular Weight and Long Chain Branch Distributions of Branch‐Block Olefinic Thermoplastic Elastomers

Márcio Nele、João B. P. Soares2003-07-01Macromolecular Theory and Simulations

Abstract Olefinic thermoplastic elastomers can be prepared by incorporating semi‐crystalline macromonomers (e.g. isotactic or syndiotactic poly(propylene), high‐density polyethylene) onto amorphous backbones (e.g. atactic poly(propylene), ethylene/ α ‐olefin copolymers). The macromonomer incorporation reaction can be…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Polyoxolenes may provide a tool for designing paramagnetic molecules with predetermined spin topologies

Alessandro Bencini、Andréa Caneschi、Andrea Dei 等 8 位作者2003-07-01Comptes Rendus Chimie

The development of the chemistry of transition metal complexes formed by o -semiquinonato radical ligands has provided a useful topic for learning how to use chemical methods for obtaining systems with predetermined magnetic properties. Similar complexes can be used as building blocks for assembling magnetically coupl…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Changes in particle area measurements due to SEM accelerating voltage and magnification

María Julia Yañez、Silvia E. Barbosa2003-07-01Microscopy Research and Technique

Scanning electron microscopy (SEM) images of polymer blends followed by digital image analysis is a rapid and easy method for the measurement of particle size and dispersion. The particle size determination is done with appropriate off-line image analysis software. However, it is necessary to understand how machine pa…

Corrosion Behavior and InhibitionElectron and X-Ray Spectroscopy TechniquesSurface Roughness and Optical Measurements

Structure‐mechanical properties relationship of poly(ethylene terephthalate) fibers

Milena Žiberna Šujica、Majda Sfiligoj Smole2003-07-01Journal of Applied Polymer Science

Abstract The correlation between the fiber structure and mechanical properties of two different poly(ethylene terephthalate) fiber types, that is, wool and cotton types produced by three producers, was studied. Fiber structure was determined using different analytical methods. Significant differences in the suprastruc…

Advanced Sensor and Energy Harvesting MaterialsTextile materials and evaluationsMaterial Properties and Processing

Deposition of silicon modified aluminide coatings on nickel base superalloys by pack cementation process

Zheng Xiang、P.K. Datta2003-07-01Materials Science and Technology

The equilibrium partial pressures of vapour species generated in halide activated pack powder mixtures at high temperatures were calculated for a series of compositions using thermochemical analysis tools. The results obtained were applied to identify suitable activators and pack compositions for codepositing Al and S…

High-Temperature Coating BehaviorsIntermetallics and Advanced Alloy PropertiesThermal and Kinetic Analysis

Factorial design in optimization of PHAs processing

Emo Chiellini、Elizabeth Grillo Fernandes、Matteo Pietrini 等 4 位作者2003-07-01Macromolecular Symposia

Abstract Poly(hydroxyalkanoate)s (PHA)s, as all melt‐processed polymers, may undergo thermal degradation at temperatures close to the melting point. The primary purpose of the present study is to screen out process variables on the basis of a factorial design for two variables at two levels. The investigated parameter…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Theoretical and experimental determination of the permeability tensor components of magnetized ferrites at microwave frequencies

Stéphane Mallégol、Patrick Quéffélec、M. Le Floc’h 等 4 位作者2003-07-01IEEE Transactions on Magnetics

We compare the diagonal /spl mu/ and off-diagonal /spl kappa/ permeability tensor components of magnetized polycrystalline ferrites given by the theoretical model of Gelin and Berthou with experimental ones at microwave frequencies. We used a broad-band and noniterative measurement technique recently developed within…

Magnetic Properties and Synthesis of FerritesElectromagnetic wave absorption materialsMagneto-Optical Properties and Applications

Effect of filler shape on mechanical properties of rigid polyurethane composites containing plant particles

Masahiro Funabashi、Shigeo Hirose、Tatsuko Hatakeyama 等 4 位作者2003-07-01Macromolecular Symposia

Abstract The effect of types of fillers on mechanical properties of rigid polyurethane composite samples was investigated. Polyurethane (PU) composites were prepared using a molasses polyol (MP, a mixture of molasses and polyethylene glycol, Mw=200) diphenylmethane diisocyanate (MDI) and fillers. The following plant p…

Natural Fiber Reinforced CompositesPolymer composites and self-healingPlant Surface Properties and Treatments

Experimental resolution measurement in critical dimension scanning electron microscope metrology

Gian F. Lorusso、David C. Joy2003-07-01Scanning

By applying the basic principles of metrology we discuss how to define the standards that any experimental method to measure resolution has to obey. Our results clearly indicate the need to apply a calibration procedure when designing algorithms to estimate resolution to satisfy accuracy requirements. Similarly, the p…

Advanced Electron Microscopy Techniques and ApplicationsAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Imaging multispectral polarimetric sensor: single-pixel design, fabrication, and characterization

Donghyun Kim、Cardinal Warde、K. Vaccaro 等 4 位作者2003-07-01Applied Optics

A discrete-component approach was taken to establish the operational feasibility of a novel, imaging, midinfrared, multispectral, polarimetric sensor for remote-sensing application. The sensor is designed to exploit the spectral and polarimetric characteristics of the scene as discriminants. Pixelated multispectral fi…

Photonic and Optical DevicesOptical Coatings and GratingsOptical Polarization and Ellipsometry

Investigations of a Control Surface Seal for Reentry Vehicles

Patrick H. Dunlap、Bruce M. Steinetz、Donald M. Curry 等 6 位作者2003-07-01Journal of Spacecraft and Rockets

Covers advancements in spacecraft and tactical and strategic missile systems, including subsystem design and application, mission design and analysis, materials and structures, developments in space sciences, space processing and manufacturing, space operations, and applications of space technologies to other fields.

