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Biological control on calcite crystallization: AFM investigation of coccolith polysaccharide function

K. Henriksen、S. L. S. Stipp、J. R. Young 等 4 位作者2004-11-01American Mineralogist

Calcite crystals grown by organisms can be elaborate and enigmatic. One of the best examples is the tiny calcite shields known as coccoliths that are produced by unicellular algae. Coccoliths consist of interlocking single crystals of highly modified morphology, and complex organic molecules called CAPs (coccolith ass…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionBiocrusts and Microbial Ecology

Planar Tetracoordinate Carbon in Extended Systems

Pattath D. Pancharatna、M.A. Mendéz-Rojas、Gabriel Merino 等 5 位作者2004-11-01Journal of the American Chemical Society

A recently proposed system with a central planar tetracoordinate carbon linking two three-membered rings, C(5)(2-), lends itself to extension in one, two, and three dimensions. Our construction of potential realizations begins with an analysis of the electronic structure of C(5)(2-). Dimers such as C(10)Li(3-), C(10)L…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research

Two-dimensional dendritic ZnO nanowires from oxidation of Zn microcrystals

Hong Jin Fan、Roland W. Scholz、Florian Kolb 等 4 位作者2004-11-01Applied Physics Letters

Spontaneous formation of ZnO dendritic nanowires has been achieved on the faceted surfaces of polyhedral Zn microcrystals by oxidizing the latter at 600°C. Electron microscopy investigations reveal that all the dendritic branches are elongated in ⟨11–20⟩ directions within the ±(0001) primary planes, forming two-dimens…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesNanomaterials and Printing Technologies

Superconductivity in Charge Ordered Organic Conductor –α-(ET)2I3 Salt–

Akito Kobayashi、Shinya Katayama、Kouji Noguchi 等 4 位作者2004-11-01Journal of the Physical Society of Japan

We theoretically examine superconductivity in quasi-two-dimensional organic conductor, α-(ET) 2 I 3 salt, which has been found under uniaxial pressure and at temperature below the charge ordering. The interplay of many bands and several repulsive interactions gives rise to novel role of the charge ordering (CO), which…

Physics of Superconductivity and MagnetismPerovskite Materials and ApplicationsOrganic and Molecular Conductors Research

Ensemble and single particle photophysical properties (two‐photon excitation, anisotropy, FRET, lifetime, spectral conversion) of commercial quantum dots in solution and in live cells

Hernán E. Grecco、Keith A. Lidke、Rainer Heintzmann 等 8 位作者2004-11-01Microscopy Research and Technique

In this work, we characterized streptavidin-conjugated quantum dots (QDs) manufactured by Quantum Dot Corporation. We present data on: (1) two-photon excitation; (2) fluorescence lifetimes; (3) ensemble and single QD emission anisotropy; (4) QDs as donors for Forster resonance energy transfer (FRET); and (5) spectral…

Quantum Dots Synthesis And PropertiesAdvanced Fluorescence Microscopy TechniquesAdvanced Biosensing Techniques and Applications

Optical Properties and Potential Applications of Doped Semiconductor Nanoparticles

Wei Chen、Jin Z. Zhang、Alan G. Joly2004-11-01Journal of Nanoscience and Nanotechnology

Recent studies on the optical properties, in particular, luminescence, of a variety of doped semiconductor nanoparticles are reviewed. The effects of quantum confinement, temperature and pressure on luminescent properties are discussed. In addition, electroluminescence, cathodoluminescence, magnetoluminescence and rel…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesOptical properties and cooling technologies in crystalline materials

Carbon nanotubes for the delivery of therapeutic molecules

Alberto Bianco2004-11-01Expert Opinion on Drug Delivery

Functionalised carbon nanotubes (f-CNTs) are emerging as new tools in the field of nanobiotechnology and nanomedicine. This is because they can be easily manipulated and modified by encapsulation with biopolymers or by covalent linking of solubilising groups to the external walls and tips. The possibility of incorpora…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesGraphene and Nanomaterials Applications

Switching of Molecular Spin States in Inorganic Complexes by Temperature, Pressure, Magnetic Field and Light: Towards Molecular Devices

Azzedine Bousseksou、Gábor Molnár、G.S. Matouzenko2004-11-01European Journal of Inorganic Chemistry

Abstract The spin crossover phenomenon in molecular inorganic compounds is one of the most spectacular examples of bistability phenomena leading to a switching between the high‐spin and the low‐spin states of the molecule by several means such as temperature, pressure, light and magnetic field (multi‐property molecula…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Tensile Properties of Unsaturated Polyester-Based Sisal Fiber–Glass Fiber Hybrid Composites

K. John、S. Venkata Naidu2004-11-01Journal of Reinforced Plastics and Composites

The variation of tensile strength of unsaturated polyester based sisal–glass hybrid composites with fiber loading has been studied. The tensile strength of these hybrid composites has been found to be higher than that of the matrix. The effects of NaOH treatment and trimethoxy silane (coupling agent) treatment on the…

Natural Fiber Reinforced Composites

Optical Orientation of Excitons in CdSe Self-Assembled Quantum Dots

S. Mackowski、T. Gurung、H. E. Jackson 等 6 位作者2004-11-01arXiv

We study spin dynamics of excitons confined in self-assembled CdSe quantum dots by means of optical orientation in magnetic field. At zero field the exciton emission from QDs populated via LO phonon-assisted absorption shows a circular polarization of 14%. The polarization degree of the excitonic emission increases dr…

