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Characterization of High Surface Area Zr−Ce (1:1) Mixed Oxide Prepared by a Microemulsion Method

A. Martı́nez-Arias、Marcos Fernández–García、Villamil Ballesteros 等 7 位作者1999-06-04Langmuir

A Zr−Ce mixed oxide with ca. a 1:1 atomic ratio is prepared by a microemulsion method and studied by X-ray diffraction, transmission electron microscopy, and Raman, X-ray photoelectron (XPS) and electron paramagnetic resonance (EPR) spectroscopies. The results show the formation of a high surface area material ( S BET…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation Reactions

Rate-and-State Theory of Plastic Deformation Near a Circular Hole

J. S. Langer、Alexander E. Lobkovsky1999-06-04arXiv

We show that a simple rate-and-state theory accounts for most features of both time-independent and time-dependent plasticity in a spatially inhomogeneous situation, specifically, a circular hole in a large stressed plate. Those features include linear viscoelastic flow at small applied stresses, strain hardening at l…

Materials Science

Effects of noise and nonlocal interactions in nonlinear dynamics of molecular systems

Peter L. Christiansen、Galina I. Gaididei、Yuri B. Gaididei 等 6 位作者1999-06-03arXiv

We show that the NLS systems with multiplicative noise, nonlinear damping and nonlocal dispersion exhibit a variety of interesting effects which may be useful for modelling the dynamical behavior of one- and two-dimensional molecular systems.

Materials Science

Equilibrium shapes and energies of coherent strained InP islands

Q. K. K. Liu、N. Moll、M. Scheffler 等 4 位作者1999-06-02arXiv

The equilibrium shapes and energies of coherent strained InP islands grown on GaP have been investigated with a hybrid approach that has been previously applied to InAs islands on GaAs. This combines calculations of the surface energies by density functional theory and the bulk deformation energies by continuum elasti…

Materials Science

Anisotropic spin freezing in the S=1/2 zigzag ladder compound SrCuO2

I. A. Zaliznyak、C. Broholm、M. Kibune 等 5 位作者1999-06-02arXiv

Using magnetic neutron scattering we characterize an unusual low temperature phase in orthorhombic SrCuO2. The material contains zigzag spin ladders formed by pairs of S=1/2 chains (J=180 meV) coupled through a weak frustrated interaction |J'|<0.1J. At T

Materials Science

Optimum heat treatment condition for PZT thin films prepared by Sol-Gel

Aili Ding、Wel-Gen Luo、Pingsun Qiu 等 4 位作者1999-06-01Ferroelectrics

The effects of pyrolysis and annealing conditions on the orientation of PZT thin films prepared by Sol-Gel process have been investigated. The influence of the interface behaves between Ti and Pt formed at different heat treatment conditions on orientation of final PZT thin films was emphasized in this paper. The rela…

Dielectric materials and actuatorsAcoustic Wave Resonator TechnologiesFerroelectric and Piezoelectric Materials

Fractal-percolation model of the stability of foam

Yu. V. Pakharukov、T. E. Shevnina1999-06-01Journal of Experimental and Theoretical Physics Letters

A fractal-percolation model describing the stability of foam is studied. In this model, a correspondence is established between the system of branched channels and a fractal tree. In the proposed model, the foam breaks down by a scale-invariant load-transfer mechanism. A formula is obtained for calculating the height…

Stochastic processes and statistical mechanicsPickering emulsions and particle stabilizationTheoretical and Computational Physics

Untersuchungen zum chemischen Transport intermetallischer Phasen, I: GeTe, SnTe, PbTe / Investigations on the Chemical Transport of Intermetallic Phases, I: GeTe, SnTe, PbTe

O. Bosholm、H. Oppermann1999-06-01Zeitschrift für Naturforschung B

GeTe, SnTe, and PbTe have been prepared by chemical transport reactions with iodine as transport agent in the temperature range between T 2 (800 - 700°C) and T 1 (700 - 500°C). The effective transport equilibria were determineted. Total pressure measurements in the system Ge- Te-I give the coexistence equlibria for co…

Advanced Thermoelectric Materials and DevicesThermodynamic and Structural Properties of Metals and AlloysOptical properties and cooling technologies in crystalline materials