Diamond and Carbon-based Materials ResearchTribology and Lubrication EngineeringSilicone and Siloxane Chemistry

Alkylated naphthalenes as high‐performance synthetic fluids

E. T. Hessell、Richard A. Abramshe2003-07-01Journal of Synthetic Lubrication

Abstract The physical and chemical properties for a series of structurally well‐defined, alkylated naphthalenes have been compared. Structural characteristics, such as the alkyl chain length, alkyl chain branching, and number of alkyl groups on the naphthalene ring, have been correlated with physical properties, such…

Surfactants and Colloidal SystemsPolymer composites and self-healingLignin and Wood Chemistry

Polymorphism and design of noncentrosymmetric crystals of 4-hydroxybenzaldehyde-4-nitrophenylhydrazone and N′-(2-phenyl-1H-indole-3-aldehyde)-4-nitrophenylhydrazone

L. N. Kuleshova、Mikhail Yu. Antipin、Victor N. Khrustalev 等 6 位作者2003-07-01Crystallography Reports

The products of crystallization of 4-hydroxybenzaldehyde-4-nitrophenylhydrazone ( I ) and N ′-(2-phenyl-1 H -indole-3-aldehyde)-4-nitrophenylhydrazone ( II ) from different solvents are studied by X-ray diffraction with the aim of examining the polymorphism of hydrazone derivatives. The structural features of the crys…

Synthesis and biological activityNonlinear Optical Materials ResearchChemical synthesis and pharmacological studies

Acid-Base Titrations in Nonaqueous Solvents and Solvent Mixtures

Lajos Barcza、Ágnes Buvári-Barcza2003-07-01Journal of Chemical Education

The acid–base determination of different substances by nonaqueous titrations is highly preferred in pharmaceutical analyses since the method is quantitative, exact, and reproducible. The modern interpretation of the reactions in nonaqueous solvents started in the last century, but several inconsistencies and unsolved…

Process Optimization and IntegrationCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Ti-Zr-Ni bulk quasicrystals prepared by casting

Jianbing Qiang、Yingmin Wang、Dehe Wang 等 5 位作者2003-07-01Philosophical Magazine Letters

A broad bulk-quasicrystal-forming region, (Ti x Zr100− x )100− y Ni y (43.75 ≤⃒ x ≤⃒ 81.25, 17 ≤⃒ y ≤⃒ 23), has been identified in the Ti-Zr-Ni system, and quasicrystals can be obtained by using a conventional suction-casting method. The quasilattice constant of the icosahedral (i) phase is within the range 0.505-0.53…

Intermetallics and Advanced Alloy PropertiesQuasicrystal Structures and PropertiesEurasian Exchange Networks

Study of Polymer Glasses by Modulated Differential Scanning Calorimetry in the Undergraduate Physical Chemistry Laboratory

J.C.W. Folmer、Stefan Franzen2003-07-01Journal of Chemical Education

Recent technological advances in thermal analysis present educational opportunities. In particular, modulated differential scanning calorimetry (MDSC) can be used to contrast reversing and nonreversing processes in practical laboratory experiments. The introduction of these concepts elucidates the relationship between…

Thermal and Kinetic AnalysisAdsorption, diffusion, and thermodynamic properties of materials

Insitu TEM studies of the mechanisms of crack nucleation and propagation in fully lamellar microstructures

Shaozhi Li、T.H. Yip、R.V. Ramanujan 等 4 位作者2003-07-01Materials Science and Technology

The mechanisms of crack nucleation and propagation of the lamellar microstructures found in pearlite were studied by in situ transmission electron microscopy. It was found that, in addition to the predominant mechanism of cleavage fracture in the cementite plates, ductile fracture of the cementite plates is another cr…

Advanced ceramic materials synthesisRock Mechanics and ModelingMicrostructure and mechanical properties

Investigation of oxide (V2O5) thin films as electrodes for rechargeable microbatteries using Li

A. Talledo、Héctor Valdivia、Carsten Benndorf2003-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

V 2 O 5 thin films were prepared by reactive rf sputtering and used in the application as electrodes in rechargeable battery with Li as a counterelectrode. The V2O5 films were deposited onto uncoated and SnO2 coated glass by sputtering a V cathode using Ar+O2 gas mixtures. The structural properties of the V2O5 films w…

Advancements in Battery MaterialsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials