Materials Literature
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The authors propose an approach to constructing three-dimensional tissue with capillaries using cellulose hollow fibers. Fibronectin (FN) was immobilized on hollow fibers to assure cell attachment. Bovine coronary artery smooth muscle cells (BCASMC) and L cells were seeded on FN-immobilized fibers and cultured for an…
ABSTRACT: Several proteins, lipids and waxes were tested as edible coatings on sweet corn. Only zein, a natural constituent of corn, gave a continuous adhesive and stable coating with satisfactory sensory properties. After 8 days at 10 °C, the population of L. monocytogenes was 10‐fold lower on coated sweet corn than…
Infrared and far infrared transmission spectra have been measured for the ferromagnetic Ga 1- x Mn x As ( x =0.034 and x =0.050) between 10 and 12000 cm -1 . A broad peak is observed around 1600 cm -1 , and this energy is close to the deep acceptor level of Mn impurity in GaAs. A finite featureless absorption, spreadi…
The role that alkyl chain packing density in a self-assembled monolayer (SAM) plays in the adsorption of protein to the SAM surface was investigated using in situ neutron reflectivity (NR) and total internal reflection fluorescence (TIRF) measurements of the adsorption behavior of human serum albumin (HSA) and human i…
A method is proposed for the local atomic distribution function analysis of amorphous materials. This method is based on local halo-electron diffraction intensity analysis with nano-sized electron probes as small as 25 to approximately 3 nm, taking advantage of the intensity recording with imaging plate. Nanodiffracti…
Abstract Clay-Polyacrylate hybrid material was prepared from Montmorillonite (M) clay and polytrimethylol propane triacrylate (PA) using intercalation polymerization process. Characterization of the composite was done by x-ray diffraction (XRD), infrared (IR) spectroscopy, scanning electron microscopy (SEM) and energy…
An approach for determining nonlinear optical properties within a quantum mechanics/molecular mechanics method is presented. The response equations in the multiconfigurational self-consistent-field/molecular mechanics approach that includes polarization effects are derived and implemented for second order in response…
Pyrochlore free 0.9Pb(Mg1/3Nb2/3)O3–0.1PbTiO3 thin films were prepared from alkoxide-based solution precursors. Preferential (111) crystallographic orientation was obtained on TiO2/Pt/TiO2/SiO2/Si substrates by spin coating. Dielectric, electrostrictive, and piezoelectric properties of the films were characterized in…
Total energy calculations have been performed within the periodic density-functional theory framework to study the dissociation of molecularly adsorbed nitrogen monoxide NO over three different catalytic surfaces: palladium, rhodium, and palladium-manganese (100). The potential energy surfaces for NO dissociation on t…
Mesoporous organosilicas based on a bridged organosilicate have been synthesized using a triblock PEO−PLGA−PEO copolymer containing a more hydrophobic poly(dl-lactic acid-co-glycolic acid) block and the structural difference between mesoporous organosilicas prepared from PEO−PLGA−PEO and PEO−PPO−PEO block templates is…
Onconase is an amphibian protein that is now in Phase III clinical trials as a cancer chemotherapeutic. Human pancreatic ribonuclease (RNase 1) is homologous to Onconase but is not cytotoxic. Here, ERDD RNase 1, which is the L86E/N88R/G89D/R91D variant of RNase 1, is shown to have conformational stability and ribonucl…
A new copper carboxylate polymer with cyanoacetate anion as a ligand was synthesized and studied using X-ray diffraction, IR, and EPR spectroscopy. The crystal is tetragonal: a = 14.702(2) Å, c = 13.470(3) Å, Z = 8, space group I 4 1 / a , and R = 0.0634. The copper atoms in the centrosymmetric dimeric fragment have a…
In this study, we explore the use of La0.7Ba0.3MnO3−δ (LBMO) for use in uncooled infrared bolometers. To obtain a high temperature coefficient of resistance (TCR) (defined as 1/R dR/dT) at near-room temperature, thin films were deposited on SrTiO3 (100), LaAlO3 (100) and MgO (100) substrates by a laser ablation method…
ABSTRACT: This study investigated the esterification of pigskin gelatin with fatty acid catalyzed by acid in aqueous medium. Factors affecting the esterification reaction B temperature, pH, water content, fatty acid concentration, fatty acid type and reaction time‐ were elucidated in the view of optimizing the reactio…
The preparation of starch carbamates of wrinkled pea starch in homogeneous phase catalysed by dibutyltin dilaurate in DMSO as solvent is described. The empfloyed isocyanates have linear alkyl chains with 7, 9, 11, 15 or 18 carbon atoms. Starch carbamates with equal degrees of substitution and different alkyl chains le…
The current work is focused on the examination of a new method for the determination of the specific surface areas of non-porous and macroporous carbons from gas adsorption isotherms. This method has rigorous foundations since it utilizes the adsorption potential distribution which is a unique thermodynamic characteri…
Three Cocconeis Ehrenberg species, epiphytic on the leaves of Posidonia oceanica (L.) Delile, were studied by light and electron microscopy. A new species, C. pseudonotata, is described which is closely related to C. notata Petit and C. diruptoides Hustedt. Gross morphology and the presence of a sigmoid raphe and ster…
The mechanical response of knitted glass- (GF) and carbon fiber (CF) fabric-reinforced polyamide-12 (PA-12) composites was compared both under static (tensile, flexural) and dynamic (perforation impact) conditions. The GF- and CF-content of the composites produced by hot pressing of 8 layers of planar weft knits conta…
Abstract Catalytic reduction of NO by propene in the presence of oxygen was studied over Sn–Al2O3 prepared by the sol–gel method. The maximum NO conversion did not change much with Sn loading (1–5 wt%), although the effective temperature window for NO reduction shifted to lower temperatures with increasing Sn loading.…
Abstract While the association constant of the colored form of a thermally irreversible photochromic indolylfulgimide with 2, 6-bis (octanoylamino)pyridine in toluene at 21 °C was 156 ± 11 mol−1 dm3 through triplex hydrogen bonding, that of its colorless form, generated by visible-light irradiation, was increased to 8…