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Copper(II) Complexes of Inverted Porphyrin and Its Methylated Derivatives

Piotr J. Chmielewski、Lechosław Latos‐Grażyński、Izabela Schmidt2000-11-01Inorganic Chemistry

The inverted porphyrins 2-aza-5,10,15,20-tetraphenyl-21-carbaporphyrin (CTPPH2) and its methylated derivatives 2-aza-2-methyl-5,10,15,20-tetraphenyl-21-carbaporphyrin (2-NCH3CTPPH) and 2-aza-2-methyl-5,10,15,20-tetraphenyl-21-methyl-21-carbaporphyrin (2-NCH3-21-CH3CTPPH) stabilize the rare organocopper(II) complexes (…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Magnetoelectric properties ofLiCoPO4andLiNiPO4

Igor Kornev、М. И. Бичурин、J.‐P. Rivera 等 7 位作者2000-11-01Physical review. B, Condensed matter

In strong magnetic fields up to 20 T quasistatic measurements of the magnetic-field-induced electric polarization have been performed in ${\mathrm{LiNiPO}}_{4}$ single crystals between 4.2 and $\ensuremath{\sim}25$ K. The magnetoelectric (ME) effect has been studied in detail near the N\'eel temperature. The temperatu…

Multiferroics and related materialsSolid-state spectroscopy and crystallographyOptical and Acousto-Optic Technologies

High resolution x-ray photoemission study of plasma oxidation of indium–tin–oxide thin film surfaces

Victor Christou、M. Etchells、O. Renault 等 7 位作者2000-11-01Journal of Applied Physics

The influence of plasma oxidation and other surface pretreatments on the electronic structure of indium–tin–oxide (ITO) thin films has been studied by high resolution x-ray photoemission spectroscopy. Plasma oxidation compensates n-type doping in the near surface region and leads to a reduction in the energy of plasmo…

ZnO doping and propertiesGa2O3 and related materialsElectronic and Structural Properties of Oxides

Carbon Monoxide Adsorption on Selected Gold Clusters: Highly Size-Dependent Activity and Saturation Compositions

William T. Wallace、Robert L. Whetten2000-11-01The Journal of Physical Chemistry B

The carbon monoxide (CO) adsorption activity of small gold-cluster anions (Au N -, N = 4−19) has been measured by pulsed helium flow-reactor methods at room temperature. In contrast to other metals, the reaction-product distributions, Au N (CO) M = ( N, M ), measured over a range of CO partial pressure, reveal highly…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceNanocluster Synthesis and Applications

Hydrothermal Synthesis of Layered Double Hydroxide−Deoxycholate Intercalation Compounds

Makoto Ogawa、Shiho Asai2000-11-01Chemistry of Materials

The Mg/Al layered double hydroxide−deoxycholate intercalation compounds were successfully synthesized by a novel hydrothermal reaction between brucite, gibbsite, and deoxycholic acid. The layered double hydroxide−deoxycholate intercalation compounds showed some important characteristics such as curved platy morphology…

Layered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic ConductivityMagnesium Oxide Properties and Applications

Selective dip-coating of chemically micropatterned surfaces

Anton A. Darhuber、Sandra M. Troian、Jeffrey M. Davis 等 5 位作者2000-11-01Journal of Applied Physics

We characterize the selective deposition of liquid microstructures on chemically heterogeneous surfaces by means of dip coating processes. The maximum deposited film thickness depends critically on the speed of withdrawal as well as the pattern size, geometry, and angular orientation. For vertically oriented hydrophil…

Surface Modification and SuperhydrophobicityFluid Dynamics and Thin FilmsNanofabrication and Lithography Techniques

Physical Properties of Poly(Lactic Acid) and Starch Composites with Various Blending Ratios

Tianyi Ke、Xiuzhi Susan Sun2000-11-01Cereal Chemistry

ABSTRACT Two‐phase polymer blends of poly(lactic acid) (PLA) and corn or wheat starches at various ratios were prepared by using a laboratory‐scale twin‐screw extruder and compression molding. The blends were characterized for thermal transitions, mechanical properties, and water absorption. Starch and PLA were immisc…

Food composition and propertiesNanocomposite Films for Food Packagingbiodegradable polymer synthesis and properties

Focused electron beam induced deposition of gold

Ivo Utke、P. Hoffmann、B. Dwir 等 6 位作者2000-11-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Codeposition of hydrocarbons is a severe problem during focused electron beam writing of pure metal nanostructures. When using organometallic precursors, a low metal content carbonaceous matrix embedding and separating numerous nanosized metal clusters is formed. In this work, we present a new and easy approach to obt…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Flame retardant mechanism of silica gel/silica

Takashi Kashiwagi、Jeffrey W. Gilman、Kathryn M. Butler 等 6 位作者2000-11-01Fire and Materials

Various types of silica, silica gel, fumed silicas and fused silica were added to polypropylene and polyethylene oxide to determine their flame retardant effectiveness and mechanisms. Polypropylene was chosen as a non-char-forming thermoplastic and polyethylene oxide was chosen as a polar char-forming (slight) thermop…

Polymer Nanocomposites and PropertiesFire dynamics and safety researchFlame retardant materials and properties

Ferroelectric phase transition and maximum dielectric permittivity of displacement type ferroelectrics (BaxSr1−xTiO3)

