Materials Literature
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The decomposition of benzene was carried out using a plasma reactor packed with a mixture of BaTiO/sub 3/ and zeolite pellets, the zeolite-hybrid reactor. The reactor performance was characterized by measuring CO/sub x/ formed during plasma discharge and CO/sub x/ adsorbed on the solid surface, The decomposition effic…
Electrodes made by depositing ruthenium oxide on conducting poly(3,4-ethylenedioxythiophene) (PEDT) were studied for their electrochemical and impedance properties. In acidic electrolytes the composite electrodes exhibited large capacitance due to contributions from the double-layer capacitance and the faradaic capaci…
Bidimensional hexagonal or centred-rectangular mesoporous zirconia thin films have been reproducibly prepared by evaporation-induced self-assembly (EISA), which are stable up to 300 degrees C, with pore size around 35 A; the films can be post-functionalised with organic ligands presenting different functions, opening…
Successive reactions of gaseous trimethylaluminium (TMA) and ammonia on porous alumina were studied with the goal of finding suitable process conditions for preparing aluminium nitride (AlN) by atomic layer deposition (ALD), a technique based on separate saturating gas–solid reactions. The reaction of TMA was studied…
Abstract A fractional factorial experimental design was used to investigate relative effects of operating conditions on the filtration resistance of a slurry produced in a pharmaceutical semicontinuous batch crystallizer. The six operating variables were seed type, seed amount, temperature, solvent ratio, addition tim…
The aliphatic polyesters with high molecular weight have been prepared according to two methods. First is the synthesis of the polyesters by polycondensation of dimethyl succinate (DMS) with 1,4-butanediol (BD) using various metal alkoxides as a catalyst. Among the metal alkoxides used, titanium tetraisopropoxide [Ti(…
Silicon dioxide glass rods of micrometer sizes were synthesized by using surfactant–carbon nanotube co-micelles as templates. These glass rods were used as additives to reinforce inorganic ceramics. The mechanical strength of the silicon dioxide ceramic is enhanced by ∼100% in the presence of ∼6 wt% of CNTs.
Advanced finite element techniques for the simulation of materials behavior under mechanical loading are reviewed. Advantages, limitations and perspectives of different approaches are analyzed for the simulation of deformation, damage and fracture of materials taking into account their micro- and mesostructure. Develo…
A simple and predictive model is put forward explaining the experimentally observed substantial shift of the glass transition temperature, T g, of sufficiently thin polymer films. It focuses on the limit of small molecular weight, where geometrical `finite size' effects on the chain conformation can be ruled out. The…
Collagen matrices, crosslinked using N-(3-dimethylaminopropyl)-N'-ethylcarbodiimide (E) and N-hydroxysuccinimide (N), were previously developed as a substrate for endothelial cell seeding of small-diameter vascular grafts. In the present study, the biocompatibility of various EN-crosslinked collagen matrices was evalu…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTMultiphoton Gated Photochromic Reaction in a Diarylethene DerivativeHiroshi Miyasaka, Masataka Murakami, Akira Itaya, Dominique Guillaumont, Shinichiro Nakamura, and Masahiro IrieView Author Information Department of Polymer Science and Engineering Kyoto Institute of T…
Atomistic computer simulation methods have been employed to model the structure of the (104) surfaces of calcite (CaCO3), dolomite [CaMg(CO3)2] and magnesite (MgCO3). Our calculations show that, under anhydrous vacuum conditions, calcite undergoes the greatest degree of surface relaxation with rotation and distortion…
Monocytes and macrophages play important roles in host responses to implanted biomedical devices. Monocyte and macrophage interactions with biomaterial surfaces are thought to be mediated by adsorbed adhesive proteins such as fibrinogen and fibronectin. Non-fouling surfaces that minimize protein adsorption may therefo…
The use of porous matrices to enable damage tolerance in ceramic composites has emerged as a new paradigm in high performance materials. This paradigm obviates the need for fiber coatings for the purpose of crack deflection, thereby providing opportunities for lower cost manufacturing relative to that of conventional…
Poly(ethylene terephthalate) (PET) pellets used for production of soft drink bottles were reprocessed in a single-screw extruder and cut into pellets in five processing cycles. The reprocessed pellets were characterized by its rheological, mechanical, and thermal properties. Carboxylic end groups number concentration…
We study heat conduction in one-dimensional mass-disordered harmonic and anharmonic lattices. It is found that the thermal conductivity kappa of the disordered anharmonic lattice is finite at low temperature, whereas it diverges as kappa approximately N0.43 at high temperature. Moreover, we demonstrate that a unique n…
The optically active binaphthalene boron–dipyrromethene (BDP) conjugate 1 shows chiral discrimination towards the enantiomers of 1-phenylethylamine by distinguishable quenching rates of the BDP fluorescence.
Magnetoliposomes (MLs) were conjugated with an antibody fragment to give specificity to a tumor. The antibody fragment was cross-linked to N-(6-maleimidocaproyloxy)-dipalmitoyl phosphatidylethanolamine (EMC-DPPE) in liposomal membrane. The immobilization of the antibody fragment was optimal when the content of EMC-DPP…
The aim of this study was to generate spinel-type oxides by a continuous ultrasonic aerosol pyrolysis procedure and to evaluate the chemical and physical properties of the product powders. The ultrasonic aerosol pyrolysis process consists of three steps, which include “atomisation” of an aqeous metal nitrate solution,…
Lanthanum carbonate particles, which can be used as precursors to lanthanum oxide, have been synthesised from lanthanum nitrate and urea in the presence and absence of ultrasound irradiation. The use of ultrasound irradiation was found to have a remarkable effect on the morphology of the lanthanum carbonate particles…