Ferroelastic transition triggered by an ordering mechanism in[(CH3)4N]SCN

M. Bonin、A. Fuith、Kurt Schenk 等 4 位作者1999-06-01Physical review. B, Condensed matter

Differential scanning calorimetry on powders and x-ray diffraction on single crystals of $({\mathrm{CH}}_{3}{)}_{4}\mathrm{NSCN}$ reveal a cell-doubling cubic-to-orthorhombic ${(O}_{h}^{1}\ensuremath{\rightarrow}{D}_{2h}^{13})$ ferroelastic transition at 181 \ifmmode^\circ\else\textdegree\fi{}C. This transformation is…

Organic and Molecular Conductors ResearchSolid-state spectroscopy and crystallographyCrystallography and molecular interactions

X-ray powder diffraction data for the ternary phases W 5 As 2.5 P 1.5 and Ni 4 Nb 5 P 4

Patricia Bénard-Rocherullé、Stéphanie Députier、F. Charki 等 4 位作者1999-06-01Powder Diffraction

The two ternary phases W 5 As 2.5 P 1.5 and Ni 4 Nb 5 P 4 have been investigated by X-ray powder diffraction. Precise data for the two compounds were collected using Cu K α 1 radiation over the range 11°–140° 2θ. Unit cell refinements (space group I 4/ m ) led to a =9.4729(3) Å, c =3.2414(2) Å ( D x =13.16 g cm −3 ) w…

X-ray Diffraction in CrystallographyRare-earth and actinide compoundsInorganic Chemistry and Materials

Design method of volt/turn for minimizing life cost of a superconducting transformer

Toshifumi Ise、Yohei Murakami1999-06-01IEEE Transactions on Applied Superconductivity

Many transformers using low Tc or high Tc superconductors have been built and tested, but it is still not clear how to design the volt/turn ratio property. This paper shows one design method, which minimizes total cost including initial cost and running cost. According to the results, the optimized volt/turn will be a…

Magnetic Properties and ApplicationsSuperconducting Materials and ApplicationsPhysics of Superconductivity and Magnetism

Novel phase behaviour in two (smectic/cholesteric) liquid crystal mixtures

Jenn Chiu Hwang、Shi Chang Liang、Kung Heng Liang 等 4 位作者1999-06-01Liquid Crystals

The phase behaviours of mixed liquid crystal systems having either Sm/N or Sm/Ch properties have been studied. The (smectic/nematic) binary system formed smectic phases over a wide and much enhanced range of temperature (42 C) and a broad concentration range (0-90 wt %). The ternary smectic/cholesteric system, in appr…

Molecular spectroscopy and chiralityPlant Reproductive BiologyLiquid Crystal Research Advancements

Dielectric and piezoelectric properties of PZN-PMN-PT ceramics

Feng Xia、Xi Yao1999-06-01Ferroelectrics

There is a morphotropic phase boundary (MPB) in the (1−x)(0.6PZN-0.4PMN)-xPT ceramic system when x=0.23. The dielectric and piezoelectric properties are very good for compositions lying near the MPB. After partially substituting Pb with Sr, dielectric and piezoelectric properties are increased apparently. The piezoele…

Microwave Dielectric Ceramics SynthesisAcoustic Wave Resonator TechnologiesFerroelectric and Piezoelectric Materials

In situ high-t neutron diffraction studies of non-convergent order/disorder in minerals: From simple oxides to complex silicates

Simon A. T. Redfern、Mark D. Welch、C. M. B. Henderson 等 4 位作者1999-06-01Phase Transitions

Neutron powder time of flight diffraction provides a powerful tool for the measurement of the temperature dependence of cation ordering in minerals, including non-convergent ordering. The successful application of the technique to the study of metal cation long range order in olivines and spinels is reviewed, and the…

X-ray Diffraction in CrystallographyAdvanced Condensed Matter PhysicsHigh-pressure geophysics and materials

A new type of surface spin wave in magnetoelectric crystals

С. В. Тарасенко1999-06-01Physics of the Solid State

It is shown for the case of a two-sublattice model of an antiferromagnet with a linear magnetoelectric effect that a new type of surface spin wave can arise at a boundary between a magnetoelectric and a nonmagnetic metal or between a magnetoelectric and a nonmagnetic insulator. This type of surface magnon arises from…