O. G. Vendik、S. P. Zubko2000-11-01Journal of Applied Physics

The main interest in the area of practical applications of ferroelectrics, particularly at the microwave frequency, is oriented now to room temperature. In this connection, ferroelectrics like BaxSr1−xTiO3 should be carefully studied. Such materials are characterized by the second order phase transition. In a perfect…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Production of Hollow Polymeric Microspheres by Surface-Confined Living Radical Polymerization on Silica Templates

Tarun K. Mandal、Michael S. Fleming、David R. Walt2000-11-01Chemistry of Materials

Uniform hollow polymer microspheres were prepared by coating silica microsphere templates with poly(benzyl methacrylate) using surface-initiated controlled/living radical polymerization and subsequently removing the core by chemical etching. Shell thickness was controlled by varying the polymerization time. Scanning e…

Mesoporous Materials and CatalysisPolymer Surface Interaction StudiesElectrophoretic Deposition in Materials Science

Wetting or non-wetting liquid?

Iordan Karmakov2000-11-01Physics Education

What factors determine whether or not a particular liquid will wet a particular surface? Is it possible for a meniscus in a capillary to become convex from concave? What would you have to do to flatten it out? In university courses in physics there is often a lack of example or comment concerning the influence of temp…

Surface Modification and Superhydrophobicity

Toy model for the mean-field theory of hard-sphere liquids

G. Parisi、František Slanina2000-11-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We investigate a toy model of liquid, based on simplified hypernetted chain equations in very large spatial dimension D. The model does not exhibit a phase transition, but several regimes of behavior when D-->infinity can be observed in different intervals of the density.

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesTheoretical and Computational Physics

Damage-Resistant Brittle Coatings

B. R. Lawn、K. S. Lee、Herzl Chai 等 8 位作者2000-11-01Advanced Engineering Materials

No abstracts

Material Properties and Applications

Fine structure of defects in radial nematic droplets

S. Mkaddem、Eugene C Gartland2000-11-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We investigate the structure of defects in nematic liquid crystals confined in spherical droplets and subject to radial strong anchoring. Equilibrium configurations of the order-parameter tensor field in a Landau-de Gennes free energy are numerically modeled using a finite-element package. Within the class of axially…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant Reproductive Biology

Radiation filters and emitters for the NIR based on periodically structured metal surfaces

Andreas Heinzel、Volkmar Boerner、Andreas Gombert 等 6 位作者2000-11-01Journal of Modern Optics

The spectrally selective optical properties of wavelength selective radiation emitters and filters based on periodically microstructured metal surfaces were investigated. Metal surfaces were structured by the use of a holographic mask and subsequent etching processes. Due to the microstructure, thermally excited surfa…

Optical Coatings and GratingsCalibration and Measurement TechniquesThermal Radiation and Cooling Technologies

Charge and spin ordering process in the mixed-valence systemLuFe2O4:Charge ordering

Y. Yamada、K. Kitsuda、Shinichiro Nohdo 等 4 位作者2000-11-01Physical review. B, Condensed matter

The charge ordering process in a mixed valence system ${\mathrm{LuFe}}_{2}{\mathrm{O}}_{4}$ is investigated both experimentally and theoretically. The experimental results using various types of diffraction techniques reveal the following unique features. (i) The system undergoes sequential transitions: $\mathrm{disor…

Physics of Superconductivity and MagnetismMultiferroics and related materialsAdvanced Condensed Matter Physics

Nucleation of Hydroxyapatite Crystal through Chemical Interaction with Collagen

Sang‐Hoon Rhee、Jae Do Lee、Junzo Tanaka2000-11-01Journal of the American Ceramic Society

The nucleation of hydroxyapatite (HAp) crystal through chemical interaction with collagen was investigated. A collagen membrane was soaked in a supersaturated simulated body fluid (1.5 SBF) solution with ion concentrations at 1.5 times that of normal simulated body fluid (1.0 SBF). A few carbonate‐containing HAp cryst…

Bone Tissue Engineering MaterialsBone health and osteoporosis researchCollagen: Extraction and Characterization

Synthesis, Structure, and Magnetic Properties of the Low-Symmetry Tetranuclear Cubane-like Nickel Complex [Ni4(pypentO)(pym)(μ3-OH)2(μ-Oac)2(NCS)2(OH2)]

J.M. Clemente-Juan、B. Chansou、B. Donnadieu 等 4 位作者2000-11-01Inorganic Chemistry

The tetranuclear [Ni4(pypentO)(pym)(mu 3-OH)2(mu-Oac)2(NCS)2(OH2)] cubane-like complex has been prepared, and its structure and magnetic properties have been studied (pypentO and pym are the deprotonated forms of 1,5-bis[(2-pyridylmethyl)amino]pentane-3-ol and 2-pyridylmethanol, respectively). The X-ray diffraction an…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Ultrasonic cavitation monitoring by acoustic noise power measurement

Jacques Frohly、Stéphane Labouret、C. Bruneel 等 5 位作者2000-11-01The Journal of the Acoustical Society of America

In this paper, a new tool is proposed to carry out acoustic cavitation monitoring and to have an overview of its effects in applications. After a brief review of the cavitation characterization techniques, it is shown that cavitation noise is a suitable and accurate indicator of the cavitation activity induced in a li…

Ultrasound and Cavitation PhenomenaNuclear Physics and ApplicationsElectrostatics and Colloid Interactions