Materials Science

Materials Design of Transparent and Half-Metallic Ferromagnets of MgO, SrO and BaO without Magnetic Elements

Kazuhide Kenmochi、Van An Dinh、Kazunori Satō 等 5 位作者2004-11-01Journal of the Physical Society of Japan

We propose materials design to fabricate a new class of diluted magnetic semiconductors (DMSs) based on MgO, SrO and BaO without magnetic elements. Replacing the oxygen atoms by other atoms such as C atoms leads to the induction of a deep-impurity band. These materials show ferromagnetic behaviour if the impurity-band…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Effects of Interparticle Interactions upon the Magnetic Properties of CoFe2O4 and MnFe2O4 Nanocrystals

Christy R. Vestal、Qing Song、Z. John Zhang2004-11-01The Journal of Physical Chemistry B

The interparticle distance has been systematically varied by controlling the concentration of 8-nm CoFe 2 O 4 or MnFe 2 O 4 spinel ferrite nanocrystals dispersed in eicosane. For both nanoparticulate systems, the blocking temperature decreased with increasing interparticle distance through dilution of nanocrystals, wh…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Electrochemically deposited nanowhiskers of nickel oxide as a high-power pseudocapacitive electrode

K. Rajendra Prasad、Norio Miura2004-11-01Applied Physics Letters

High performance pseudocapacitive characteristics of potentiodynamically deposited NiO are reported here. Three-dimensional nanowhiskers of NiO were prepared by potentiodynamically depositing nickel hydroxide on stainless steel (SS) and heating the hydroxide in air at 300°C for 3h. The scan rate used for the depositio…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

1 ∕ f noise in single-walled carbon nanotube devices

E. S. Snow、James P. Novak、Marcus D. Lay 等 4 位作者2004-11-01Applied Physics Letters

We report the scaling behavior of 1∕f noise in single-walled carbon nanotube devices. In this study we use two-dimensional carbon nanotube networks to explore the geometric scaling of 1∕f noise and find that for devices of a given resistance the noise scales inversely with device size. We have established an empirical…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

An Explanation for the Size-Effect in Machining Using Strain Gradient Plasticity

Suhas S. Joshi、Shreyes N. Melkote2004-11-01Journal of Manufacturing Science and Engineering

This paper aims to explain the size-effect in the Primary Deformation Zone (PDZ) in machining using strain gradient plasticity theory. Considering a parallel-sided shear zone configuration, models are formulated for the evaluation of strain gradient, density of geometrically necessary dislocations, shear strength and…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsNonlocal and gradient elasticity in micro/nano structures

Förster energy transfer from blue-emitting polymers to colloidal CdSe∕ZnS core shell quantum dots

M. Anni、Liberato Manna、R. Cingolani 等 6 位作者2004-11-01Applied Physics Letters

We have studied the interactions in the solid phase between a blue-light-emitting organic conjugated polymer {poly[(9,9-dihexylfluorenyl-2,7-diyl)-alt-co-(9,ethyl-3,6-carbazole)]} and colloidal CdSe∕ZnS core shell quantum dots. We demonstrate by time resolved photoluminescence measurements that efficient Förster energ…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesOrganic Light-Emitting Diodes Research

Synthesis and piezoresponse of highly ordered Pb(Zr0.53Ti0.47)O3 nanowire arrays

X. Y. Zhang、Xu Zhao、Chuilin Lai 等 6 位作者2004-11-01Applied Physics Letters

We report the synthesis and characterization of ferroelectric lead zirconate titanate Pb(Zr0.53Ti0.47)O3 (PZT) nanowires. The PZT nanowires, with diameters of about 45nm and lengths of about 6μm, were fabricated by means of a sol-gel method utilizing nanochannel alumina templates. After postannealing at 700°C, the PZT…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesAnodic Oxide Films and Nanostructures

Effect of Compatibilizer on Nanostructure of the Biodegradable Cellulose Acetate/Organoclay Nanocomposites

Hwan-Man Park、Xuemei Liang、Amar K. Mohanty 等 5 位作者2004-11-01Macromolecules

Biodegradable nanocomposites were successfully fabricated from cellulose acetate (CA) plasticized with triethyl citrate (TEC), and combined with Cloisite 30B organoclay, using maleic anhydride grafted cellulose acetate butyrate (CAB- g -MA) as the compatibilizer. The nanostructure of the nanocomposites was investigate…

Polymer Nanocomposites and PropertiesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Synthesis of High Purity Silicon Nanoparticles in a Low Pressure Microwave Reactor

Jörg Knipping、Hartmut Wiggers、Bernd Rellinghaus 等 6 位作者2004-11-01Journal of Nanoscience and Nanotechnology

The formation of pure single crystalline silicon nanoparticles by microwave induced decomposition of silane in a low pressure flow reactor is reported. The morphology and crystal structure of the particles are characterized in situ by particle mass spectrometry (PMS) and ex situ by means of X-ray diffraction, high res…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisSilicon Nanostructures and Photoluminescence

Double-Exchange Model on Triangle Chain

Atsuo Satou、Masanori Yamanaka2004-11-01arXiv

We study ground state properties of the double-exchange model on triangle chain in the classical limit on $t_{2g}$ spins. The ground state is determined by a competition among the kinetic energy of the $e_g$ electron, the antiferromagnetic exchange energy between the $t_{2g}$ spins, and frustration due to a geometric…

Materials ScienceStrongly Correlated Electrons