Advanced Condensed Matter PhysicsMultiferroics and related materialsMagnetic properties of thin films

Kristallstruktur des „supramolekularen“ Komplexes [K(Benzo-18-krone-6)][Zn(CN)3]*H2O mit einem polymeren kettenförmigen Tricyanozincat-Anion / Crystal Structure of the “Supramolecular” Complex [K(benzo-18-crown-6)][Zn(CN)3] •H2O with a Polymeric Tricyano Zincate Anion with Chain Structure

Joachim Pickardt、P. Wischlinski1999-06-01Zeitschrift für Naturforschung B

Crystals o f the complex [K (benzo-18-crown-6][Zn(CN) 3 ] H 2 O were obtained from a solution o f Zn(CN) 2 , KCN, and benzo-18-crown-6 in water/methanol. The compound crystallizes in the triclinic space group PI (no. 2),: Z = 2, a = 818,6(5), b = 1236,7(8), c = 1359,6(6) pm, a = 67,02(4), β = 87,38(4), 7 = 75,46(5). E…

Magnetism in coordination complexesInorganic Chemistry and MaterialsMetal-Organic Frameworks: Synthesis and Applications

Stability of the X-ray contrast agent iodixanol=3,3',5,5'-tetrakis(2,3-dihydroxypropylcarbamoyl)-2,2',4,4',6,6'-hexaiodo-N,N'-(2-hydroxypropane-1,3-diyl)-diacetanilide towards acid, base, oxygen, heat and light

Hanno Priebe、A. Aukrust、Hans‐René Bjørsvik 等 5 位作者1999-06-01Journal of Clinical Pharmacy and Therapeutics

BACKGROUND: During the production process of the X-ray contrast agent iodixanol the drug substance may be exposed to acid, base, air, heat and daylight, conditions that may cause decomposition products. OBJECTIVE: To investigate the chemical stability of iodixanol under accelerating conditions. METHOD: Chemometrical s…

Lanthanide and Transition Metal ComplexesOxidative Organic Chemistry ReactionsChemical Reactions and Mechanisms

Advances in PSII deposited DLC coatings for use as barriers to corrosion

R. S. Lillard、Darryl P. Butt、Neil Baker 等 5 位作者1999-06-01Surface Engineering

Plasma source ion implantation (PSII) is a non-line of sight process for implanting complex shaped targets without the need for complex fixturing. The breakdown initiation of materials coated with diamondlike carbon (DLC) produced by PSII occurs at defects in the DLC, which expose the underlying material, thus establi…

Diamond and Carbon-based Materials ResearchIon-surface interactions and analysisMetal and Thin Film Mechanics

Characteristics of Au/PbZr0.52Ti0.48O3/YBa2Cu3O7−δ capacitors fabricated on LaAlO3 and Y2O3-stabilized ZrO2 substrates during irradiation

Jianxia Gao、Lirong Zheng、Zhitang Song 等 7 位作者1999-06-01Philosophical Magazine B

PbZr0.52Ti0.48O3 (PZT)/YBa2Cu3O7−δ (YBCO) structures were fabricated on LaAlO3 and Y2O3-stabilized ZrO2 (YSZ) substrates by a pulsed-excimer-laser deposition method. The total dose effects on the Au/PZT/YBCO ferroelectric capacitors were considered by measuring the capacitance-voltage (C-V) characteristics and the ret…

Electronic and Structural Properties of OxidesAcoustic Wave Resonator TechnologiesFerroelectric and Piezoelectric Materials

Gasification of spent alkylation sulfuric acid droplets in hot environments

Difei F. Wang、Benjamin D. Shaw、Albert Yang1999-06-01AIChE Journal

Abstract Experimental results on gasification behaviors of freely‐falling spent alkylation sulfuric acid droplets in high‐temperature environments are presented, as well as baseline data on evaporation of water droplets and sulfuric acid droplets. Low evaporation constants have been measured for sulfuric acid droplets…

Thermochemical Biomass Conversion ProcessesThermal and Kinetic AnalysisCombustion and Detonation Processes