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Effect of pH and ionic strength on the electrical charge and particle size distribution of starch nanocrystal suspensions

Ahlem Romdhane、M Aurousseau、Agnès Guillet 等 4 位作者2014-12-05Starch - Stärke

The current study investigates the amount of charged groups induced by sulfuric acid hydrolysis on the surface of starch nanocrystals. Conductometric titration revealed the existence of both weak and strong acidic groups. Strong acidic groups (sulfate ester groups) were present at low amounts (13.2 mmol kg −1 ) and th…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesElectrostatics and Colloid Interactions

Red-Green Emitting and Superparamagnetic Nanomarkers Containing Fe3O4 Functionalized with Calixarene and Rare Earth Complexes

Latif Ullah Khan、Hermi F. Brito、Jorma Hölsä 等 8 位作者2014-12-05Inorganic Chemistry

The design of bifunctional magnetic luminescent nanomaterials containing Fe3O4 functionalized with rare earth ion complexes of calixarene and β-diketonate ligands is reported. Their preparation is accessible through a facile one-pot method. These novel Fe3O4@calix-Eu(TTA) (TTA = thenoyltrifluoroacetonate) and Fe3O4@ca…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Fabrication of poly(methyl methacrylate)-MoS2/graphene heterostructure for memory device application

Sachin M. Shinde、Golap Kalita、Masaki Tanemura2014-12-05Journal of Applied Physics

Combination of two dimensional graphene and semi-conducting molybdenum disulfide (MoS2) is of great interest for various electronic device applications. Here, we demonstrate fabrication of a hybridized structure with the chemical vapor deposited graphene and MoS2 crystals to configure a memory device. Elongated hexago…

Graphene research and applicationsPerovskite Materials and Applications2D Materials and Applications

Toward Purple-to-Green-to-Transmissive-to-Black Color Switching in Polymeric Electrochrome

Elif Karabiyik、Emre Sefer、Fatma Baycan Koyuncu 等 6 位作者2014-12-05Macromolecules

A novel 3,4-ethylenedioxythiophene (EDOT)-based donor–acceptor electroactive monomer (HCQE) bearing carbazole subunit is synthesized, and then the corresponding polymer, poly(HCQE), is directly deposited onto ITO/glass surface via electrochemical process. Spectroelectrochemical studies demonstrate that poly(HCQE) is c…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Janus Si Micropillar Arrays with Thermal-Responsive Anisotropic Wettability for Manipulation of Microfluid Motions

Tieqiang Wang、Hongxu Chen、Kun Liu 等 9 位作者2014-12-05ACS Applied Materials & Interfaces

In this paper, Janus micropillar array (MPA) with fore-aft controllable wettability difference was demonstrated. With two-step modification process, we successfully decorate the Janus pillar skeletons with wettability-switchable polymer brush on one side and hydrophilic self-assembled monolayer on the other. Owing to…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsPickering emulsions and particle stabilization

Shock response of He bubbles in single crystal Cu

B. Li、Liang Wang、J. C. E 等 5 位作者2014-12-05Journal of Applied Physics

With large-scale molecular dynamics simulations, we investigate shock response of He nanobubbles in single crystal Cu. For sufficient bubble size or internal pressure, a prismatic dislocation loop may form around a bubble in unshocked Cu. The internal He pressure helps to stabilize the bubble against plastic deformati…

Microstructure and mechanical propertiesFusion materials and technologiesHigh-Velocity Impact and Material Behavior

Optimization of nanofibrous silk fibroin scaffold as a delivery system for bone marrow adherent cells: in vitro and in vivo studies

Mazaher Gholipourmalekabadi、Masoud Mozafari、Mojgan Bandehpour 等 10 位作者2014-12-05Biotechnology and Applied Biochemistry

Electrospun silk fibroin nanofibrous scaffolds (ESFNSs) were successfully prepared by electrospinning of various Bombyx mori silk fibroin concentrations (10, 12, and 14% in formic acid). After characterizing the purified silk fibroin, the morphology, porosity, fibers' diameter, and uniformity of the prepared scaffolds…

Electrospun Nanofibers in Biomedical ApplicationsPeriodontal Regeneration and TreatmentsSilk-based biomaterials and applications

One-dimensional barium titanate coated multi-walled carbon nanotube heterostructures: synthesis and electromagnetic absorption properties

Yaofeng Zhu、Qing‐Qing Ni、Yaqin Fu2014-12-05RSC Advances

BaTiO <sub>3</sub> @MWCNT heterostructures have been explored as microwave absorbers, which showed the maximum reflection loss with value of −25.7 dB at 12.1 GHz for 40 wt% loadings in wax, and the frequency bandwidth less than −20 dB is from 11.3 to 13.8 GHz.

Metamaterials and Metasurfaces ApplicationsElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface Technologies

Anomalous critical fields in quantum critical superconductors

Carsten Putzke、Philip Walmsley、J. D. Fletcher 等 15 位作者2014-12-05Nature Communications

Fluctuations around an antiferromagnetic quantum critical point (QCP) are believed to lead to unconventional superconductivity and in some cases to high-temperature superconductivity. However, the exact mechanism by which this occurs remains poorly understood. The iron-pnictide superconductor BaFe2(As(1-x)P(x))2 is pe…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

The role of reaction conditions in the polymorphic control of Eu 3+ doped YInO 3 : structure and size sensitive luminescence

Rakesh Shukla、Santosh K. Gupta、V. Grover 等 5 位作者2014-12-05Dalton Transactions

With the aim of exploring the effect of particle size and different polymorphic structures on the luminescence behaviour of Eu(3+) ions, all in a single compound, the YInO(3):Eu(3+) system was synthesized. Metastable C-type modification could be obtained in YInO(3) nanopowders synthesized by gel combustion. The broade…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesAdvanced Condensed Matter Physics

Vanadyl–Catecholamine Hydrogels Inspired by Ascidians and Mussels

Joseph P. Park、In Taek Song、Juwon Lee 等 6 位作者2014-12-05Chemistry of Materials

In general, mechanical properties and gelation kinetics exhibit a positive correlation with the amount of gelation reagents used. Similarly, for catechol-containing hydrogels, which have attracted significant attention, because of their unique dual properties of cohesion and adhesion, increased amounts of cross-linkin…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesInfectious Aortic and Vascular Conditions

Energy transfer within responsive pi-conjugated coassembled peptide-based nanostructures in aqueous environments

Herdeline Ann M. Ardoña、John D. Tovar2014-12-05Chemical Science

-phenylenevinylene)-based donor units and quaterthiophene-based acceptor units in completely aqueous environments. These peptide-based assemblies encourage energy migration along the stacking axis, thus resulting in the quenching of donor emission peaks along with the development of new spectral features reminiscent o…

2D Materials and ApplicationsConducting polymers and applicationsSupramolecular Self-Assembly in Materials

Inorganic Janus particles for biomedical applications

Isabel Schick、Steffen Lorenz、Dominik Gehrig 等 9 位作者2014-12-05Beilstein Journal of Nanotechnology

Based on recent developments regarding the synthesis and design of Janus nanoparticles, they have attracted increased scientific interest due to their outstanding properties. There are several combinations of multicomponent hetero-nanostructures including either purely organic or inorganic, as well as composite organi…

Nanoparticle-Based Drug DeliveryGold and Silver Nanoparticles Synthesis and ApplicationsPickering emulsions and particle stabilization

Cu2O nanoparticles synthesis by microplasma

Changming Du、MuDan Xiao2014-12-05Scientific Reports

A simple microplasma method was used to synthesize cuprous oxide (Cu2O) nanoparticles in NaCl-NaOH-NaNO3 electrolytic system. Microplasma was successfully used as the cathode and copper plate was used as the anode. The Cu2O products are characterized by X-ray powder diffraction (XRD), field emission scanning electron…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Effect of Temperature on the Growth of Silver Nanoparticles Using Plasmon-Mediated Method under the Irradiation of Green LEDs

Shan-Wei Lee、Shi‐Hise Chang、Yen‐Shang Lai 等 8 位作者2014-12-05Materials

Plasmon-mediated shape conversion of spherical silver nanoparticles (NPs) to nanostructures with other shapes under the irradiation of green LEDs (520 ± 20 nm, 35 mw/cm2) at various temperatures (60, 40, 20, 10, 5, and 0 °C) was performed in this study. It was found that the bath temperature used in the reaction can i…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsLaser-Ablation Synthesis of Nanoparticles

A Stencil Printed, High Energy Density Silver Oxide Battery Using a Novel Photopolymerizable Poly(acrylic acid) Separator

Kyle Braam、Vivek Subramanian2014-12-05Advanced Materials

A novel photopolymerized poly(acrylic acid) separator is demonstrated in a printed, high-energy-density silver oxide battery. The printed battery demonstrates a high capacity of 5.4 mA h cm(-2) at a discharge current density of 2.75 mA cm(-2) (C/2 rate) while delivering good mechanical flexibility and robustness.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsTransition Metal Oxide Nanomaterials

The effect of CuO NPs on reactive oxygen species and cell cycle gene expression in roots of rice

Shuling Wang、Hanzhu Liu、Yuxi Zhang 等 4 位作者2014-12-05Environmental Toxicology and Chemistry

To evaluate the effect of CuO nanoparticles (NPs) on root growth, root reactive oxygen species (ROS) production, and the expression of 2 genes (OsCDC2 and OsCYCD) associated with root growth of Oryza sativa (rice), rice roots were treated with 5 mg/L CuO NP suspension, 5 mg/L CuO bulk particle suspension, and 0.27 mg/…

Nanoparticles: synthesis and applicationsGraphene and Nanomaterials ApplicationsMedicinal Plants and Neuroprotection

Sugar and pH dual-responsive mesoporous silica nanocontainers based on competitive binding mechanisms

M. Deniz Yilmaz、Min Xue、Michael W. Ambrogio 等 10 位作者2014-12-05Nanoscale

A sugar and pH dual-responsive controlled release system, which is highly specific towards molecular stimuli, has been developed based on the binding between catechol and boronic acid on a platform of mesoporous silica nanoparticles (MSNs). By grafting phenylboronic acid stalks onto the silica surface, catechol-contai…

Nanoparticle-Based Drug DeliveryMesoporous Materials and CatalysisAnalytical Chemistry and Chromatography

Strain effects on oxygen migration in perovskites

Tam Mayeshiba、Dane Morgan2014-12-05Physical Chemistry Chemical Physics

Fast oxygen transport materials are necessary for a range of technologies, including efficient and cost-effective solid oxide fuel cells, gas separation membranes, oxygen sensors, chemical looping devices, and memristors. Strain is often proposed as a method to enhance the performance of oxygen transport materials, bu…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Self-Assembly of Amphiphilic Janus Particles into Monolayer Capsules for Enhanced Enzyme Catalysis in Organic Media

Wei Cao、Renliang Huang、Wei Qi 等 5 位作者2014-12-05ACS Applied Materials & Interfaces

Encapsulation of enzymes during the creation of an emulsion is a simple and efficient route for enhancing enzyme catalysis in organic media. Herein, we report a capsule with a shell comprising a monolayer of silica Janus particles (JPs) (referred to as a monolayer capsule) and a Pickering emulsion for the encapsulatio…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization